Origin of Oils in “Subtle pools” in the Dongying Depression, Bohai Bay Basin, China     

Li Sumei  Jiang Zhengxue  Liu Keyu  Qiu Guiqiang  Gao Yongjin 《《地质学报》英文版》2008,82(1):184-196

Subtle traps or oil pools have become an important exploration play in the Dongying Depression, Bohai Bay Basin, east China. Despite recent successes in exploration, the formation mechanisms of subtle traps are still not well understood. The majority of subtle oil pools in the Dongying Depression are developed in the middle interval of the Es3 Member of the Paleogene Shahejie Formation with the subtle traps being primarily of lenticular basin-floor turbidite sands encompassed in mudstones. Oil in the subtle traps was previously thought to have migrated directly from the surrounding source rocks of the same formation （Es3）. Detailed geochemical investigation of 41 oils and 41 rock samples from the depression now indicates that the oils from the subtle traps cannot be correlated well with the surrounding Es3 source rocks, which are characterized by high Pr/ Ph （〉1）, low Gammacerane/C30hopane, representing a freshwater lacustrine setting. In contrast the oils features low Pr/Ph （〈1） and relatively high Gammacerane content, showing a genetic affinity with the underlying Es4 source rocks, which also have the same qualities, indicating a brackish lacustrine setting. Oils in the Es3 subtle traps are probably derived from mixed sources with the contribution from the upper Es4 source rocks predominating. Therefore unconventional oil migration and accumulation mechanisms need to be invoked to explain the pooling of oils from the ES4 source rocks, which probably came through a thick low interval of the Es3 source rocks with no apparent structural or stratigraphic pathways. We suggest that the subtle oil migration pathway probably plays an important role here. This finding may have significant implications for future exploration and the remaining resource evaluation in the Dongying Depression.  相似文献   

The Glarus thrust: excursion guide and report of a field trip of the Swiss Tectonic Studies Group (Swiss Geological Society, 14.–16. 09. 2006)     

Marco Herwegh  Jean-Pierre Hürzeler  O. Adrian Pfiffner  Stefan M. Schmid  Rainer Abart  Andreas Ebert 《Swiss Journal of Geoscience》2008,101(2):323-340

This excursion guide results form a field trip to the Glarus nappe complex organized by the Swiss Tectonic Studies Group in 2006. The aim of the excursion was to discuss old and recent concepts related to the evolution of the Glarus thrust. The major aspects were (i) the interplay between deformation, fluid flow and geochemical alteration, (ii) episodic versus continuous deformation and fluid flow, and (iii) the link between large-scale structures, microstructures, and geochemical aspects. Despite 150 years of research in the Glarus nappe complex and the new results discussed during the excursion, there exist controversies that still are unsolved.  相似文献   

Quantification of the risk associated with high levels of mercury pollution at Temirtau, Kazakhstan     

Huiwen HSIAO Susanne M. Ullrich Trevor W. Tanton 《中国地球化学学报》2006,25(B08):233-233

This research aims to establish the risks of hurnan exposure to modeling approach. The study site was located on the River Nura 1990s, an acetaldehyde production plant located in the industrial high environmental mercury levels, based on a quantitative risk in central Kazakhstan. From the 1950s until its closure in the mid city of Temirtau released mercury-containing wastewater into the river. River sediments are highly contaminated with mercury up to a distance of 25 km and beyond. In addition, a local power station released an estimated 6 million tonnes of fly-ash into the water and the mercury has become quite tightly associated with the ash deposits. River water, fish and agricultural land in the floodplain are also contaminated with mercury, yet the risks posed to the local population have not been evaluated to date. In June and July 2005, we took samples of soil, interior and exterior dust, drinking water, and food from individual households, communal areas and markets. Additionally, water and sediment samples and fish were taken from the river. Interviews were conducted with householders to establish their age and body weight, general living conditions and sources of irrigation and drinking water. A food frequency questionnaire （FFQ） was designed to investigate the frequencies of consumption of several common regional food items, including fish from the fiver and/or local market. Human hair samples were also collected to estimate the mercury bioburden and to enable the validity of the modeling approach to be established. The paper expands on the main pathways of contamination and looks at linkages between exposure pathways and mercury concentrations found in human hair. Uncertainties inherent in risk analysis as well as their influence on the relative importance of different exposure routes are also discussed.  相似文献   

油气成藏机理研究进展和前沿研究领域   总被引：23，自引：7，他引：23  

郝芳  邹华耀  王敏芳  杨旭升 《地质科技情报》2002,21(4):7-14

随着地质工作者刻划和认识地下地质体构成、结构的能力及研究和预测沉积盆地能量场（温度场、压力场和应力场）及其演化能力的不断提高，以流体流动和油气运移为核心的油气成藏机理研究取得了重要进展：（1）证实了油气的优势通道运移并妆步提示了优势运移通道的微观和宏观控制机制，从而使基于油气运移路径三维预测的油气藏定位预测成为可能；（2）证实了幕式快速成藏过程并初步揭示了幕式成藏的驱动机制、有利场所和地球化学识别标志，突破了油气成藏是一个缓慢渗流过程的传统模式；（3）深盆气勘探和成藏机理研究取得了进展，从而突破了背斜成藏的传统观念，使“向斜”（盆地凹陷区）成为一些盆地寻找大型天然气藏的重要场所。沉积盆地深层油气成藏过程和保存条件、活动构造背景下油气晚期快速成藏过程是油气成藏机理研究的重要前沿研究领域。  相似文献   

柴达木盆地三湖地区第四系生物气的形成途径与运聚方式   总被引：22，自引：1，他引：22  

张晓宝  徐自远  段毅  马立元  孟自芳  周世新  贺鹏 《地质论评》2003,49(2):168-174

柴达木盆地三湖(台吉乃尔湖、涩聂湖、达布逊湖)地区第四系生物气区是我国最大的生物气区。笔者系统采集了该气区21个天然气样品,测量了其组分和碳同位素组成,重点探讨了生物气形成途径和运聚方式。生物气δ~(13)C_1和δ~(13)C_(CO_2)均随深度增大而变重,显示了CO_2还原途径成气的特征。生物气δ~(13)C_1、δ~(13)C_(CO_2)和δD分布与CO_2还原方式形成的生物气的相应同位素值分布范围接近。在有关成因图解中这些数据主要位于CO_2还原途径成气范围内。生物气CO_2和CH_4之间的碳同位素分馏系数α_c>1.055,具有CO_2还原途径成气的特征。柴达木盆地第四纪干旱的古气候、较低的古温度、较高的沉积速率和水体中较高的硫酸盐含量使得甲烷菌的大量繁殖只能在较大的深度范围内才能实现,从而,有利于CO_2还原途径成气作用进行。涩北一号、涩北二号气田生物气δ~(13)C_1组成分布可能表明,生物气形成以后沿疏导层水平运移进入气藏,基本不存在垂向运移。该项研究对于进一步深入探讨生物气成因、形成条件,确定生物气模拟实验方式与条件,计算生物气资源量,建立成藏模式和选择天然气有利勘探区块均具有重要价值。  相似文献   

An Algorithm for the Determination of All Significant Pathways in Chemical Reaction Systems     

Ralph Lehmann 《Journal of Atmospheric Chemistry》2004,47(1):45-78

When the output of a complex chemical model is analysed, a typical topic isthe determination of pathways, i.e., reaction sequences, that produce ordestroy a chemical species of interest.A representative example is the investigation of catalytic ozone destruction cycles in the stratosphere.An algorithm for the automatic determination of pathways in any given reactionsystem is presented. Under the assumption that reaction rates are known, it finds all significant pathways, i.e., all pathways with a rate above a prescribed threshold.The algorithm forms pathways step by step, starting from single reactions.The chemical species in the system are consecutively considered as `branching points'.For every branching-point species, each pathway producing it is connected witheach pathway consuming it.Rates proportional to `branching probabilities' are calculated.Pathways with a rate that is smaller than a prescribed threshold arediscarded.If a newly formed pathway contains sub-pathways, e.g., null cycles, it is split into these simpler pathways.In order to demonstrate the performance of the algorithm, it has been applied to the determination of catalytic ozone destruction cycles and methaneoxidation pathways in the stratosphere.  相似文献   

上海中心城就业中心体系测度————基于手机信令数据的研究   总被引：17，自引：2，他引：15  

丁亮  钮心毅  宋小冬 《地理学报》2016,71(3):484-499

利用手机信令数据识别上海市域内手机用户的工作地和居住地,获取就业者的通勤数据,测度上海中心城的就业中心体系.首先用就业者工作地数据生成就业密度分布图,基于中心城的就业密度识别就业中心.随后,用就业者工作地和居住地数据分别从就业密度和通勤联系两方面测度各中心的能级,分析各中心的腹地和势力范围.研究发现:① 上海中心城的就业中心呈主中心强大的弱多中心体系;② 就业密度越高的中心与其他地区的通勤联系一般也越强,但通勤联系在各中心间的差异更显著;③ 能级越高的中心腹地面积越大,但势力范围不一定越大;④ 相比于能级,职住功能混合度对职住平衡的影响更大;⑤缺少就业中心的地区势力范围呈交替状.本研究一定程度上能有助于解决既往就业中心体系研究因空间单元较大,缺少通勤数据在中心识别,通勤联系测度等方面受到的局限,希望能为构建上海中心城就业多中心体系提供帮助.  相似文献   

Manganese in runoff from upland catchments: temporal patterns and controls on mobilization / Teneur en manganèse de l'écoulement en bassins versants d'altitude: variations temporelles et contrôles de la mobilisation     

K. V. HEAL  P. E. KNEALE  A. T. McDONALD 《水文科学杂志》2013,58(5):769-780

Abstract

Knowledge of the hydrochemical dynamics of the trace metal manganese (Mn) in upland catchments is required for water quality management. Stream water Mn and other solutes and flow were monitored in two upland catchments in northern England with different soils: one dominated by peat (HS7), the other by mineral soils (HS4). Maximum Mn concentrations occurred at different times in the two catchments: in summer baseflow at HS4 and during late summer storm events at HS7. A two-component chemical mixing model was used to identify the hydrological processes controlling Mn concentrations in stream water. This approach was more successful for HS4 than HS7, probably because of different processes of Mn release in the two catchments and also difficulties in selecting conservative solutes. Factor analysis of the stream water chemistry data set for each catchment was more useful in identifying the controls on Mn release into runoff. The factors indicate that the main source of Mn at HS4 is the hydrological pathway supplying summer baseflow, whereas at HS7 Mn is released during the rewetting of dried peat soils. Manganese concentrations in stream water in upland catchments appear to depend on soil type and antecedent moisture conditions. This has implications for the design of sampling strategies in upland catchments and also for managing the quality of water supplies from such areas.  相似文献   

塔里木盆地轮南地区油气运移的路径、期次及方向研究   总被引：9，自引：3，他引：9       下载免费PDF全文

周凤英  孙玉善等 《地质论评》2001,47(3):329-335

本文通过对塔里木盆地轮南地区及附近的钻井（出油井和未出油井）中揭示的裂缝，裂缝与成岩序列的穿插关系，连通砂体及断层和不整合面附近的矿物及矿物中流体包裹体研究，对塔里木盆地轮南地区油气运移路径和期次进行了探讨。通过研究指出了塔里木盆地轮南地区主要经历了3期大规模的油气运聚，地层之间的不整合面为油气横向运移的主要通道。高角度的裂隙及微裂缝为纵向运移主要通道。第一期油气运聚主要发生于海西期，第二期油气运聚主要发生在14－17Ma；第3期油气运聚主要发生在最近的5Ma以来。第一期油气运聚主要为自塔北隆起的西南，南向北，以横向运移为主；第二，第三期运聚主要自西南，南向北，自东向西运移，但主要以垂向运移为主。  相似文献   

Relationship between structures of substituted indolic compounds and their degradation by marine anaerobic microorganisms   总被引：1，自引：0，他引：1  

Gu JD  Fan Y  Shi H 《Marine pollution bulletin》2002,45(1-12):379-384

Degradation of selected indolic compounds including indole, 1-methylindole, 2-methylindole, and 3-methylindole was assessed under methanogenic and sulfate-reducing conditions using the serum-bottle anaerobic technique and marine sediment from Victoria Harbour, Hong Kong as an inoculum. Our results showed that indole degradation was achieved in 28 days by a methanogenic consortium and 35 days by a sulfate-reducing consortium. During degradation under both conditions, two intermediates were isolated, purified and identified as oxindole and isatin (indole-2,3-dione) suggesting that both methanogenic and sulfate-reducing bacteria use an identical degradation pathway. Degradation processes followed two steps of oxidation accomplished by hydroxylation and then dehydrogenation at 2- and then 3-position sequentially prior to the cleavage of the pyrrole ring between 2- and 3-positions. However, none of 1-methylindole or 2-methylindole was degraded under any conditions. 3-Methylindole (3-methyl-1H-indole, skatole) was transformed under methanogenic conditions and mineralized only under sulfate-reducing conditions. It is clear that methyl substitution on 1- or 2-position inhibits the initial attack by hydroxylation enzymes making them more persistent in the environment and posing longer toxic impact.  相似文献