Suspended sediments and organic matter in mountain headwaters of the Amazon River: Results from a 1-year time series study in the central Peruvian Andes   总被引：1，自引：0，他引：1  

Amy Townsend-Small  Michael E. McClain  Jorge L. Noguera  Jay A. Brandes 《Geochimica et cosmochimica acta》2008,72(3):732-740

Few studies have examined the dynamics of sediments and suspended organic matter and their export from headwater basins in the Andes Mountains to the Amazon River, despite the fact that the Andes are the primary source of sediments to the lower Amazon basin. We measured river discharge as well as the concentration, δ¹⁵N, δ¹³C, %N, and %OC of coarse and fine suspended sediments (CSS and FSS) in the Chorobamba River, located in the central Andean Amazon of Peru. Samples were taken at least weekly over an entire year (July 2004-July 2005), with additional sampling during storms. Concentrations of particulate organic matter (POM) were generally low in the study river, with concentrations increasing by up to several orders of magnitude during episodic rain events. Because both overall flow volumes and POM concentrations increased under stormflow conditions, the export of POM was enhanced multiplicatively during these events. We estimated that a minimum of 80% of annual suspended sediment transfer occurred during only about 10 days of the year, also accounting for 74% of particulate organic carbon and 64% of particulate organic nitrogen transport. Significant differences occurred between seasons (wet and dry) for δ¹³C of coarse and fine POM in the Chorobamba River, reflecting seasonal changes in organic matter sources. The time series data indicate that this Andean river exports approximately equal amounts of fine and coarse POM to the lower Amazon. The observation that the vast majority of sediments and associated OM exported from Andean rivers is mobilized during short, infrequent storm events and landslides has important implications for our understanding of Amazon geochemistry, especially in the face of incipient global change.  相似文献   

Electrochemical study of hydrothermal and sedimentary pyrite dissolution     

Ran Liu  Amy L. Wolfe  David A. Dzombak  Colin P. Horwitz  Brian W. Stewart  Rosemary C. Capo 《Applied Geochemistry》2008

The dissolution of pyrite is of interest in the formation of acid mine drainage and is a complex electrochemical process. Being able to measure the rate of dissolution of particular pyrite samples under particular conditions is important for describing and predicting rates of AMD generation. Electrochemical techniques offer the promise of performing such measurements rapidly and with small samples. The oxidation of pyrite and the reduction of Fe³⁺ ions and/or O₂ half reactions involved in the pyrite dissolution process were investigated by cyclic voltammetry and steady-state voltammetry using three pyrite materials formed in both sedimentary and hydrothermal environments. For each sample, two kinds of pyrite working electrodes (conventional constructed compact solid electrode, and carbon paste electrode constructed from fine-grained pyrite particles) were employed. Results indicated that for both the hydrothermal and sedimentary pyrite samples the oxidation and reduction half reactions involved in dissolution were governed by charge transfer processes, suggesting that hydrothermal and sedimentary pyrites obey the same dissolution mechanism despite their different formation mechanisms. In addition, the results showed that it is feasible to use a C paste electrode constructed from fine-grained or powdered pyrite to study the pyrite dissolution process electrochemically and to derive approximate rate expressions from the electrochemical data.  相似文献   

Comparison of dissolution under oxic acid drainage conditions for eight sedimentary and hydrothermal pyrite samples   总被引：1，自引：0，他引：1  

Ran Liu  Amy L. Wolfe  David A. Dzombak  Brian W. Stewart  Rosemary C. Capo 《Environmental Geology》2008,56(1):171-182

The abiotic oxidative dissolution behaviors of eight natural pyrite samples, five sedimentary and three hydrothermal, from various geological environments were compared under oxic conditions at pH 3 and 6 in a highly controlled batch reactor dissolution system. The three sedimentary pyrite samples associated with coal had greater specific surface areas and also exhibited greater apparent dissolution rates and extent than the other two sedimentary and three hydrothermal samples under both pH conditions. However, after normalizing for surface area, the dissolution rate constants for the different pyrite samples were similar; the greatest difference was between the two non-coal sedimentary pyrite samples. Pyrite morphology and the presence of trace metals could contribute to the differences in dissolution behavior as reflected in the normalized dissolution rates. The sulfur:iron ratio observed in the aqueous solution at pH 3 increased with time, but was always less than 2.0 (predicted from the stoichiometry of dissolution) for all the pyrite samples during the 24-h experimental duration. This can be explained by the disproportionation dissociation of thiosulfate, an initial product of pyrite dissolution, to elemental sulfur and sulfate which does not occur in a 1:1 ratio. The results of this work indicate the importance of extracting and using the specific pyrite(s) relevant to particular mining areas in order to understand pyrite dissolution rates and the influence of environmental conditions on those rates.  相似文献   

Current‐aligned dewatering sheets and ‘enhanced’ primary current lineation in turbidite sandstones of the Marnoso‐arenacea Formation          下载免费PDF全文

Lawrence A. Amy  Peter J. Talling  Esther J. Sumner  Giuseppe Malgesini 《Sedimentology》2016,63(5):1260-1279

Turbidite sandstones of the Miocene Marnoso‐arenacea Formation (northern Apennines, Italy) display centimetre to decimetre long, straight to gently curved, 0·5 to 2·0 cm regularly spaced lineations on depositional (stratification) planes. Sometimes these lineations are the planform expression of sheet structures seen as millimetre to centimetre long vertical ‘pillars’ in profile. Both occur in the middle and upper parts of medium‐grained and fine‐grained sandstone beds composed of crude to well‐defined stratified facies (including corrugated, hummocky‐like, convolute, dish‐structured and dune stratification) and are aligned sub‐parallel to palaeoflow direction as determined from sole marks often in the same beds. Outcrops lack a tectonic‐related fabric and therefore these structures may be confidently interpreted to be sedimentary in origin. Lineations resemble primary current lineations formed by the action of turbulence during bedload transport under upper stage plane bed conditions. However, they typically display a larger spacing and micro‐topography compared to classic primary current lineations and are not associated with planar‐parallel, finely laminated sandstones. This type of ‘enhanced lineation’ is interpreted to develop by the same process as primary current lineations, but under relatively high near‐bed sediment concentrations and suspended load fallout rates, as supported by laboratory experiments and host facies characteristics. Sheets are interpreted to be dewatering structures and their alignment to palaeoflow (only noted in several other outcrops previously) inferred to be a function of vertical water‐escape following the primary depositional grain fabric. For the Marnoso‐arenacea beds, sheet orientation may be linked genetically to the enhanced primary current lineation structures. Current‐aligned lineation and sheet structures can be used as palaeoflow indicators, although the directional significance of sheets needs to be independently confirmed. These indicators also aid the interpretation of dewatered sandstones, suggesting sedimentation under a traction‐dominated depositional flow – with a discrete interface between the aggrading deposit and the flow – as opposed to under higher concentration grain or hindered‐settling dominated regimes.  相似文献   

Macrofaunal succession in sediments around kelp and wood falls in the deep NE Pacific and community overlap with other reducing habitats     

Angelo F. Bernardino  Craig R. Smith  Amy Baco  Iris Altamira  Paulo Y.G. Sumida 《Deep Sea Research Part I: Oceanographic Research Papers》2010,57(5):708-723

Sunken parcels of macroalgae and wood provide important oases of organic enrichment at the deep-sea floor, yet sediment community structure and succession around these habitat islands are poorly evaluated. We experimentally implanted 100-kg kelp falls and 200 kg wood falls at 1670 m depth in the Santa Cruz Basin to investigate (1) macrofaunal succession and (2) species overlap with nearby whale-fall and cold-seep communities over time scales of 0.25–5.5 yr. The abundance of infaunal macrobenthos was highly elevated after 0.25 and 0.5 yr near kelp parcels with decreased macrofaunal diversity and evenness within 0.5 m of the falls. Apparently opportunistic species (e.g., two new species of cumaceans) and sulfide tolerant microbial grazers (dorvilleid polychaetes) abounded after 0.25–0.5 yr. At wood falls, opportunistic cumaceans become abundant after 0.5 yr, but sulfide tolerant species only became abundant after 1.8–5.5 yr, in accordance with the much slower buildup of porewater sulfides at wood parcels compared with kelp falls. Species diversity decreased significantly over time in sediments adjacent to the wood parcels, most likely due to stress resulting from intense organic loading of nearby sediments (up to 20–30% organic carbon). Dorvilleid and ampharetid polychaetes were among the top-ranked fauna at wood parcels after 3.0–5.5 yr. Sediments around kelp and wood parcels provided low-intensity reducing conditions that sustain a limited chemoautrotrophically-based fauna. As a result, macrobenthic species overlap among kelp, wood, and other chemosynthetic habitats in the deep NE Pacific are primarily restricted to apparently sulfide tolerant species such as dorvilleid polychaetes, opportunistic cumaceans, and juvenile stages of chemosymbiont containing vesicomyid bivalves. We conclude that organically enriched sediments around wood falls may provide important habitat islands for the persistence and evolution of species dependent on organic- and sulfide-rich conditions at the deep-sea floor and contribute to β and γ diversity in deep-sea ecosystems.  相似文献   

Mercury Dynamics in a San Francisco Estuary Tidal Wetland: Assessing Dynamics Using In Situ Measurements     

Brian A. Bergamaschi  Jacob A. Fleck  Bryan D. Downing  Emmanuel Boss  Brian A. Pellerin  Neil K. Ganju  David H. Schoellhamer  Amy A. Byington  Wesley A. Heim  Mark Stephenson  Roger Fujii 《Estuaries and Coasts》2012,35(4):1036-1048

We used high-resolution in situ measurements of turbidity and fluorescent dissolved organic matter (FDOM) to quantitatively estimate the tidally driven exchange of mercury (Hg) between the waters of the San Francisco estuary and Browns Island, a tidal wetland. Turbidity and FDOM??representative of particle-associated and filter-passing Hg, respectively??together predicted 94?% of the observed variability in measured total mercury concentration in unfiltered water samples (UTHg) collected during a single tidal cycle in spring, fall, and winter, 2005?C2006. Continuous in situ turbidity and FDOM data spanning at least a full spring-neap period were used to generate UTHg concentration time series using this relationship, and then combined with water discharge measurements to calculate Hg fluxes in each season. Wetlands are generally considered to be sinks for sediment and associated mercury. However, during the three periods of monitoring, Browns Island wetland did not appreciably accumulate Hg. Instead, gradual tidally driven export of UTHg from the wetland offset the large episodic on-island fluxes associated with high wind events. Exports were highest during large spring tides, when ebbing waters relatively enriched in FDOM, dissolved organic carbon (DOC), and filter-passing mercury drained from the marsh into the open waters of the estuary. On-island flux of UTHg, which was largely particle-associated, was highest during strong winds coincident with flood tides. Our results demonstrate that processes driving UTHg fluxes in tidal wetlands encompass both the dissolved and particulate phases and multiple timescales, necessitating longer term monitoring to adequately quantify fluxes.  相似文献   

松辽盆地徐家围子断陷玄武岩气藏储层的CO2 封存潜力研究   总被引：1，自引：0，他引：1  

吾尔娜  吴昌志  季峻峰  王震宇  顾连兴  舒萍  丁日新 《高校地质学报》2012,18(2):239-247

玄武岩油气藏储层一方面含有大量可与CO2 反应生成碳酸盐的造岩矿物,另一方面又有枯竭油气藏的良好储（储集
空间）、运（运移通道）、盖（盖层条件）和保（保存能力）等 CO2 封存优势,是潜力大、实施易、成本低和安全性高的碳
汇靶区。该文选取了位于松辽盆地东北部的徐家围子断陷玄武岩气藏开展CO2 封存潜力研究,在对该气藏地质特征和储层
发育特征详细描述的基础上,结合玄武岩矿物组成和化学成分的鉴定分析结果,探讨该气藏的矿物固碳能力和油气储层固
碳能力,并对其封存CO2 的可行性进行了初步评价。研究表明,徐家围子断陷玄武岩气藏有着良好的储集空间,且易碳酸
盐化,其盖层可阻止所充注CO2 的逸散,稳定的圈闭条件可保证所充注CO2 的安全性,因而是CO2 封存的理想靶区。初步的
定量计算结果表明,徐家围子断陷玄武岩油气藏的矿物固碳潜力约为89.33×108 t,油气储层的封存能力约为6.2×108 t,总
计约95.53×108 t,具有十分可观的固碳潜力。  相似文献   

Scaling of melt production in hypervelocity impacts from high-resolution numerical simulations     

Amy C. Barr  Robert I. Citron 《Icarus》2011,211(1):913-916

The volume of melt produced in hypervelocity planetary impacts and the size and shape of the melted region are key to understanding the impact histories of solid planetary bodies and the geological effects of impacts on their surfaces and interiors. Prior work of Pierazzo et al. (Pierazzo, E., Vickery, A.M., Melosh, H.J. [1997]. Icarus 127, 408-423) gave the first estimates of impact melt production in geological materials using a modern hydrocode and equation of state. However, computational limits at the time forced use of low resolution, which may have resulted in low melt volumes. Our simulations with 50 times higher resolution provide independent confirmation of the Pierazzo et al. (Pierazzo, E., Vickery, A.M., Melosh, H.J. [1997]. Icarus 127, 408-423) melt volumes in aluminum, iron, dunite, and granite impacts at velocities between 20 and 80 km/s. In ice/ice impacts, we find that melt volumes depend on target temperature and are lower than predicted by Pierazzo et al. (Pierazzo, E., Vickery, A.M., Melosh, H.J. [1997]. Icarus 127, 408-423). Our melt volumes are directly proportional to impact energy for all materials, over a wide range of impact velocity. We also report new data for melt volume scalings for ice/dunite and iron/dunite impacts and the size and shape of melted region, valuable for interpretation of cratering records and studies of impact-induced differentiation.  相似文献   

Ages of Globally Distributed Lunar Paleoregoliths and Soils from 3.9 Ga to the Present     

Amy L. Fagan  Katherine H. Joy  Donald D. Bogard  David A. Kring 《Earth, Moon, and Planets》2014,112(1-4):59-71

This study determines the ages of 191 discrete lunar regolith samples from the Apollo, Luna, and meteorite collections. Model closure ages (for lithified breccias) and appearance ages (for unconsolidated soils) are calculated using the trapped ⁴⁰Ar and ³⁶Ar abundances of each sample, determined from published Ar data. Model closure ages of regolith breccias span ~3.9 to 0.01 Ga and appearance ages of soils range from ~3.6 to 0.03 Ga; 169 of these ages are published here for the first time, while 22 are recalculated ages. The regolith breccias with the oldest closure ages originate from the ancient highlands and oldest mare surfaces sampled by the Apollo missions. Soils generally have similar ages to each other, regardless of location and collection depth, with most model ages <2.0 Ga. Together, the soils and regolith breccias represent a record of regolith processes over the past 3.9 Ga. The data illustrate that individual landing sites can provide a diversity of ages, which has implications for planning future missions. Differences in maturity between older and younger regolith samples may reflect a change in collisional regimes over time. We note, too, that the closure ages published here are critical data needed for selecting temporally appropriate regolith samples used to decipher the diversity of impactors hitting the lunar surface over time and how the Sun has changed in time.  相似文献   

Climate change adaptation advantage for African road infrastructure   总被引：1，自引：0，他引：1  

Paul Chinowsky  Amy Schweikert  Niko Strzepek  Kyle Manahan  Kenneth Strzepek  C. Adam Schlosser 《Climatic change》2013,117(1-2):345-361

The African continent is facing the potential of a $183.6 billion USD liability to repair and maintain roads damaged from temperature and precipitation changes directly related to predicted climate change through 2100. This cost is strictly to retain the current road inventory. This cost does not include costs associated with impacts to critically needed new roads. In many African countries, limited or non-existent funds for adaptation and mitigation are challenging these countries to identify the threats that are posed by climate change, develop adaptation approaches to the predicted changes, incorporate changes into mid-range and long-term development plans, and secure funding for the proposed and necessary adaptations. Existing studies have attempted to quantify the impact of climate change on infrastructure assets that will be affected by climate change in the coming decades. The current study extends these efforts by specifically addressing the effect of climate change on the African road infrastructure. The study identifies both total costs and opportunity costs of repairing and maintaining infrastructure due to increased stressors from climate change. Proactive and reactive costs are examined for six climate scenarios, with costs ranging, respectively, from an average of $22 million USD to $54 million USD annually per country. A regional analysis shows contrast between impacts in five areas of the continent, with impacts ranging from 22 % opportunity cost to 168 %. These costs have the potential to delay critical infrastructure development on the continent and present a challenge to policy makers balancing short-term needs with long-term planning.  相似文献