An icy satellite whose interior is composed of a homogeneous ice/rock mixture must avoid melting during its entire history, including during its formation when it was heated by deposition of accretional energy and short-lived radioisotopes. Estimates of the temperature rise associated with radiogenic and accretional heating, coupled with limits on satellite melting can be used to constrain the timing of formation of a partially differentiated satellite relative to the origin of the calcium-aluminum-rich inclusions (CAI's) as a function of its accretion timescale and the protosatellite disk temperature (Td). Geological characterization and spacecraft radio tracking data suggest that Callisto, the outermost regular satellite of Jupiter, and Saturn's mid-sized satellite Rhea, are partially differentiated if their interiors are in hydrostatic equilibrium. Because the specific conditions during the satellites' formation are uncertain, we determine accretional temperature profiles for a range of values for Td and accretion time scales with the limiting assumption that impactors deposit all their energy close to the surface, leading to maximally effective radiative cooling. We find that Callisto can remain unmelted during formation if it accreted on a time scale longer than 0.6 Myr. Considering both radiogenic and accretional heating, Callisto must have finished accreting no earlier than ∼4 Myr after formation of CAI's for Td=100 K. Warmer disks or larger impactors that deposit their energy at depth in the satellite would require longer and/or later formation times. If Rhea accreted slowly (in 105 to 106 years), its growth must have finished no earlier than ∼2 Myr after CAI's for 70 K?Td?250 K to avoid early melting. If Rhea formed quickly (?103 yr), its formation must have been delayed until at least 2 to 7 Myr after CAI's and in a disk with Td<190 K in the small impactor limit. If the satellites form in slow-inflow-supplied disks as proposed by Canup and Ward [Canup, R.M., Ward, W.R., 2002. Astron. J. 124, 3404-3423], the implied satellite ages suggest that gas inflow to the giant planets ceased no earlier than ∼4 Myr after CAI's, comparable to average nebular lifetimes inferred from observations of circumstellar disks. 相似文献
In early April 2003, fishermen from Kino Bay Sonora alerted us about a massive die-off of fish and mollusks occurring at Kun Kaak Bay. Phytoplankton samples taken on 17 May 2003 reported the presence of a harmful algal bloom composed of Chatonella marina, Chatonella cf. ovata, Gymnodinium catenatum and Gymnodinium sanguineum. On 22 of May, we collected samples of water, sediment and organisms at the affected area. Physicochemical parameters and nutrients were measured in water samples from different depths. Sediment and benthic organisms were analyzed for Cd, Cu, Zn, Pb and Hg. We found concentrations of heavy metals higher than background levels for this area. Cadmium and Lead concentrations in sediment from the HAB area were up to 6x greater than background levels and Cd in mollusks was 8x greater than regulations allow. A relationship between elevated Cd and Pb concentrations in sediment and the survival of toxic dinoflagellates is suspected. 相似文献
Iron oxides and oxyhydroxides are common and important materials in the environment, and they strongly impact the biogeochemical
cycle of iron and other species at the Earth's surface. These materials commonly occur as nanoparticles in the 3–10 nm size
range. This paper presents quantitative results demonstrating that iron oxide reactivity is particle size dependent. The rate
and extent of the reductive dissolution of iron oxyhydroxide nanoparticles by hydroquinone in batch experiments were measured
as a function of particle identity, particle loading, and hydroquinone concentration. Rates were normalized to surface areas
determined by both transmission electron microscopy and Braunauer-Emmett-Teller surface. Results show that surface-area-normalized
rates of reductive dissolution are fastest (by as much as 100 times) in experiments using six-line ferrihydrite versus goethite.
Furthermore, the surface-area-normalized rates for 4 nm ferrihydrite nanoparticles are up to 20 times faster than the rates
for 6 nm ferrihydrite nanoparticles, and the surface-area-normalized rates for 5 × 64 nm goethite nanoparticles are up to
two times faster than the rates for 22 × 367 nm goethite nanoparticles. 相似文献
Vigtorniella flokati, a new species of polychaete worm associated with decaying whale remains, is described. Three separate V. flokati populations were sampled using submersibles: two associated with implanted gray whale carcasses in the San Diego Trough (1240 m depth) and the Santa Cruz Basin (1670 m) off California, and one from sperm whale and balaeanopterid bones implanted on the slope of Oahu, Hawaii at 1000 m. Extraordinarily large numbers of live specimens were observed and videotaped in situ using submersibles in the San Diego Trough and the Santa Cruz Basin. The populations on the carcass implanted for 4 months in San Diego Trough, and on the bones implanted for 2 years off Oahu, were composed only of small sized individuals (including juveniles). V. flokati most closely resembles the poorly known V. zaikai Kiseleva, 1992, described from the Black Sea. Forty-six morphological characters were used in a phylogenetic analysis of selected nereidiform polychaetes. The resulting most-parsimonious trees indicate sister taxon status between V. flokati and V. zaikai, and that this clade is sister to the putatively ancient polychaete clade Chrysopetalidae. Whale falls, which are intense point sources of organic enrichment at the deep-sea floor, pass through three successional stages. V. flokati appears to colonize the middle, “enrichment opportunist” stage, inhabiting organic-rich bones and sediments 4–24 months after carcass arrival. V. flokati exhibits remarkable behavior, clinging posteriorly to whale bones or nearby sediments to form a writhing carpet at densities exceeding 8000 m−2. Its extraordinary abundance on whale falls, and apparent absence from other habitats, suggests it to be a whale-fall specialist. The precise feeding mechanism of the worm remains unknown, but we hypothesize that it may utilize dissolved organic carbon derived from the organic-rich setting of whale falls. The widespread occurrence of V. flokati on ephemeral, food-rich habitat islands in the Pacific suggests life-history strategies analogous to those for hydrothermal-vent and cold-seep species. 相似文献
Washovers, dune scarps and flattened beach profiles with concentrations of coarse-grained sediment or heavy minerals are the diagnostic geological signatures of large storms on barriers today. It is clear that storms are a major force driving transgressive barriers onshore, but what is not as well understood is the role these powerful erosive events play in the evolution of prograding barriers. Application of ground-penetrating radar (GPR) and a combination of coring techniques have significantly improved our ability to image barrier architecture. Results of these studies reveal a more complex evolution than previously recognized. It is now possible to precisely locate and map storm deposits within prograded barrier lithosomes.
A comprehensive study of northern Castle Neck, Massachusetts was performed using 15 km of GPR surveys, a 120-m-long seismic line, 11 cores, and several radiocarbon dates. Storm-related layers are the most prominent horizons contained in the barrier stratigraphy. The geometry and sedimentology of these layers closely resembles those of a present-day post-storm beach. Twenty closely spaced, curvilinear heavy mineral layers imaged in the landward portion of the barrier suggest that the Castle Neck barrier was heavily influenced by storms during its initial phase of progradation beginning 4000 years BP. Approximately 1800 years BP, two intense storms impacted the coast depositing two extensive coarse-grained units. These layers mimic the flat-lying sand and gravel deposits that occur in front of a nearby eroding till outcrop following major storms. The great number of storm deposits in the early history of Castle Neck is related to either a period of greater storm activity and/or a slow rate of barrier progradation. The occurrence and preservation of these earlier storm layers are likely a product of the exposure of nearby drumlins resulting in greater availability of iron oxide and ferromagnesian sands. The supply of heavy-mineral sands has gradually diminished as the barrier prograded and the proximal drumlin source was buried by beach and dune sands. 相似文献
Sediment and water column data from four sites in North, Central and South San Francisco Bays were collected monthly from November 1999 through November 2001 to investigate the seasonal variation of benthic organic matter and chlorophyll in channel sediments, the composition and quality of sediment organic matter (SOM), and the relationship between seasonal patterns in benthic organic matter and patterns in water column chlorophyll. Water column chlorophyll peaked in the spring of 2000 and 2001, characteristic of other studies of San Francisco Bay phytoplankton dynamics, however an unusual chlorophyll peak occurred in fall 2000. Cross-correlation analysis revealed that water column chlorophyll at these four channel sites lead sediment parameters by an average of 2 to 3 months. Sediment organic matter levels in the San Francisco Bay channel showed seasonal cycles that followed patterns of water column production: peaks in water column chlorophyll were followed by later peaks in sediment chlorophyll and organic matter. Cyclical, seasonal variations also occurred in sediment organic matter parameters with sediment total organic carbon (TOC) and total nitrogen (TN) being highest in spring and lowest in winter, and sediment amino acids being highest in spring and summer and lowest in winter. Sediment chlorophyll, total organic carbon, and nitrogen were generally positively correlated with each other. Sediment organic matter levels were lowest in North Bay, intermediate in Central Bay, and highest in South Bay. C:N ratio and the ratio of enzyme hydrolyzable amino acids to TOC (EHAA:TOC) data suggest that SOM quality is more labile in Central and northern South Bay, and more refractory in North Bay and southern South Bay. 相似文献
ABSTRACTExisting theory of urban transformation under neoliberalization describes cities as the institutional arena in and through which neoliberal strategies of urbanism emanate and are contested. Emphasis is placed on the interaction between state and market without paying adequate attention to their internal dynamics. This study of urban transformation in the Beijing metropolis identifies a distinct trajectory whereby commodification of urban land has been actively pursued in response to the decentralization of developmental responsibilities and recentralization of tax revenue collection instituted by the central state. An urban development strategy is practiced whereby land commodification, city planning, and mega event hosting are integrated and mutually reinforcing. The research shows a pattern of land commodification and development dominated by newly developed construction land in the near suburbs, and reveals a picture of increased spatial inequality and intensified social discontent as a consequence of city-centered land development. Contrary to popular perception of the state and market as diametrically opposed principles of political organization, the Chinese state is found to have transformed and reshuffled itself to embrace and take advantage of the market for its developmental agenda. 相似文献