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1.
Much of coral reef ecology has focused on how human impacts change coral reefs to macroalgal reefs. However, macroalgae may not always be a good indicator of reef decline, especially on reefs with significant sea urchin populations, as found in Kenya and Hawaii. This study tests the effects of trophic interactions (i.e. herbivory by fishes and sea urchins) and spatial competition (between algae and coral) on algal community structure of reefs surrounding two Hawaiian Islands that vary in their level of human impacts. Reef‐building organisms (corals and crustose coralline algae) were less abundant and turf algae were more abundant on Maui as compared to Lanai, where human impacts are lower. In contrast to previous studies, we found no evidence that macroalgae increased with human impacts. Instead, low turf and macroalgal abundance were best explained by the interactive effects of coral cover and sea urchin abundance. Fishing sea urchin predators appeared to have cascading effects on the benthic community. The absence of sea urchin predators and high sea urchin densities correspond to a disproportionately high abundance of turf and crustose coralline algae. We propose that high turf algal abundance is a better indicator of reef decline in Hawaii than high macroalgal abundance because turf abundance was highest on reefs with low coral cover and few fish. The results of this study emphasize that understanding changes in community composition are context‐dependent and that not all degraded reefs look the same.  相似文献   
2.
Theoretical analysis and laboratory column experiments were carried out to investigate the conditions required for petroleum products (oil) to flow into a well installed through a sandy porous medium contaminated with the oil. The results indicated that oil would flow into a well only after a layer of "free oil" is formed in the adjacent porous medium. Because significant quantities of oil could be stored in the porous medium under the influence of capillary suction prior to the formation of the zone of free oil, the presence of oil in a well would indicate an advanced stage of oil contamination of the subsurface. While monitoring wells could be used to delineate the extent of the free-oil plume and the plume of dissolved petroleum constituents, they are not useful for delineating the extent of capillary held oil.
The experimental results also indicated that the ratio of the oil-layer thickness in the well to that in the porous medium is not a constant as is sometimes assumed in practice. Further, estimates of the oil thickness in the medium based on the oil thickness in wells and on capillary properties measured in the laboratory were sensitive to the values of the parameters used in these estimates. The measured thickness of the oil layer in a monitoring well alone may not yield reliable estimates of the amount of oil in the subsurface, and assuming that the oil-thickness ratio is a constant can lead to inadequate site assessments and inappropriate remedial plans.  相似文献   
3.
Anisotropy of magnetic susceptibility (AMS) of the middle Tertiary Bloodgood Canyon and Shelley Peak Tuffs of the Mogollon-Datil volcanic field has been used to (1) evaluate the ability of AMS to constrain flow lineations in low-susceptibility ash-flow tuffs; (2) establish a correlation between magnetic fabric, magnetic mineralogy, tuff facies, and characteristics of the depositional setting; and (3) constrain source locations of the tuffs. The tuffs are associated with the overlapping Bursum caldera and Gila Cliff Dwellings basin. The high-silica Bloodgood Canyon Tuff fills the Gila Cliff Dwellings basin and occurs as thin outcrops outside of the basin. The older Shelley Peak Tuff occurs as thin outcrops both along the boundary between the two structures, and outside of the complex. AMS data were collected from 16 sites of Bloodgood Canyon Tuff basin fill, 19 sites of Bloodgood Canyon Tuff outflow, and 11 sites of Shelley Peak Tuff. Sites were classified on the basis of within-site clustering of orientations of principal susceptibility axes, based on the categories of Knight et al. (1986). Most microscopically visible oxide minerals in the Bloodgood Canyon Tuff outflow and basin fill, and in the Shelley Peak Tuff are members of the hematite-ilmenite solid solution series. However, IRM acquisition data indicate that Bloodgood Canyon Tuff basin fill and Shelley Peak Tuff have magnetic mineralogy dominated by single- or pseudo-single-domain magnetite, and that the magnetic mineralogy of the Bloodgood Canyon Tuff outflow is dominated by hematite. Hematite in Bloodgood Canyon Tuff outflow is likely to be the result of deuteric and/or low-temperature alteration of magnetite and iron silicate minerals. Bulk magnetic susceptibility is higher in magnetite-dominated ash-flow tuff (Bloodgood Canyon Tuff basin fill and Shelley Peak Tuff) than it is in hematite-dominated ash-flow tuff (Bloodgood Canyon Tuff outflow). Bloodgood Canyon Tuff outflow has the highest total anisotropy (H) of the three units, followed by Shelley Peak Tuff and Bloodgood Canyon Tuff basin fill. All three ash-flow tuffs are genearlly characterized by oblate susceptibility ellipsoids, with those of the Bloodgood Canyon Tuff basin fill nearest to spherical. At high values of total anisotropy, Shelley Peak Tuff susceptibility ellipsoids attain a prolate shape; those of Bloodgood Canyon Tuff outflow attain an increasingly oblate shape. Three factors may influence differences in total anisotropy and susceptibility ellipsoid shape: (1) ash which travelled the greatest distance before deposition may show the best development of magnetic fabric, particularly of magnetic lineation; (2) deposition of ash in a closed basin may inhibit laminar flow throughout the sheet and the resulting development of flow textures; and (3) replacement of magnetite and iron silicates preferentially oriented within the foliation plane by hematite with strong crystalline anisotropy may enhance the magnetic susceptibility within that plane. Scatter in AMS axis orientation within sites may result from: (1) greater orientation inaccuracy in block-sampled than in fielddrilled samples; (2) rheomorphism; and (3) low accuracy of AMS measurement in low-susceptibility ashflow tuffs. Evaluation of flow lineation based on AMS of sites with well-clustered K 1 axes indicates that (1) Bloodgood Canyon Tuff basin fill flowed along a generally northwest-southeast azimuth; (2) Shelley Peak Tuff located on the boundary of the Bursum caldera and the Gila Cliff Dwellings basin flowed along a nearly east-west azimuth; and (3) Bloodgood Canyon Tuff outflow sites have K 1 susceptibility axes generally radial to the Bursum-Gila Cliff Dwellings complex, but within-site scatter of K 1 orientations is generally too large to draw conclusions about flow lineation orientation. Limited petrographic work on pilot thin sections adds flow direction information to AMS-derived flow lineation information.  相似文献   
4.
Marine mammals are probably frequently exposed to floating oil but little is known about the effect oil pollution has on them. Oil stranded on the shore in Pembrokeshire, West Wales in September 1974 coincided with the start of the Grey Seal breeding season there. Observations have been made on the effect the oil had on the newborn pups and their mothers.  相似文献   
5.
We report radiocarbon measurements of dissolved inorganic carbon (DIC) in surface water samples collected daily during cruises to the central North Pacific, the Sargasso Sea and the Southern Ocean. The ranges of Δ14C measurements for each cruise (11–30‰) were larger than the total uncertainty (7.8‰, 2-sigma) of the measurements. The variability is attributed to changes in the upper water mass that took place at each site over a two to four week period. These results indicate that variability of surface Δ14C values is larger than the analytical precision, because of patchiness that exists in the DIC Δ14C signature of the surface ocean. This additional variability can affect estimates of geochemical parameters such as the air–sea CO2 exchange rate using radiocarbon.  相似文献   
6.
Spatial and seasonal variations in CO2 and CH4 concentrations in streamwater and adjacent soils were studied at three sites on Brocky Burn, a headwater stream draining a peatland catchment in upland Britain. Concentrations of both gases in the soil atmosphere were significantly higher in peat and riparian soils than in mineral soils. Peat and riparian soil CO2 concentrations varied seasonally, showing a positive correlation with air and soil temperature. Streamwater CO2 concentrations at the upper sampling site, which mostly drained deep peats, varied from 2·8 to 9·8 mg l?1 (2·5 to 11·9 times atmospheric saturation) and decreased markedly downstream. Temperature‐related seasonal variations in peat and riparian soil CO2 were reflected in the stream at the upper site, where 77% of biweekly variation was explained by an autoregressive model based on: (i) a negative log‐linear relationship with stream flow; (ii) a positive linear relationship with soil CO2 concentrations in the shallow riparian wells; and (iii) a negative linear relationship with soil CO2 concentrations in the shallow peat wells, with a significant 2‐week lag term. These relationships changed markedly downstream, with an apparent decrease in the soil–stream linkage and a switch to a positive relationship between stream flow and stream CO2. Streamwater CH4 concentrations also declined sharply downstream, but were much lower (<0·01 to 0·12 mg l?1) than those of CO2 and showed no seasonal variation, nor any relationship with soil atmospheric CH4 concentrations. However, stream CH4 was significantly correlated with stream flow at the upper site, which explained 57% of biweekly variations in dissolved concentrations. We conclude that stream CO2 can be a useful integrative measure of whole catchment respiration, but only at sites where the soil–stream linkage is strong. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   
7.
The Fourier transform infrared spectra of individual conodonts with various CAI values indicate definite changes in conodont francolite during diagenesis. Steady decarbonation can be observed in the increasing intensity of the band with the wavenumber 2340 an-1, which is assigned to trapped molecular CO2. Carbon dioxide originates from decomposing CO2-3-ions occupying the B-site in francolite. Furthermore, the intensity of the water-deformation band at 1644 cm-1 decreases with higher CAI values. These changes of intensity can be quantified by calculating the maximum extinction (Emax) for the corresponding absorption maxima and correlated with the CAI. Unaltered conodonts have a relative variable water 'content' and very little CO2. Up to a CAI value of 4 conodont francolite continuously expells water and carbon dioxide is trapped. Conodonts with CAI = 5 have similar water 'contents' to CAI = 4 conodonts, but decarbonation continues to take place during this stage of diagenesis.  相似文献   
8.
Private wells in Cayuga and Orange counties in New York were sampled to determine the occurrence of pesticide contamination of groundwater in areas where significant pesticide use coincides with shallow or otherwise vulnerable groundwater. Well selection was based on local groundwater knowledge, risk modeling, aerial photo assessments, and pesticide application database mapping. Single timepoint samples from 40 wells in each county were subjected to 93‐compound chromatographic scans. All samples were nondetects (reporting limits ≤1 μg/L), thus no wells from either county exceeded any of 15 state groundwater standards or guidance values. More sensitive enzyme‐linked immunosorbent assays (ELISA) found two wells with quantifiable atrazine in each county (0.1–0.3 μg/L), one well with quantifiable diazinon (0.1 μg/L) in Orange County, and one well with quantifiable alachlor (0.2 μg/L) in Cayuga County. Trace detections (<0.1 μg/L) in Cayuga County included atrazine (five wells), metolachlor (six wells), and alachlor (one well), including three wells with multiple detections. All 12 Cayuga County wells with ELISA detections had either corn/grain or corn/forage rotations as primary surrounding land uses (although 20 other wells with the same land uses had no detections) and all quantified detections and most trace detections occurred in wells up to 9‐m deep. Orange County trace (<0.1 μg/L) ELISA detections (atrazine three wells, diazinon one well, and metolachlor five wells) and quantified detections were only generally associated with agricultural land uses. Finding acceptable drinking water quality in areas of vulnerable groundwater suggests that water quality in less vulnerable areas will also be good.  相似文献   
9.
Early reproductive success of hard clams (Mercenaria mercenaria) in Long Island Sound was measured to determine whether pollution may have adverse effects on fragile recruitment to fisheries. Clams were collected at five sites in 1987 when ready to spawn naturally, along with water from within 39 cm of the bottom. Levels of polychlorinated biphenyls (PCBs), copper, and cadmium were measured in the mature gonad and were found to be generally low. Clams were spawned and the gametes were collected and cultured both in their respective site waters and in reference laboratory seawater. In both site and reference seawater, embryos of clams from the most highly industrialized area (Bridgeport) with higher contaminant levels exhibited more irregularity in chromosome numbers and greater larval abnormality, possible indicators of long-term sublethal effects. Fertilization and early meiotic success at 1 to 1 1/2 h were significantly lower (p≤0.05) for clams from Norwalk (55%) than for those from Greenwich (75%). At 48 h, mortality was lowest for Greenwich larvae and highest for Norwalk larvae in their respective site waters, but the mortality for these two sites was significantly lower than for other sites in reference water. This suggests sporadically poor environmental quality. Milford larvae also had significant mortality. Population-level significance of pollution effects on clam reproduction will depend on how contaminated the environment is over the entire reproductive season of the clams in Long Island Sound, and over how large a portion of the spawning grounds.  相似文献   
10.
The center-to-center method of strain analysis can be used to estimate flow lineation in high-silica ash-flow tuffs. It can be used as an alternative or supplement to other techniques for flow lineation identification, such as the examination of flow textures in thin sections and the measurement of anisotropy of magnetic susceptibility. The center-to-center method is a modification of a technique described by Fry (1979) and by Ramsay and Huber (1983) for determination of finite strain based on the spacing of particles within a deformed rock. In the present study, application of the method to an anticlustered array of phenocrysts in the flattening plane of an ash-flow tuff produces an ellipse with center to edge distances representative of the minimum distance between centers of phenocrysts in all directions within the flattening plane. The long axis of the ellipse corresponds to the maximum axis of finite strain; this direction is suggested to correspond to the flow lineation. The orientation of the stretching lineation was chosen both by eye and by least-squares analysis from center-to-center plots. The calculated orientation of the long ellipse axis can be varied by choice of a maximum distance between digitized objects which are included in the calculation. Comparison is made between late-stage flow lineations identified using the center-to-center method, and the AMS (anisotropy of magnetic susceptibility) method on samples of the high-silica Oligocene Bloodgood Canyon Tuff from the Mogollon-Datil volcanic field of southwestern New Mexico. Flow lineations based on center-to-center analyses of flattening plane-parallel rock slabs and thin sections agree well with AMS-derived flow lineations on most samples from which high-quality AMS lineations were obtained. Center-to-center analuses from flattening plane-perpendicular, lineation-parallel planes of ash-flow tuff produce ellipses inclined from 15° to 85° to the flattening plane, despite compaction of the ash, which should cause angles of inclination to be very low. The inclined ellipses may result from heterogeneities in grain size and distribution of phenocrysts in vertical sections of tuff, or from fragmentation of phenocrysts which occurred during the final stages of emplacement and compression. Center-to-center analyses on rock slabs rather than thin sections helps to avoid the effects of either textural heterogeneity and fragmentation of phenocrysts. With flow lineation identified by center-to-center analysis, petrographic examination of thin sections cut perpendicular to the flattening plane and parallel to the flow lineation allow for the identification of flow direction.  相似文献   
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