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31.
Fabien Nex Gerhard Schäfer Jean-Marie Côme Timothy M. Vogel 《Comptes Rendus Geoscience》2006,338(5):297-306
The goal of this study was to develop an innovative chloroethene biodegradation module based on biological, thermodynamical and mechanistic concepts. The biodegradation scheme was based on the postulate that in each part of an aquifer only one degradation mechanism is dominant: the one involving the most energetic electron acceptor. Thus, the selection of the active degradation mechanism was a function of the concentration of different electron acceptors. Modified Monod-type kinetics was used in order to take into account the possible influence of some compounds on the biodegradation of a given organic compound. The numerical model developed was applied to a simple test case, whose results are presented here. To cite this article: F. Nex et al., C. R. Geoscience 338 (2006). 相似文献
32.
Vincent Artus Louis J. Durlofsky Jérôme Onwunalu Khalid Aziz 《Computational Geosciences》2006,10(4):389-404
The determination of the optimal type and placement of a nonconventional well in a heterogeneous reservoir represents a challenging optimization problem. This determination is significantly more complicated if uncertainty in the reservoir geology is included in the optimization. In this study, a genetic algorithm is applied to optimize the deployment of nonconventional wells. Geological uncertainty is accounted for by optimizing over multiple reservoir models (realizations) subject to a prescribed risk attitude. To reduce the excessive computational requirements of the base method, a new statistical proxy (which provides fast estimates of the objective function) based on cluster analysis is introduced into the optimization process. This proxy provides an estimate of the cumulative distribution function (CDF) of the scenario performance, which enables the quantification of proxy uncertainty. Knowledge of the proxy-based performance estimate in conjunction with the proxy CDF enables the systematic selection of the most appropriate scenarios for full simulation. Application of the overall method for the optimization of monobore and dual-lateral well placement demonstrates the performance of the hybrid optimization procedure. Specifically, it is shown that by simulating only 10% or 20% of the scenarios (as determined by application of the proxy), optimization results very close to those achieved by simulating all cases are obtained. 相似文献
33.
Thermal expansion differences between minerals within rocks under insolation have previously been assumed to drive breakdown by means of granular disaggregation. However, there have been no definitive demonstrations of the efficacy of this weathering mechanism. Different surface temperatures between minerals should magnify thermal expansion differences, and thus subject adjacent minerals to repeated stresses that might cause breakdown through fatigue failure. This work confirms the existence of surface temperature differences between minerals in granitic rocks under simulated short-term temperature fluctuations so as to discriminate their potential for initiating granular disaggregation. The influence of colour, as a surrogate for albedo, and crystal size, as a function of thermal mass are specifically identified because of their ease of quantification. Four rock types with a range of these properties were examined, and subjected to repeated short-term temperature cycles by radiative heating and cooling under laboratory conditions. Results show that while albedo is the main control for overall and individual maximum temperatures, crystal size is the main factor controlling higher temperature differences between minerals. Thus, stones with large differences of mineral sizes can undergo magnified stresses due to thermal expansion differences. 相似文献
34.
Geraldo Magela da Costa Gabriel de Oliveira Polli Márcio A. Kahwage Eddy de Grave Antônio Claret Soares Sabioni Júlio Cesar Mendes 《Physics and Chemistry of Minerals》2006,33(3):161-166
Mössbauer spectra (MS) of blue, green and yellow beryl (ideally Be3Al2Si6O18) containing approximately 1% of iron were obtained at 295 and 500 K. Room temperature (RT) spectra of both blue and green samples showed the presence of an asymmetric Fe2+ doublet (ΔE
Q~2.7 mm/s, δ~1.1 mm/s), with a very broad low-velocity peak. There is no clear evidence for the presence of a ferric component. The MS of the yellow sample at RT consists of an intense central absorption with parameters typical for Fe3+ (ΔE
Q~0.4 mm/s, δ~0.29 mm/s), plus an apparently symmetrical Fe2+ doublet. This sample acquires a light-blue shade upon heating in air at about 620 K. Thermal treatments at high temperatures caused no significant changes in the MS, but the green and yellow beryl acquire a blue colour. All these results are interpreted in relation to the existence of channel water and the distribution of iron among the available crystallographic sites. 相似文献
35.
Mohamed M. Hantush Rao. S. Govindaraju Miguel A. Marioand Zhonglong Zhang 《Journal of Hydrology》2002,260(1-4):58-74
This paper develops mass fraction models for transport and fate of agricultural pollutants in structured two-region soils. Mass fraction index models, based on a semi-infinite domain solution, are derived that describe leaching at depth, vapor losses through soil surface, absorption, and degradation in the dynamic- and stagnant-water soil regions. The models predict that leaching is the result of the combined effect of the upward vapor-phase transport relative to downward advection, residence time relative to half-life, dispersion, and lateral diffusive mass transfer. Simulations show that leached fraction of volatile compounds does not always decrease monotonically with increased residence time relative to the pollutant half-life, as a result of complex interactions among the different physical and biochemical processes. The results show that leaching, volatilization, and degradation losses can be affected significantly by lateral diffusive mass transfer into immobile-water regions and advection relative to dispersion (i.e. Peclet number) in the mobile-water regions. It is shown that solute diffusion into the immobile phase and subsequent biochemical decay reduces leaching and vapor losses through soil surface. Potential use of the modified leaching index for the screening of selected pesticides is illustrated for different soil textures and infiltration rates. The analysis may be useful to the management of pesticides and the design of landfills. 相似文献
36.
37.
The Portil lagoon is a natural freshwater reservoir located at the southwest of Spain, near the coast. In its surroundings an important tourist complex has been developed since the earlier 1970s. This has resulted in increased loads of nutrients, specially during summer months. In order to evaluate the impact from humans on the lagoon caused by anthropogenic activities, we have determined vertical profiles of excess 210Pb and 137Cs in a sediment core taken from its bottom. Vertical profile of excess 210Pb seems to indicate that the sediment core was affected by large-scale mixing processes. Nevertheless this possibility was ruled out based on the shape of the 137Cs vertical distribution after modelling the 137Cs profile considering large-scale mixing. The chronology developed from 210Pb and 137Cs has allowed us to calculate the temporal evolution of the mass sedimentation rate during the last century. This mass sedimentation rate increased in 1973: from 0.08(2) g cm-2 a-1 in the period 1900-1973 to 0.17(5) g cm-2 a-1 in the period 1973-1995. This increase could be related to land-movements in the drainage area and to permitted sewage inputs into the lagoon, both with its origin in the growing/running of the surrounding tourist complex. 相似文献
38.
Daily geomagnetic variations on the Iberian Peninsula 总被引:2,自引:0,他引:2
39.
S. K. Deb M. H. Manghnani K. Ross R. A. Livingston P. J. M. Monteiro 《Physics and Chemistry of Minerals》2003,30(1):31-38
A Raman scattering and X-ray diffraction study of the thermal decomposition of a naturally occurring, ettringite-group crystal
is presented. Raman spectra, recorded with increasing temperature, indicate that the thermal decomposition begins at ≈55 °C,
accompanied by dehydration of water molecules from the mineral. This is in contrast to previous studies that reported higher
temperature breakdown of ettringite. The dehydration is completed by 175 °C and this results in total collapse of the crystalline
structure and the material becomes amorphous. The Raman scattering results are supported by X-ray diffraction results obtained
at increasing temperatures.
Received: 9 July 2001 / Accepted: 14 August 2002 相似文献
40.
Synoptic and mesoscale study of a severe convective outbreak with the nonhydrostatic Global Environmental Multiscale (GEM) model 总被引:1,自引:0,他引:1
A. Erfani A. Méthot R. Goodson S. Bélair K.-S. Yeh J. Côté R. Moffet 《Meteorology and Atmospheric Physics》2003,82(1-4):31-53
Summary ?A nonhydrostatic 4-km version of the Global Environmental Multiscale (GEM) model, with detailed microphysics included, was
used to forecast the initiation, development, and structure of a tornado-producing supercell storm that occurred near Pine
Lake (Alberta, Canada) on 15 July 2000. Examination of observations and comparison with conceptual models indicate that this
storm is a good example of supercell storms that regularly produce summertime severe weather over Alberta.
It was found that the high-resolution model was able to reproduce the early initiation of convective activity along the Rocky
Mountains foothills, as well as the rapid northeastward propagation towards the Pine Lake area and the subsequent intensification
into a supercell storm. The general structures of the forecasted convective system correspond well with conceptual representations
of such events. Overall, this high-resolution forecast of the Pine Lake supercell storm was a significant improvement over
the current operational version of the GEM model (24 km), which was not able to intensify the foothills’ convection into a
supercell storm. Finally, it was found that the nonhydrostatic version of the model produces better trajectory and propagation
speed of the convective system, as compared with the hydrostatic one.
Received March 20, 2001; revised August 24, 2001 相似文献