南海高钙沉积物中18种常微量元素的ICP-AES测定方法研究     

王湘芹  陈志华  任红  孙琼 《海洋科学进展》2007,25(2):220-225

在利用ICP-AES分析南海高钙沉积物中的常微量元素时,钙、镁常常干扰其它元素测试。通过采用优化仪器工作参数、扣除背景值、谱线干扰校正和基体匹配的步骤,消除了元素干扰和钙、镁基体效应,提高了方法的灵敏度和准确度。通过对南海沉积物样品的大量实验和国家一级标准样验证,建立了适宜高钙海洋沉积物元素含量的ICP-AES测试方法。该方法检出限为1.55~271μg/L,相对标准偏差RSD<4.54%(n=6)。  相似文献   

华南石炭纪岩关-大塘界线期牙形石地层分带   总被引：4，自引：0，他引：4  

田树刚  M.科恩 《地质通报》2004,23(8):737-749

系统采集不同沉积相区和连续沉积的剖面，即浅海台地相广西柳江龙殿山剖面、台缘缓坡相云南施甸鱼硐剖面和台内盆地相广西柳州碰冲剖面，运用数理统计方法，研究了华南岩关一大塘界线过渡期牙形石的产出丰度和相分布，在恢复生物演化序列的基础上，对各剖面首先详细分带，再进一步综合成系统的5个牙形石带，即Gnathodus typicus—G．cuneiformis带、Gnathodus typicus—Protognathodus cordiformis带、Scaliognathus anchoralis—Gnathodus pseu-dosemiglaber带、Gnathodus praebilineatus带和Paragnathodus horrtopunctatus带。以生物系统发生为标准，严格限定各带的界线，并与北美、西欧同期地层进行精确对比，为建立杜内阶一维宪阶界线的全球层型(GSSP)提供可靠依据。  相似文献   

广东良口黄田埔高分异Ⅰ型花岗岩地球化学特征及大地构造意义     

苏扣林 《江苏地质》2018,42(2):197-205

广州从化区良口亚髻山霞石正长岩为典型岩石遗迹,在碱性岩体野外填图研究过程中,新发现东侧分布有黄田埔高分异花岗岩,形成时间约(146±13)Ma,为晚侏罗世岩浆活动产物。元素地球化学特征显示硅高、钾富、分异指数高、Rb/Sr比值高以及Rb/Ba、Nb/Ta、Zr/Hf、TFeO/MgO比值低;稀土元素ΣREE平均值为248 g/t,ΣCe/ΣYb平均值为2.34,δEu(0.16)负异常明显;Ga(×10~4)/Al比值较低(平均值为3.47),Zr+Nb+Ce+Y含量(平均值为264g/t)低于A型花岗岩(350 g/t);I(Sr)值为0.691 8~0.712 8,平均值为0.708 1;ε_(Nd)(t)值为-3.5~-10.0,平均值为-6.7。元素地球化学、同位素地球化学和同位素年代学综合研究结果表明,岩株的形成可能与上地幔岩浆分异有关,为高分异Ⅰ型花岗岩。  相似文献   

湘南地区芙蓉锡矿床中硼矿化的发现及意义     

李小赛  李厚民  李立兴  沈宏飞 《矿床地质》2021,40(6):1351-1356

硼矿是中国重要的紧缺矿产,长期依赖进口,找寻新的硼矿资源迫在眉睫.笔者在湘南地区芙蓉锡矿床新发现了矽卡岩型硼矿化,硼矿物包括硼镁铁矿、遂安石和氟硼镁石,1件典型样品的X射线粉晶衍射分析结果表明硼矿物总含量达到47.4％,换算成w(B)(以B2O3计)约为9.5％,高于5％的硼矿最低工业品位.该发现预示着湘南地区,乃至华南与高分异花岗岩有关的钨锡多金属矿集区有良好的硼成矿潜力,在今后的找矿过程中,需加强与钨锡多金属共伴生的硼矿化评价工作.  相似文献   

西藏甲玛矿床南坑高分异Ⅰ型花岗斑岩及黑云母矿物学特征     

陈国良  张忠坤  孙渺  林彬  赫健  唐攀  格桑顿珠  苏贵喆  任绍渊  胡海涛 《矿物岩石地球化学通报》2021,40(2):411-424

高硅花岗岩对于理解浅部岩浆房的行为具有重要意义。本文对西藏甲玛矿区南坑矿段的花岗斑岩开展了岩相学、岩石地球化学及黑云母矿物学研究。结果显示,该花岗斑岩具有高SiO2(73.39%~77.99%)、高K2O(4.34%~6.45%)和低P2O5(0.03%~0.06%)特征,铝饱和指数为0.97~0.98,富集Rb、Th、U和Pb,明显亏损Ba、Nb、Ta、Sr、P、Ti和Eu等,属准铝质高分异I型花岗岩类;其中的黑云母具有高Al2O3(9.87%~10.92%)、高MgO(13.38%~14.64%)、高F(0.56%~1.11%)和高Cl(0.07%~0.12%)特征,Mg#为0.61~0.63,属镁质黑云母,黑云母源区为壳幔混合源。研究认为,该区花岗斑岩可能为甲玛矿区浅部埃达克质二长花岗斑岩的岩浆经矿物结晶分异演化出高硅残余熔体,并以岩脉形式上侵就位,而残留在岩浆房的物质结晶形成似斑状二长花岗岩,二者构成互补的关系,即主体为似斑状二长花岗岩,补体为高分异花岗斑岩。  相似文献   

Petroleum isoprenoid hydrocarbons derived from catagenetic degradation of archaebacterial lipids     

J. Albaigés  J. Borbón  W. Walker 《Organic Geochemistry》1985,8(4):293-297

The three GC coeluting C₄₀ bis-phytanes with head-to-tail, tail-to-tail and head-to-head linkages considered to be archaebacterial markers, have been recognized in petroleum by enhanced mass-fragmentography. Supporting evidence has been obtained by the simultaneous occurrence of two C₂₁–C₂₄ series of isoprenoid and quasi-isoprenoid hydrocarbons that are supposedly formed during the catagenetic degradation of the isomeric C₄₀ isoprenoids. The C₂₁–C₂₄ quasi-isoprenoid hydrocarbons have been identified conclusively for the first time by comparison with authentic standards.  相似文献   

高表面活性矿物对Zn~(2+)的吸附机理及其环境意义     

吴平霄  廖宗文  毛小云 《矿物学报》2001,(3)

本文利用高表面活性矿物蒙脱石、蛭石、沸石在一定的介质条件下对Zn2 +进行吸附实验研究。蒙脱石和蛭石对Zn2 +的等温吸附线呈双“S”型 ,而沸石对Zn2 +的等温吸附线则呈“Langmuir”型。三种矿物对Zn2 +的吸附容量大小顺序为 :蒙脱石 >蛭石 >沸石。运用粉晶X射线衍射、红外光谱、差热及热重分析等技术对矿物及矿物吸附Zn2 +后的结构特征进行了研究。结果表明 ,蒙脱石吸附锌后其层间域中吸附锌大量水解形成新的物相 ,而蛭石与沸石吸附锌后水解很少。这为利用高表面活性矿物控制和治理环境污染及其可循环利用提供了理论依据。  相似文献   

Impact of root architecture on the erosion‐reducing potential of roots during concentrated flow     

S. De Baets  J. Poesen  A. Knapen  P. Galindo 《地球表面变化过程与地形》2007,32(9):1323-1345

Many studies focus on the effects of vegetation cover on water erosion rates, whereas little attention has been paid to the effects of the below ground biomass. Recent research indicates that roots can reduce concentrated flow erosion rates significantly. In order to predict this root effect more accurately, this experimental study aims at gaining more insight into the importance of root architecture, soil and flow characteristics to the erosion‐reducing potential of roots during concentrated flow. Treatments were (1) bare, (2) grass (representing a fine‐branched root system), (3) carrots (representing a tap root system) and (4) carrots and fine‐branched weeds (representing both tap and fine‐branched roots). The soil types tested were a sandy loam and a silt loam. For each treatment, root density, root length density and mean root diameter (D) were assessed. Relative soil detachment rates and mean bottom flow shear stress were calculated. The results indicate that tap roots reduce the erosion rates to a lesser extent compared with fine‐branched roots. Different relationships linking relative soil detachment rate with root density could be established for different root diameter classes. Carrots with very fine roots (D < 5 mm) show a similar negative exponential relationship between root density and relative soil detachment rate to grass roots. With increasing root diameter (5 < D < 15 mm) the erosion‐reducing effect of carrot type roots becomes less pronounced. Additionally, an equation estimating the erosion‐reducing potential of root systems containing both tap roots and fine‐branched roots could be established. Moreover, the erosion‐reducing potential of grass roots is less pronounced for a sandy loam soil compared with a silt loam soil and a larger erosion‐reducing potential for both grass and carrot roots was found for initially wet soils. For carrots grown on a sandy loam soil, the erosion‐reducing effect of roots decreases with increasing flow shear stress. For grasses, grown on both soil types, no significant differences could be found according to flow shear stress. The erosion‐reducing effect of roots during concentrated flow is much more pronounced than suggested in previous studies dealing with interrill and rill erosion. Root density and root diameter explain the observed erosion rates during concentrated flow well for the different soil types tested. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

Preissmann隐式格式在分汊和环状河道中的应用   总被引：1，自引：0，他引：1       下载免费PDF全文

雷正雄  蒋艳 《水科学进展》2001,12(4):485-490

环状河道在平原地区水系中非常常见,分汊河道也较常见,对这两种河道基于Preissmann格式的水流计算提出了可行的方法。对圣维南方程组进行离散后,用追赶法对各河道进行演算,由水量平衡原理对各结点进行计算,就可求得河道各断面的水流情况。用长江下游江阴至青龙港及杨林段河道的实例进行计算,取得了较为理想的效果。  相似文献   

Evolution mechanism of the western Pacific subtropical high   总被引：4，自引：0，他引：4  

曹杰  黄荣辉  谢应齐  陶云 《中国科学D辑(英文版)》2003,46(3):257-268

Ever since Charney et al.[1] studied the multiple equilibrium states in atmosphere with highly truncated spectral method in 1979, many Chinese researchers, such as Li Maicun et al. (1983)[2], Liu Chongjian et al. (1983)[3], Miu Jinhai et al. (1985)[4] and…  相似文献