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排序方式： 共有74条查询结果，搜索用时 15 毫秒
1.
百花湖是一个具有季节性分层的富营养小型湖泊,在秋季湖水倒转期经常发生水质恶化事件,碳氮循环出现异常。文章研究特选择在秋初,湖泊分层开始消失时,测定了湖水中不同深度的N2O,CH4,CO2,有机和无机碳同位素以及其他化学参数变化。结果发现:采样时百花湖在约6m和16m深度附近出现了两个温度不连续层(SDL和PDL),并影响到有机颗粒的沉降和分解。相对而言,有较多的有机质在这两个层内发生降解,但降解的途径有所不同,上部主要是有氧降解,下部则主要是无氧降解过程。N2O的产生和消耗与有机质的降解过程完全对应:PDL层以上,ΔN2O与AOU的线性关系反映了N2O主要形成于硝化作用;PDL层以下反硝化作用导致N2O严重不饱和;PDL内位于硝化作用和反硝化作用过渡带的N2O峰,显然是硝化与反硝化联合作用的结果。PDL层内较大的CH4浓度变化梯度,说明嗜甲烷细菌可能通过氧化NH+4贡献了部分N2O。百花湖秋、冬季表层湖水N2O都是过饱和的,都是大气N2O的源,依据分子扩散模型计算湖泊N2O的释放通量在12～14μmol/m·day之间,秋、冬季没有明显的差别。秋季底层湖水的反硝化作用是湖泊N2O的汇,其消耗通量与表层的释放通量基本相当。 相似文献
2.
Dissolved nitrous oxide (N2O) dynamics in agricultural field drains and headwater streams in an intensive arable catchment 
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下载免费PDF全文 Indirect nitrous oxide (N2O) emissions produced by nitrogen (N) leaching into surface water and groundwater bodies are poorly understood in comparison to direct N2O emissions from soils. In this study, dissolved N2O concentrations were measured weekly in both lowland headwater streams and subsurface agricultural field drain discharges over a 2‐year period (2013–2015) in an intensive arable catchment, Norfolk, UK. All field drain and stream water samples were found to have dissolved N2O concentrations higher than the water–air equilibrium concentration, illustrating that all sites were acting as a net source of N2O emissions to the atmosphere. Soil texture was found to significantly influence field drain N2O dynamics, with mean concentrations from drains in clay loam soils (5.3 μg N L?1) being greater than drains in sandy loam soils (4.0 μg N L?1). Soil texture also impacted upon the relationships between field drain N2O concentrations and other water quality parameters (pH, flow rate, and nitrate (NO3) and nitrite (NO2) concentrations), highlighting possible differences in N2O production mechanisms in different soil types. Catchment antecedent moisture conditions influenced the storm event mobilisation of N2O in both field drains and streams, with the greatest concentration increases recorded during precipitation events preceded by prolonged wet conditions. N2O concentrations also varied seasonally, with the lowest mean concentrations typically occurring during the summer months (JJA). Nitrogen fertiliser application rates and different soil inversion regimes were found to have no effect on dissolved N2O concentrations, whereas higher N2O concentrations recorded in field drains under a winter cover crop compared to fallow fields revealed cover crops are an ineffective greenhouse gas emission mitigation strategy. Overall, this study highlights the complex interactions governing the dynamics of dissolved N2O concentrations in field drains and headwater streams in a lowland intensive agricultural catchment. 相似文献
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In an attempt to reduce the threat of global warming, it has been proposed that the rise of atmospheric carbon dioxide concentrations be reduced by the ocean disposal of CO2 from the flue gases of fossil fuel-fired power plants. The release of large amounts of CO2 into mid or deep ocean waters will result in large plumes of acidified seawater with pH values ranging from 6 to 8. In an effort to determine whether these CO2-induced pH changes have any effect on marine nitrification processes, surficial (euphotic zone) and deep (aphotic zone) seawater samples were sparged with CO2 for varying time durations to achieve a specified pH reduction, and the rate of microbial ammonia oxidation was measured spectrophotometrically as a function of pH using an inhibitor technique. For both seawater samples taken from either the euphotic or aphotic zone, the nitrification rates dropped drastically with decreasing pH. Relative to nitrification rates in the original seawater at pH 8, nitrification rates were reduced by ca. 50% at pH 7 and more than 90% at pH 6.5. Nitrification was essentially completely inhibited at pH 6. These findings suggest that the disposal of CO2 into mid or deep oceans will most likely result in a drastic reduction of ammonia oxidation rates within the pH plume and the concomitant accumulation of ammonia instead of nitrate. It is unlikely that ammonia will reach the high concentration levels at which marine aquatic organisms are known to be negatively affected. However, if the ammonia-rich seawater from inside the pH plume is upwelled into the euphotic zone, it is likely that changes in phytoplankton abundance and community structure will occur. Finally, the large-scale inhibition of nitrification and the subsequent reduction of nitrite and nitrate concentrations could also result in a decrease of denitrification rates which, in turn, could lead to the buildup of nitrogen and unpredictable eutrophication phenomena. Clearly, more research on the environmental effects of ocean disposal of CO2 is needed to determine whether the potential costs related to marine ecosystem disturbance and disruption can be justified in terms of the perceived benefits that may be achieved by temporarily delaying global warming. 相似文献
5.
本实验基于一种新型的具有自洁功能的固定床生物滤器, 研究了不同的清洗频率: 0.5次/d (S1)、1次/d(S2)和2次/d(S3)对生物滤器的硝化性能、截污能力和硝酸盐氮积累的影响。研究表明: 清洗频率对生物滤器去除氨氮(NH4+-N)没有显著影响(P > 0.05); 在第6~9 d对生物滤器内亚硝酸盐氮(NO2–-N)的浓度有显著影响(P < 0.05), 第11 d后均无显著影响(P > 0.05); 在整个实验过程中, S3处理组与S1、S2处理组相比总固体悬浮物(TSS)去除分别提高53.52%和19.01%, 化学需氧量(CODMn)去除分别提高57.94%和27.01%, 差异性显著(P < 0.05); 在硝酸盐氮(NO3–-N)积累方面, S3处理组积累最少, 在整个实验过程期间与S1、S2处理组相比分别降低16.04%和23.01%, 差异性显著(P < 0.05)。总体来说, 高清洗频率对生物滤器的硝化性能无显著影响, 但能使生物滤器截留的TSS快速排出系统, 从而减少系统内的水处理负荷和硝酸盐氮积累, 有利于系统的长期稳定运行。 相似文献
6.
Tanveer Ferdous Saeed 《湿地科学》2012,10(2):142-148
This study investigated the effects of two alternative substrates(wood mulch and zeolite) on the performance of three laboratory-scale hybrid wetland systems that had identical system components and configurations.Each system consisted of a vertical flow(VF) wetland column,followed by a horizontal flow(HF) column and a vertical flow column.The substrates employed were wood mulch,gravel and zeolite,and Phragmites australis were planted in each column.The systems received synthetic wastewater,with pollutant loadings in the range of 8.5-38.0 g/(m2·d) total nitrogen(TN) and 4.0-46.4 g/(m2·d) biological oxygen demand(BOD5).Wood mulch and zeolite substrates showed higher efficiencies in terms of removing nitrogenous compounds and biodegradable organics.The supply of organic carbon from the organic mulch substrates enhanced denitrification,while adsorption of influent ammoniacal nitrogen(NH4-N) in zeolite played a major role in the removal of nitrogenous species in the wetland columns.Overall,the average percentage removals of TN and BOD5 reached >66% and >96% respectively,indicating stable performances by the hybrid wetland systems under the experimental loading ranges.Mathematical models were developed,based on the combination of Monod kinetics and continuously-stirred tank reactor(CSTR) flow patterns to describe the degradation of nitrogenous compounds.Predictions by the models closely matched the experimental data,indicating the validity and potential application of Monod kinetics in the modelling and design of treatment wetlands. 相似文献
7.
N2O是一种重要的温室气体,土壤是全球N2O的重要排放源。通过测定土壤源N2O中N、O同位素值,可以有效识别N2O的来源途径。本文采集了南极法尔兹半岛两个地点的海豹粪土（HS和GS）、阿德雷岛两个地点的企鹅粪土(AB和AF)以及东南极的帝企鹅粪土(DQ和DQT),在室内对所采集的样品分别在有氧和厌氧条件下进行冻融培养实验。结果表明：土壤在厌氧条件下比有氧条件下排放了更多的N2O。土壤排放的N2O与当地大气N2O相比普遍贫15N和18O。除DQT和HS外, δ15N和δ18O在有氧和厌氧培养下均呈现很好的正相关性。N2O排放量下降的同时伴随着培养瓶内剩余N2O中δ15N和δ18O 值的增加,证实N2O还原为N2的过程会引起重同位素富集。高的水分含量有利于土壤反硝化作用的进行,使释放的N2O气体富集重同位素;pH值也会影响N2O的同位素组成,低pH会引起δ15N值增加。 相似文献
8.
采用在模拟池塘中投放过硫酸氢钾复合物（KMPS）进行对比实验的方法,探究KMPS对养殖底质硝化作用的影响。通过对氨氮和亚硝态氮含量的检测,探究对不同时期氮素转化的影响,低频率高剂量投放组中的氨氮和亚硝态氮含量显著降低,而高频率低剂量组中氨氮和亚硝态氮的含量显著上升。高频率低剂量KMPS的投放使氨氧化古菌（AOA）和氨氧化细菌（AOB）丰度降低,而低频率高剂量KMPS的投放不会造成丰度降低,而且还表现出部分时期AOB丰度的上升。进一步对群落结构进行分析发现KMPS的投放使AOA群落中Nitrosopumilu属相对丰度降低,Nitrososphaera属的相对丰度上升,这种相对丰度的变化与KMPS的投放方式无关;但AOB群落受到KMPS投放方式的影响,低频率高剂量的KMPS投放下AOB群落优势属相对丰度显著提高。以上结果均说明低频率高剂量KMPS的投放起到了促进底质硝化作用的效果。同时,可为KMPS用于对虾养殖池塘底质改良开辟一个新的途径。 相似文献
9.
Nitrification is a key step in the global nitrogen cycle.Compared with autotrophic nitrification,heterotrophic nitrification remains poorly understood.In this study,Halomonas venusta MA-ZP17-13,isolated from seawater in shrimp aquaculture (Penaeus vannamei),could simultaneously undertake nitrification and denitrification.With the initial ammonium concentration at 100 mg/L,the maximum ammonium-nitrogen removal rate reached98.7%under the optimal conditions including C/N concentration ratio at 5.95,p H at 8.93,and Na Cl at 2.33%.The corresponding average removal rate was 1.37 mg/(L·h)(according to nitrogen) in 3 d at 11.2°C.By whole genome sequencing and analysis,nitrification-and denitrification-related genes were identified,including ammonia monooxygenase,nitrate reductase,nitrite reductase,nitric oxide dioxygenase and nitric oxide synthase;while no gene encoding hydroxylamine oxidase was identified,it implied the existence of a novel nitrification pathway from hydroxylamine to nitrate.These results indicate heterotrophic bacterium H.venusta MA-ZP17-13 can undertake simultaneous nitrification and denitrification at low temperature and has potential forNH_4~+-N/NH3-N removal in marine aquaculture systems. 相似文献
10.