排序方式： 共有32条查询结果，搜索用时 140 毫秒
1.
高温密闭溶样电感耦合等离子体质谱准确测定辉钼矿铼-锇地质年龄 总被引：176，自引：28，他引：176
采用Carius管高温密闭溶样,电感耦合等离子体质谱(ICP MS)法对采自两个不同金属矿床的辉钼矿样品的Re Os同位素地质年龄进行了准确测定。所得出的Re Os年龄的平均值分别为14.26±0.19Ma和34.39±0.81Ma,相对标准偏差分别为1.3%(以2s计算,n=6)和2.4%(以2s计算,n=7)。采用国际通用的ISOPLOT软件按Model1模式对这两组样品分别进行处理,所得Re Os等时线年龄分别为14.32±0.46Ma和34.52±0.38Ma(均为95%置信水平)。同批次样品中所带的内部管理样JDC的Re Os年龄与国际先进实验室采用负离子热表面电离质谱测量所得的结果吻合也较好。说明在严格的质量体系保证及有效地降低实验室空白水平的前提下,ICP MS完全可以准确地测定辉钼矿的Re Os年龄。 相似文献
2.
锇粉中杂质元素分析方法研究 总被引：2，自引：0，他引：2
利用ＩＣＰ＿ＭＳ技术建立了锇粉中痕量杂质元素的分析方法。在浓ＨＮＯ３介质中，锇以ＯｓＯ４形式挥发除去，分离锇基体后，可直接测定的痕量元素达５０余种。取样量０．１ｇ，测定限为０．２～２４６ｎｇ／ｇ，可实现质量分数ｗ（Ｏｓ）为９９．９９９９％锇粉中杂质元素测定。结合ＩＣＰ＿ＡＥＳ测定Ｋ、Ｎａ、Ｃａ、Ｍｇ、Ａｌ、Ｆｅ、Ｓｉ和Ｐ，可实现锇粉原料及产品的纯度分析。 相似文献
3.
催化光度法测定痕量锇 总被引：3，自引：0，他引：3
在０５ｍｏｌ／Ｌ的Ｈ２ＳＯ４介质中，Ａｓ（Ⅲ）存在下，Ｏｓ（Ⅷ）催化ＫＣｌＯ３氧化邻苯二酚紫褪色反应。反应受温度、反应时间影响，冷却及加入抗坏血酸可终止反应。据此，建立了一个测定痕量Ｏｓ（Ⅷ）的新方法。方法的灵敏度为２５７×１０－１０ｇ／ＬＯｓ（Ⅷ），测定范围为０～００９１μｇ／Ｌ，用地质管理样中锇的测定验证，结果与原结果相符 相似文献
4.
Osmium-strontium-neodymium-lead isotopic covariations in mid-ocean ridge basalt glasses and the heterogeneity of the upper mantle 总被引：4，自引：0，他引：4
Pierre Schiano Jean-Louis Birck Claude J. Allgre 《Earth and Planetary Science Letters》1997,150(3-4):363-379
Osmium, strontium, neodymium, and lead isotopic data have been obtained for 30 hand picked samples of basaltic glass from the Pacific, Atlantic and Indian mid-oceanic ridges. Large variations in Os isotopic ratios exist in the glasses, from abyssal peridotite-like values to radiogenic compositions similar to oceanic island basalts (187Os/186Os and 187Os/188Os ratios range from 1.06 to 1.36 and from 0.128 to 0.163, respectively). Os isotopic and elemental data suggest the existence of mixing correlations. This relationship might be ascribed to secondary contamination processes; however, such a hypothesis cannot account for the negative correlation observed between Os and Nd isotopes and the existence of complementary covariations between Os and SrPb isotopes. In this case, OsSrNdPb isotopic variations are unrelated to late post-eruption or shallow level contamination. These relationships provide strong evidence that the Os isotopic composition of the samples are derived from the mantle and thus implies a global chemical heterogeneity of the oceanic upper mantle. The results are consistent with the presence of recycled oceanic crust in the mantle sources of mid-ocean ridge basalts, and indicate that the unique composition of the upper mantle below the Indian ocean results from its contamination by a mantle component characterized by radiogenic Os and particularly unradiogenic Nd and Pb isotopic compositions. 相似文献
5.
A suite of pyroxenites from the Beni Bousera peridotite massif,northern Morocco, have been analysed for Re–Os and Lu–Hfisotopic compositions. Measured sections of the massif indicatethat pyroxenite layers make up between 1 and 9% by volume ofthe total outcrop. Clinopyroxenes from two Cr-diopside pyroxeniteshave unradiogenic Hf isotope compositions ( 相似文献
6.
铼—锇同位素分析中试样化学预处理方法进展 总被引：4，自引：0，他引：4
评述了用于Re-Os同位素体系分析的化学前处理技术的发展。简要介绍了卡洛斯管熔样法、Os的CCl4提取、溴提取和微蒸馏方法。卡洛斯管封闭熔样方法，有效地防止了Os的挥发损失和保证了Os同位素平衡，是一种很有发展前景的熔样方法。蒸馏法仍是分离和纯化Os的有效方法，溶剂（CCl4)提取和溴提取法在许多实验室里应用，而微蒸馏则是Os的二次纯化的主要方法。Re的化学分离和纯化仍是离子交换和萃取法。引用主要文献29篇。 相似文献
7.
Ilia Rodushkin Emma Engström Douglas C. Baxter 《Geostandards and Geoanalytical Research》2007,31(1):27-38
The analytical performance of a method for Os isotope ratio measurement by double‐focusing, sector field ICP‐MS (ICP‐SFMS) was evaluated. The method is based on several optimised, concurrent processes: Os extraction from samples in hot concentrated nitric acid; separation of Os from the digest solution by the formation of volatile osmium tetroxide accelerated by continuous hydrogen peroxide addition; transport of analyte vapour by an oxygen flow into the ICP; and isotopic determination by ICP‐SFMS. Due to the very efficient utilisation of analyte (approaching 0.5‰), Os isotope ratio measurement could be performed at low pg levels. Combined with an ability to process sample sizes up to 2 g (up to 50 g if the organic matrix of biological or botanical samples is eliminated by ashing), materials with Os concentrations in the low, or even sub pg g?1 range could be determined by this method. Given that two complete digestion/distillation systems were available for interchangeable use, throughputs of up to fifteen samples per 8 hour shift could be achieved. The method precision, evaluated as the long‐term reproducibility of 187 Os/188Os ratio measurements in a commercial Os reference sample containing 0.5 ng Os, was 0.16% relative standard deviation (RSD, 1s). The method has been applied to perform replicate 187 Os/188 Os ratio measurements on a suite of fifty reference materials of various origins and matrix compositions, with Os concentrations varying from < 0.1 pg g?1 to > 100 ng g?1, yielding an average precision of 3% RSD. Though none of the materials tested are certified for Os content or Os isotope composition, comparison of the obtained data with published Os isotope information for similar sample types revealed close agreement between the two. The method can also be used for the simultaneous, semi‐quantitative determination of Os concentrations. 相似文献
8.
金川铜镍硫化物样品中锇同位素比值的高精度分析 总被引：11，自引：2，他引：9
采用两种独立的190Os稀释剂、4个不同的化学流程,用等离子体质谱仪、TRITON热表面电离质谱仪和MAT-262固体质谱仪3种质谱仪器,在4个实验室分别对采自金川铜镍硫化物样品的187Os/188Os同位素比值进行分析,样品分析数量达到56个。4个实验室获得的结果分别为0.3356±0.0018(n=12,2s)、0.3363±0.0008(n=6,2s)、0.3363±0.0010(n=18,2s)和0.3353±0.0034(n=20,2s)。采用ISOPLOT软件对所得56个数据进行加权平均计算,得到187Os/188Os同位素比值为0.33602±0.00022(置信度95%)。两台TRITON热表面电离质谱仪测量的结果几乎完全一致,且精度高于MAT-262固体质谱仪和等离子体质谱仪。比较了碱熔和Carius管两种溶样方法,结果表明,对于所研究的样品,用Carius管溶矿方式可以将含锇矿物完全溶解。 相似文献
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10.
Os同位素地层法可以得到包含生长间断期的分辨率较高的结壳年代框架,相对传统定年方法具有更优的发展前景.在比对多金属结壳分层Os同位素组成曲线与大洋海水标准曲线从而为多金属结壳定年的同时,研究标准曲线的区域性特征及其与壳源、幔源物质供应的关系.依据比值和趋势贴合原则,得到的多金属结壳生长期包括80~75 Ma、70~65 Ma、60~50 Ma、42~40 Ma、35~28 Ma、15~10 Ma、8~0 Ma.在中、西太平洋地区,麦哲伦和马绍尔海山区结壳Os同位素组成测定值与标准曲线形态和取值贴合良好,而马尔库斯威克和莱恩海山区结壳测定值虽与标准曲线趋势较为贴合,但分别在7 Ma以来和33 Ma以前相对标准曲线取值异常偏高.这种异常偏高现象的出现与2个海山区进、出盛行西风带和赤道信风带的过程有关,结壳在处于风带时接收到风力输运的美洲和亚洲陆源风尘物质,使得其记录的Os同位素组成相对标准曲线偏高. 相似文献