运用3DEEMs及荧光偏振方法研究pH、离子强度及浓度效应对腐殖酸荧光光谱特性的影响   总被引：6，自引：0，他引：6  

梅毅  吴丰昌  王立英  白英臣 《地球化学》2008,37(2):165-173

利用三维荧光激发.发射光谱(3DEEMs)及荧光偏振法研究了3例腐殖酸和1例湖泊溶解有机物(DOM)在不同腐殖酸浓度、离子强度和pH条件下的荧光光谱特性.实验结果表明,随着浓度增大,各腐殖酸样的荧光强度增大,其中垃圾渗滤液腐殖酸和Pahokee泥炭腐殖酸的荧光峰出现红移.随着浓度进一步增大,腐殖酸的荧光偏振值增大,由此推断在此浓度范围内腐殖酸由于分子间的排斥作用使其构型出现伸展.离子强度增大导致腐殖酸及阿哈湖DOM的荧光强度降低.随着氯化钾(KCI)浓度增大,Fluka腐殖酸的荧光峰A蓝移,荧光峰B的荧光偏振值出现减小,推测是由于静电中和作用使其荧光基团发生卷曲造成的.离子强度对其余腐殖酸样和阿哈湖DOM的其他荧光特性没有明显的影响.总的来说,pH值的变化对腐殖酸和湖泊DOM的荧光特征的影响是很明显的.随着pH值增大,腐殖酸和湖泊DOM的荧光强度增强.而pH值减小时,Fluka腐殖酸和Pahokee泥炭腐殖酸的荧光峰(A峰)蓝移,当pH值降到5时,Fhka腐殖酸的荧光峰突然红移到最大,随后又继续蓝移;垃圾渗滤液腐殖酸和阿哈湖DOM的荧光峰位无明显的漂移.所有样品的荧光偏振值都减小(但阿哈湖DOM的A峰变化不大),但在pHi≤5时又增大,这种现象表明随着pH值降低,腐殖酸和湖泊DOM中有机大分子发生卷曲,但在pH≤5时由于羧基的质子化又以平面伸展构型出现在溶液中.  相似文献   

An improved multiple-frequency method for measuring in situ target strengths     

Conti  Stephane G.; Demer  David A.; Soule  Michael A.; Conti  Jean H.E. 《ICES Journal of Marine Science》2005,62(8):1636-1646

  相似文献   

三维斜压模式对冬季南海环流的数值计算   总被引：7，自引：0，他引：7  

游小宝  李荣凤  张铭  曾庆存 《海洋学报》2001,23(6):1-10

用一个三维、自由表面、原始方程模式对南海环流进行了计算.计算结果表明:黑潮在巴士海峡以西呈一反气旋弯曲流动路径,有一相对高温高盐的水舌从巴士海峡伸入南海,表明有部分黑潮水侵入南海.冬季南海的一些观测事实在模式结果里得到了很好的反映,像冬季逆风向东北方向流动的“南海暖流”和一些中尺度涡旋.同时还分析了巴士海峡沿120.75°E断面的流速和盐度的垂直结构,并同观测结果进行了比较.根据模式结果,我们还进一步讨论了“南海暖流”的形成和驱动机制.  相似文献   

北部湾三维潮流场数值研究(英文)     

刘学刚  叶安乐 《中国海洋大学学报(自然科学版)》1988,(4)

本文对北部湾三维潮波进行了数值研究,并将所得结果与现有观测资料作了比较。通过比较发现两者相当一致。文中还绘制了M_2和K_1分潮的同潮图,并对其作了讨论。可以断定,北部湾的日潮优势是由日潮共振所引起的。M_2和K_1分潮流的水平分布表明,强流区位于它们各自的蜕化无潮点附近。还讨论了分潮流的铅直结构,可以看出这种结构十分接近实际分潮流场的特征。  相似文献   

ECOMSED模式在杭州湾海域流场模拟中的应用   总被引：13，自引：0，他引：13       下载免费PDF全文

堵盘军  胡克林  孔亚珍  丁平兴 《海洋学报》2007,29(1):7-16

针对杭州湾独特的喇叭型强潮河口湾的特点,基于Blumberg等(1996)的ECOMSED模式,引入动边界技术,建立杭州湾三维动边界的潮流模型.模型以正交曲线坐标下三维非线性水动力方程为基本方程,应用Mellor和Yamada的2.5阶湍流闭合模型计算紊动黏滞系数,嵌入Grant和Madsen的底边界层模型考虑波浪对底部应力的作用,采用干湿网格法模拟潮流漫滩过程;综合考虑径流,风应力,密度流和M₂,S₂,K₁,O₁四个主要分潮和M₄,S₄,MS₄三个浅水分潮的作用,从而提高杭州湾潮流模拟的精度.通过验潮站调和常数和多次海流连续观测资料的验证,表明该文建立的模型可以更好的用于杭州湾流场的预报模拟.  相似文献   

珠江河口西南风强迫下潮流场的数值模拟   总被引：1，自引：0，他引：1  

包芸  任杰 《海洋通报》2003,22(4):8-14

采用Backhaus三维斜压模型模拟了均匀西南风场对珠江口近岸海域的影响，并与无风情况作了对比；通过对珠江河口盐度场及风生环流的分析比较，结果表明，模型较为真实地再现了夏季珠江河口的水动力学特性。  相似文献   

Determining the age of water and long-term transport timescale of the Chesapeake Bay   总被引：5，自引：0，他引：5  

Jian Shen  Harry V. Wang 《Estuarine, Coastal and Shelf Science》2007,74(4):585-598

The concept of age of water (AW) is applied to the Chesapeake Bay to investigate the long-term transport properties for dissolved substances. A real-time calibrated hydrodynamic Chesapeake Bay model in 3 Dimensions (CH3D), employing a boundary-fitted curvilinear grid, is used for the study. The long-term transport properties, represented by AW, are investigated under the conditions of low river inflow of 1995 and high river inflow of 1996, as well as for constant mean inflows. The influences of freshwater, density-induced circulation, and wind-induced transport on age distribution have been investigated. Model results show that river inflows, wind stress, and density-induced circulation play important roles in controlling the long-term transport in the Bay. The model results shows that it requires 120–300 days for a marked change in the characteristics of the pollutant source discharged into the Bay from the Susquehanna River to affect significantly the conditions near the mouth under different hydrodynamic conditions. An increase of river discharge results in increases of downstream residual current and gravitational circulation, and thus reduces AW. The density-induced circulation contributes to the transport substantially. The dissolved substances discharged into the Bay are transported out of the Bay more rapidly when the estuary becomes more stratified. Southeasterly and southwesterly winds have strong impacts on the transport compared to the northeasterly and northwesterly winds. The former increases lateral and vertical mixing significantly. Consequently, the gravitational circulation is reduced and the transport time is increased by 50%. The model results provide useful information for understanding the long-term transport processes in the Bay.  相似文献   

基于ArcEngine的虚拟校园信息管理系统的设计与实现     

王志恒  杨国东  吴琼  于小平  洪德发 《测绘软科学研究》2008,(3)

阐述基于组件式GIS的开发方式,结合3维建模技术、数据库技术开发虚拟校园信息管理系统的基本思路,重点研究了3维模型的入库方法,以及基于GeoDatabase的数据库设计。以VirtualCampus系统开发为例,介绍了利用Visual C++与ArcEngine开发虚拟校园信息管理系统的方法。  相似文献   

高精度煤炭三维地震勘探技术   总被引：1，自引：0，他引：1  

武喜尊 《物探与化探》2008,32(1):23-27

介绍了中国煤炭地震勘探技术的现状及所面临的问题,分析了煤炭三维地震勘探技术今后应努力研究和须重点关注的几个问题,如频率的问题,小面元高密度采集问题,加强叠前研究工作问题,及单点地震技术应用问题,从而实现高精度勘探的目的,满足煤矿生产、建设、安全等日益增长的需要。  相似文献   

The 3D simulation and optimized management model of groundwater systems based on eco-environmental water demand     

Zhang Guang-xin Ph.D.  Deng Wei  He Yan 《地理学报(英文版)》2002,12(2):226-235

Through the study of mutual process between groundwater systems and eco-environmental water demand, the eco-environmental water demand is brought into groundwater systems model as the important water consumption item and unification of groundwater’s economic, environmental and ecological functions were taken into account. Based on eco-environmental water demand at Da’an in Jilin province, a three-dimensional simulation and optimized management model of groundwater systems was established. All water balance components of groundwater systems in 1998 and 1999 were simulated with this model and the best optimal exploitation scheme of groundwater systems in 2000 was determined, so that groundwater resource was efficiently utilized and good economic, ecologic and social benefits were obtained.  相似文献