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Edgar Hiller Bronislava Lalinská Martin Chovan Ľubomír Jurkovič Tomáš Klimko Michal Jankulár Róbert Hovorič Peter Šottník Renáta Fľaková Zlatica Ženišová Ivana Ondrejková 《Applied Geochemistry》2012
Environmental contamination with As and Sb caused by past mining activities at Sb mines is a significant problem in Slovakia. This study is focused on the environmental effects of the 5 abandoned Sb mines on water, stream sediment and soil since the mines are situated in the close vicinity of residential areas. Samples of mine wastes, various types of waters, stream sediments, soils, and leachates of the mine wastes, stream sediments and selected soils were analyzed for As and Sb to evaluate their geochemical dispersion from the mines. Mine wastes collected at the mine sites contained up to 5166 mg/kg As and 9861 mg/kg Sb. Arsenic in mine wastes was associated mostly with Fe oxides, whereas Sb was present frequently in the form of individual Sb, Sb(Fe) and Fe(Sb) oxides. Waters of different types such as groundwater, surface waters and mine waters, all contained elevated concentrations of As and Sb, reaching up to 2150 μg/L As and 9300 μg/L Sb, and had circum-neutral pH values because of the buffering capacity of abundant Ca- and Mg-carbonates. The concentrations of Sb in several household wells are a cause for concern, exceeding the Sb drinking water limit of 5 μg/L by as much as 25 times. Some attenuation of the As and Sb concentrations in mine and impoundment waters was expected because of the deposition of metalloids onto hydrous ferric oxides built up below adit entrances and impoundment discharges. These HFOs contained >20 wt.% As and 1.5 wt.% Sb. Stream sediments and soils have also been contaminated by As and Sb with the peak concentrations generally found near open adits and mine wastes. In addition to the discharged waters from open adits, the significant source of As and Sb contamination are waste-rock dumps and tailings impoundments. Leachates from mine wastes contained as much as 8400 μg/L As and 4060 μg/L Sb, suggesting that the mine wastes would have a great potential to contaminate the downstream environment. Moreover, the results of water leaching tests showed that Sb was released from the solids more efficiently than As under oxidizing conditions. This might partly explain the predominance of Sb over As in most water samples. 相似文献
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The main purpose of this paper is comparison of two different approaches of solution to the Simple Molodensky’s Problem, the
Molodensky’s Approach and the Analytical Continuation Approach, based on numerical computation. Although these approaches
have been described theoretically by several authors, e.g. Molodensky et al. (1960), Heiskanen and Moritz (1967), Vaníček
(1974), Moritz (1980) and Holota (1991, unpublished results) and theoretical proof of equivalence was given by Heiskanen and
Moritz (1967), Moritz (1971), Ecker (1971) and Pellinen (1972, unpublished results), only very few practical experiences about
the differences between particular solutions and computational efficiency exist. In this paper we compare the above two mentioned
approaches in terms of the G1-effect on quasigeoid. Both quasigeoid solutions are tested by the independent GPS/levelling approach and are also compared
with the previous quasigeoid model of Slovakia where the G1-term has been approximated using the classical terrain correction. The effect of the G2-term is also numerically estimated, revealing that it might be significant for the precise quasigeoid determination. Some
practical comments and recommendations are given at the end of the paper. 相似文献
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Mining and milling of metal ores coupled with industries have bequeathed many countries the legacy of wide distribution of metal contaminants in sediments. The aim of this study was to assess potential sediment contamination via useful screening methods (XRF, CHNS, TGA/MS). The sediments were collected from the water reservoir Krompachy Eastern Slovakia in April 2015. Within the frame of evaluation it was found that the concentrations of the study elements (Cu, Zn, As, Pb, Cr, Ni, Cd) exceeded some of the MPC, TV and IV values. Sample c was the most polluted by metals, which evident according to it’s the highest CHNS proportion as well as the highest clay and silt proportion. In the samples studied the best correlation was confirmed between weight losses in the temperature range (400–620 °C) and the following metal concentrations: Cu (r = 0.89), Zn (r = 0.88), As (r = 0.93), Hg (r = 0.83), Pb (r = 0.87). The greatest proportions of m/z 44, m/z 18 were detected at temperatures (400–620 °C) associated with decomposition of minerals such as siderite, barite, and exothermic loss of more refractory aromatic C took also place. 相似文献
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Marian Marschalko David Krčmář Isik Yilmaz Renáta Fľaková Zlatica Ženišová 《Environmental Earth Sciences》2018,77(3):95
The aim of the study is to evaluate the warming effect (thermal contamination) of city centres with high building density. This phenomenon has a number of scientific and practical implications. The case study was conducted in Bratislava (Slovakia), in the geological environment of alluvial gravels of the Danube River, where a permanent warming of the subsurface in the city centre is experienced, which is mainly affected by high building density and underground utilities. Thanks to this thermal contamination, the heat pumps efficiency is greater in winter, while in summer, their effectiveness is lower. Economically, this negative phenomenon in the case of heat pumps has a positive effect, since it increases energy efficiency during the heating period. This phenomenon is not universal and depends on the specific boundary conditions of the geological settings and hydrogeological conditions. 相似文献
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Selenium fractionation and speciation in rocks, soils, waters and plants in polluted surface mine environment 总被引：1，自引：0，他引：1
A fractionation and speciation was performed to determine the distribution of selenium (Se) species in major components of quartzite surface mine environment (rocks, mine tailings, soils, stream sediments, surface waters and plants) in obov, Slovakia. A three-step sequential extraction procedure was utilised for the fractionation of Se in mine tailings and soils. The first extractant in order to evaluate the soluble and ligand exchangeable fraction of Se (0.1 mol/l K2HPO4 + KH2PO4 at pH 7.0) solubilized up to 15% of total Se content. The second step (0.1 mol/l K2S2O8 at 90°C) which extracted Se associated or occluded with organic matter released 13 – 45% of total selenium. The decomposition of the residue (HNO3 + H2SO4 1+1) was used to solubilize the remaining 35–88% of total Se as the final step. The recovery of the procedure was between 97 and 106%. Selenate predominated in natural river and lake waters about pH 7.0 (>95%) but in acid mine leakings up to 40% of selenite was found. In the plants (birch leaves, grass leaves and roots) collected from the area acidified by mine leakings no significant accumulation of selenium was observed. The correlation between total Se and S in the rocks from the mine gives an evidence of the common origin of these elements in the studied area. 相似文献
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Marek Súľovský Vladimír Falťan Hana Skokanová Marek Havlíček František Petrovič 《自然地理学》2013,34(5):470-488
AbstractThe influence of abiotic conditions on land-use development since the nineteenth century is assessed in case studies from the Czech and Slovak Carpathians. Hypotheses claim that significant land-use changes have occurred, but without pronounced differences because of similar abiotic conditions in the case studies. Abiotic conditions are expressed by physiotopes, which contain information on georelief, lithology, and soil. Our results indicate a high rate of land-use change in both case studies, and a detailed analysis of changes in two sequential periods reveals significant differences in five of the six periods compared in these case studies. Areas along state border seem to be more affected by anthropogenic changes as the proportion of plots with stable land use was only 25.7% in the Czech area (Starý Hrozenkov, Vápenice, and Vy?kovec) compared to 47.6% in the Slovak area (Lietavská Svinná-Babkov). Repeated land-use changes occurred mostly in valley floors and adjacent slopes. Land-use changes in the study areas are only partly explained by the abiotic conditions in physiotope and morphometric attributes, as shown by multiple correspondence analysis. The crucial difference in land use is in different settlement structures, which reflect differences in historical development. 相似文献
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Iterative Spherical Downward Continuation Applied to Magnetic and Gravitational Data from Satellite 总被引：1，自引：0，他引：1
Josef Sebera Michal Šprlák Pavel Novák Aleš Bezděk Miloš Vaľko 《Surveys in Geophysics》2014,35(4):941-958
In the last few decades, satellites have acquired various potential data sets hundreds of kilometers above the Earth’s surface. Conventionally, these global magnetic and gravitational data sets are approximated by using spherical harmonics that allow straightforward work with both fields outside the Earth’s mass. In this article, we present an alternative approach for working with potential data in mass-free space given over a regular coordinate grid on a spherical surface. The algorithm is based on an iterative scheme and the Poisson integral equation for the sphere. With help from the Fourier transform, global potential (magnetic or gravitational) data can efficiently be continued from a mean orbital sphere down to a reference surface without using the spherical harmonics. This is illustrated both with simulated magnetic field data and with real data from the satellite gradiometry mission GOCE. In the case of simulated magnetic data and the downward continuation for 450 km, we have achieved a root mean square at the level of 0.05 nT, while it was <1 E (eotvos) for real GOCE data continued for 250 km. The crucial point is to apply the algorithm twice as a large part of noise can be removed from the input data. 相似文献
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Holec Juraj Šveda Martin Szatmári Daniel Feranec Ján Bobáľová Hana Kopecká Monika Šťastný Pavel 《Natural Hazards》2021,108(3):3099-3120
The aim of this interdisciplinary study is to assess the heat risk for Bratislava. The following layers were created to compute the risk index: the hazard layer of air temperature, a mitigation layer of tree vegetation, an exposure layer of population and a vulnerability layer of individuals over 65 years of age. The MUKLIMO_3 model was used to evaluate the field of mean surface air temperature at 9 PM during selected days of the summer heat wave in August 2018. The tree vegetation layer, in the form of percentage per grid cell, was derived from Sentinel-2 satellite data. Population density data are based on mobile positioning data, and elderly population data are based on a gridded database from the statistical census. Input layers were unified into a resolution of 500 × 500 m, and the heat risk index was calculated by summation of the weighted input layers. The results reflect the variability of the population and the elderly population within the city, as well as the variability of the temperature field, which is caused by the joint effect of an urban heat island and topography. The highest values of risk index occur within the broader city centre, with specific hot spots at several places.
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