Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff          下载免费PDF全文

Chuan‐An Xia  Juxiu Tong  Bill X. Hu  Xiujie Wu  Alberto Guadagnini 《水文研究》2018,32(20):3140-3157

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.  相似文献   

太阳发电机理论研究进展     

姜杰  汪景琇 《天文学进展》2005,23(2):121-134

太阳发电机理论主要解释太阳磁场的起源和演化，是太阳物理中最基本、最重要的问题之一．对它的研究不仅具有重要的科学价值，而且对空间天气的预测和空间技术的发展有一定的影响．随着日震学的发展，该理论也得到了很大改进。从相关观测入手，综述了发电机理论需解释的观测事实，以及为发电机理论提供约束的太阳内部动力学结构；介绍了基本理论和近来的主流模型，并指出尚待解决的问题和进一步的努力方向。  相似文献   

对"数字地球"的几点认识   总被引：7，自引：0，他引：7  

江绵康 《地理信息世界》2003,1(3):1-3,13

自“数字地球”的概念被提出以来，已引起全球的广泛关注和积极响应。然而，数字地球在目前还仅仅是一个概念。为了逐步建立“数字地球”，需要就“数字地球”的理论、技术以及实现进行深入地探讨。从“数字地球”的产生背景、基本概念、研究内容、构成框架、关键技术、实施难点和发展战略等方面谈了对“数字地球”的一些认识。  相似文献   

海岩小说的几种叙述模式及弊端     

姚国军  李霞 《广东海洋大学学报》2006,26(5):87-90

海岩的长篇小说《河流如血》再创出版高记录，但作家仍局限于特有的小说叙述模式，这部作品设能做到相应的创新。概言之，模式第一面是“刑侦＋恋爱”；模式第二面是“财子＋佳人”；模式第三面是“道德＋法制”。文学创作需要不断创新，创新的过程也是对创作模式的不断突破过程。作家应该警惕的是，不要让模式成为创作的桎梏。  相似文献   

STRATEGY OF MAIZE′S CONCENTRATING TO ADVANTAGE AREAS IN JILIN PROVINCE     

JIANG Hui-ming  GU Li-li 《中国地理科学(英文版)》2003,(4)

WiththedevelopmentofagricultureandChina'sentryintoWTO,thesituationofsupplyanddemandinmaizemarkethaschangedgreatly.Facingtherelativesurplusofmaizeandtheformationofbuyer'smarket,weshouldfullydeveloprelativeadvantages,carryouttheunevenstrategyofsupportingthesuperior inmaizeproduction andcultivateadvantagedareasofmaize.Theabovestrategicmeasurescanrapidlyim-provetheinternationally competitiveabilityandpro-ductivityofmaizeinJilinProvince,getoutofthea-griculturalpredicamentandmaketheagriculturalde-…  相似文献   

Tidal effects on temperature front in the Yellow Sea   总被引：5，自引：0，他引：5  

Ma Jian  Qiao Fangli  Xia Changshui  Yang Yongzeng 《中国海洋湖沼学报》2004,22(3):314-321

Temperature front (TF) is one of the important features in the Yellow Sea, which forms in spring, thrives in summer, and fades in autumn as thermocline declines. TF intensity ⋎S _T ⋎ is defined to describe the distribution of TF. Based on the MASNUM wave-tide-circulation coupled model, temperature distribution in the Yellow Sea was simulated with and without tidal effects. Along 36°N, distribution of TF from the simulated results are compared with the observations, and a quantitative analysis is introduced to evaluate the tidal effects on the forming and maintaining processes of the TF. Tidal mixing and the circulation structure adapting to it are the main causes of the TF. Supported by the National Basic Research Program of China (No. G1999043809) and the National Science Foundation of China (No. 49736190).  相似文献   

中国大陆科学钻探先导孔零偏VSP资料解释   总被引：3，自引：3，他引：0  

姜修道  朱光明  朱龙生  张文波  李桂花 《地球科学与环境学报》2004,26(1):55-60

用六级三分量检波器在中国大陆科学钻探先导孔中实施了零偏VSP测量.数据处理结果表明,中国大陆科学钻探孔区超高压变质岩石的地震波速度主要介于4500～7000m/s之间,显著高于一般的沉积岩地区,而且随深度变化不明显.声波测井速度系统地稍低于VSP层速度,可能是由于井壁处岩石的完整性受到破坏而造成的.地震波速度与岩石密度和岩性存在明确的对应关系,榴辉岩的密度和地震波速度均显著高于片麻岩类岩石;由榴辉岩退变生成的斜长角闪岩类岩石,其密度和地震波速度均呈现出较大的变化,主要与其退变质程度有关;超基性岩中的裂隙系统导致其密度和地震波速度大幅度下降.由于榴辉岩与其他岩石类型之间存在较大的波阻抗差异,因此用零偏VSP资料标定该区地震波的地质层位是有效的.关于地震波反射的原因,通过综合研究地震波(包括反射纵波、上行转换横波、井筒波)的特征、岩石速度和密度分布以及井径变化,认为主要是岩性分界面、韧性剪切带和断裂(带),但还有一些因素尚待进一步研究.  相似文献   

彗木碰撞期间3.6和12cm射电观测     

蒋栋荣  金巍 《中国天文和天体物理学报》1996,(3)

本文介绍了1994年7月SL－9彗星撞击木星期间3．6cm和12cm射电连续谱观测的结果．在3．6cm波长上，撞击事件无明显的视效应，在12cm波长上，木星的射电平均视流量增加约20％．  相似文献   

PALEOSOLS　OF　SANDY　LANDS　AND　ENVIRONMENTAL　CHANGES　IN　THE　WESTERN　PART　OF　NORTHEAST　PLAIN　OF　CHINA　WESTERN　DURING　HOLOCENE     

裘善文  李取生  夏玉梅  王景璐 《中国地理科学(英文版)》1995,5(2):137-148

ＰＡＬＥＯＳＯＬＳＯＦＳＡＮＤＹＬＡＮＤＳＡＮＤＥＮＶＩＲＯＮＭＥＮＴＡＬＣＨＡＮＧＥＳＩＮＴＨＥＷＥＳＴＥＲＮＰＡＲＴＯＦＮＯＲＴＨＥＡＳＴＰＬＡＩＮＯＦＣＨＩＮＡＷＥＳＴＥＲＮＤＵＲＩＮＧＨＯＬＯＣＥＮＥ￥ＱｉｕＳｈａｎｗｅｎ（裘善文）ＬｉＱｕｓ...  相似文献   

成都及附近地区旅游气候资源研究   总被引：9，自引：0，他引：9  

胡毅  朱克云  江毓忠 《成都信息工程学院学报》2001,16(4):237-242

通过对成都及附近等7个地区多年气候资源及人体舒适指数进行分级比较，得出了7个地区的人体舒适指数的时间分布特征及对当地旅游的影响。  相似文献