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1.
The effects on ethoxyresorufin O-deethylase (EROD), NADPH-cytochrome c reductase and NADH cytochrorne b5 reductase activities of digestive gland in Meretrix meretrix exposed to tributyltin (TBT) at environmental levels (0.1,1.0,10.0 ng/dm as stannum concentration),in experimental condition, were evaluated. The EROD, NADH cytochrorne b5 reductase activities were significantly inhibited after exposure to 10.0 ng/dm^3 TBT for 8 and 20 d, the NADPH cytochrorne c reductase activities were significantly inhibited after exposure to 0.1,1.0 and 10.0 ng/dm TBT for 8 d and to 1.0 and 10.0 ng/dm for 20 d, as compared with the matched control, while NADH cytochrorne b5 reductases and NADPH cytochrome c reductase activities were induced after exposure to 10.0 ng/dm^3 TBT for 2 d. The EROD activity in the 10 ng/dm^3 group,and the NADH cytochrome b5 reductases activities in 1.0 and 10.0 ng/dm groups, were significantly induced when transferred to clean recovery tanks for 7 d. The three enzymic activities in the clams exposed to TBT were recovered to the level corresponding to that of the control group after transfer to clean recovery tanks for 20 d. NADPH cytochrome c reductase activity in Meretrix meretrix seems to be more sensitive to exposure of TBT than that of the EROD and NADH cytochrome b5 reductases. The results suggest that induction and inhibition by TBT to the monooxygenase system enzymic activity in Meretrix meretrix would simultaneously exist. The enzymic activities were inhibited by exposure for a long time. The results suggest that inhibition of the monooxygenase system should be an indication of the exposure to environmentally relevant concentrations of TBT for a long time.  相似文献   
2.
A risk assessment of Tributyltin (TBT) in Tokyo Bay was conducted using the Margin of Exposure (MOE) method at the species level using the Japanese short-neck clam, Ruditapes philippinarum. The assessment endpoint was defined to protect R. philippinarum in Tokyo Bay from TBT (growth effects). A No Observed Effect Concentration (NOEC) for this species with respect to growth reduction induced by TBT was estimated from experimental results published in the scientific literature. Sources of TBT in this study were assumed to be commercial vessels in harbors and navigation routes. Concentrations of TBT in Tokyo Bay were estimated using a three-dimensional hydrodynamic model, an ecosystem model and a chemical fate model. MOEs for this species were estimated for the years 1990, 2000, and 2007. Estimated MOEs for R. philippinarum for 1990, 2000, and 2007 were approximately 1–3, 10, and 100, respectively, indicating a declining temporal trend in the probability of adverse growth effects.A simplified software package called RAMTB was developed by incorporating the chemical fate model and the databases of seasonal flow fields and distributions of organic substances (phytoplankton and detritus) in Tokyo Bay, simulated by the hydrodynamic and ecological model, respectively.  相似文献   
3.
李张伟  韩雅莉  李平 《海洋科学》2007,31(12):38-42
检测了受三丁基锡(tributyltin,TBT)污染的牡蛎的吞噬细胞活力、超氧化物歧化酶活性、过氧化氢酶活性、脂质过氧化作用等生理生化指标。实验结果表明,牡蛎血细胞的吞噬活力随着TBT浓度的增加而下降;对不同TBT浓度下牡蛎的超氧化物歧化酶(SOD)和过氧化氢酶(CAT)活性测定发现,在较低浓度下(TBT质量浓度<10μg/L),SOD和CAT的酶活力被抑制,随着TBT浓度的增大,SOD和CAT的比活力也随着增大,但当TBT达到较高浓度时,SOD和CAT的比活力开始下降,而过氧化脂质(LPO)却随着TBT的浓度的增加而增大。  相似文献   
4.
This paper explores the effects of non-tariff measures (NTM) on extensive and intensive margins of global exports of seafood in 1996–2011. The main result of this study is the differential and opposite effect of SPS and TBT measures. While SPS measures largely increase extensive margins of export and reduce intensive margins, TBTs mostly reduce exports at extensive margins and increase exports at intensive margins. Specific trade concerns (STC) have larger effect on exports than SPS and TBT notifications, both economically and statistically. Finally, there is substantial heterogeneity of response of exports to NTMs across HS six digit product lines, but the central tendency remains the same as for aggregated data.  相似文献   
5.
Filter feeders such as bivalves are increasingly being shown to control phytoplankton blooms in eutrophic estuaries. The possibility of such a top-down effect on macroalgae, however, has not been considered previously even though most green tide algal species reproduce by pelagic swarmers that are equivalent to phytoplankton. This work presents circumstantial evidence from an oyster-culturing French embayment where, despite eutrophication since the mid-1970s, macroalgae did not proliferate until 1982. This was also the year when tributyltin pollution from antifouling paints dropped substantially following a world-wide prime ban that was implemented to save the shellfish industry. From the recorded evolution of the oyster stock, it is shown how tributyltin reduced the bivalve filter capacity within those years and resulted in Enteromorpha swarmers being much more likely to germinate and bloom. This suggests that the green tides had been successively contained by the biological activity and the chemical pressure. The effects of the latter on the former would thus have cascaded to ecosystem-level changes, and so the functional role of bivalves should be evaluated and preserved wherever relevant.  相似文献   
6.
Imposex, specifically caused by TBT pollution, refers to the superimposition of male sexual characteristics in gastropod females. Seasonal variation of imposex intensity in Thais clavigera from both slightly and severely contaminated sites in Hong Kong waters was studied from 1988 to 1999. The male penis length showed significant difference between both sites and seasons. It was shortest during late autumn and early winter (October to December) and longest during spring and early summer (February to June). Female penis length also showed significant difference between sites. It did not change seasonally, however. The RPS (Relative Penis Size) index was the highest during autumn and early winter, and the lowest during spring and early summer. The VDS (Vas Deferens Sequence) index remained stable throughout the sampling period. This study showed that VDS index is a better indicator when we compare relative intensity of imposex. The comparison can only be meaningful provided the samples from different locations are taken during the same season.  相似文献   
7.
海产腹足类有机锡化合物的检测方法   总被引:3,自引:0,他引:3  
黄长江  雷瓒  董巧香 《海洋学报》2005,27(4):174-180
三丁基锡(TBT)等有机锡化合物因其毒性及结构上的特点被广泛应用于船舶、网箱渔排等的防污涂料中.它的主要作用是在水体中持久地释放出可以有效杀死海洋污损生物的毒性物质,从而达到防护船舶、渔排等体表的目的[1],然而进入海洋环境的有机锡化合物在防污的同时也会影响到许多非靶生物,并对海洋生态系统的结构与功能产生严重的危害,被认为是迄今为止人为引入海洋环境毒性最大的物质之一[2~4].因此,检测海洋生物体内的有机锡含量成为对有机锡污染生态效应调查与研究不可缺少的手段[5~7].  相似文献   
8.
Benthic amphipod,Grandidierella japonica widely inhabits the Korean coastal waters and is developed as a standard test species for sediment toxicity tests. We exposedG . japonica to various pollutants including 4 kinds of inorganic metals (Ag, Cd, Cu and Hg), tributyltin [TBT], ammonia and 7 polycyclic aromatic hydrocarbon (PAH) compounds (acenaphthene, chrysene, fluoranthene, fluorene, naphthalene, phenanthrene and pyrene) to estimate the no observed effect concentration (NOEC) and the median lethal concentration (LC50) of each pollutant during the 96-hour acute exposure. Among all tested pollutants, TBT was most toxic toG. japonica, and Hg was most toxic among inorganic metals. The toxicity of pyrene toG. japonica was greatest among PAH compounds, followed by fluoranthene, phenanathrene, acenaphthene, fluorene and naphthalene. The toxicity of PAH compounds was closely related to their physico-chemical characteristics such as Kow and water solubility.G. japonica responded adequately to pollutant concentrations and exposure durations, and the sensitivity ofG. japonica to various inorganic and organic pollutants was generally comparable to other amphipods used as standard test species in ecotoxicological studies, indicating this species can be applied in the assessment of environments polluted by various harmful substances.  相似文献   
9.
In 1990, restrictions on the use of tributyltin (TBT)-based antifouling paints were implemented in Iceland. A previous study showed that the level of imposex in the dogwhelk, Nucella lapillus, in Icelandic waters had decreased significantly between 1992 and 1998. In this study, we repeated the survey on imposex in N. lapillus at 33 locations from the Icelandic coast in 2003. The results indicated that both Vas Deferens Sequence Index (VDSI) and Relative Penis Size Index (RPSI) had further declined in 13 locations since 1998. Among these 13 sites, RPSI was reduced to zero in five cases. While improvements from 1992/1993 to 1998 were seen in reduced levels of imposex near both large and small harbours, the pattern from 1998 to 2003 was somewhat different, with improvement mainly observed near smaller harbours. No significant changes in imposex levels near larger harbours occurred over this period. Although the imposex levels still remain high near the large harbour complexes in Reykjavík and Hafnarfjörður, it is evident that regulations, including the use of less toxic antifouling paints and community action, have lead to substantial improvements in the marine environment of Iceland. International Maritime Organisation’s ban on the application of TBT after 2003 is apparently necessary to allow further improvements in larger harbours. The environmental effects of new antifoulants replacing TBT need to be further evaluated.  相似文献   
10.
It is evident from measures of butyltin tissue burdens and imposex or intersex in neogastropods that tributyltin (TBT) contamination of coastal waters and open parts of the North Sea is now low. It has been declining for at least the past decade. This is probably due to two measures. First, regulations prohibiting the use of TBT-based paints on small boats and fish farms have reduced inputs of TBT from these sources so that they are now negligible (except possibly where the regulations are flaunted). Second, there is evidence from sites, where commercial vessels are the sole source of TBT, that the adoption of TBT SPC paints has been effective in reducing environmental levels of these contaminants. However, poor dockyard practices, allowing TBT-contaminated wastes, including paint flakes, to accumulate in sediments have left a legacy of hot-spots of contamination in some ports. The impact is localised so that TBT contamination is low in coastal areas immediately adjacent to ports.  相似文献   
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