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11.
P.J. Armitage R.H. Worden D.R. Faulkner A.C. Aplin A.R. Butcher J. Iliffe 《Marine and Petroleum Geology》2010
Fine-grained siliciclastic lithologies commonly act as sealing caprocks to both petroleum fields and host reservoirs for carbon capture (CO2 sequestration) projects. Fine-grained lithologies are thus of great importance in controlling fluid flow and storage in the subsurface. However, fine-grained rocks are rarely characterised in terms of primary sedimentary characteristics, diagenesis and how these relate to their flow properties (i.e. sealing or caprock quality). Seventeen samples from Lower Carboniferous estuarine caprock to a gas field (also to be used as a carbon capture site), have been analysed using a range of petrological and petrophysical techniques. The rock unit that represents the caprock to this gas field was found to be predominantly silt grade with porosity values as low as 1.8%. In these rocks, caprock quality (porosity) is controlled by intrinsic and extrinsic factors linked to primary mineralogy and diagenetic processes. Depositional mineralogy was dominated by quartz, detrital mica, detrital clay (likely Fe-rich 7Å clay and illite–smectite) with minor feldspar and oxide phases. Diagenetic processes included compaction, minor feldspar dissolution and kaolinite growth and the more important processes of chlorite, siderite and quartz cementation, as well as the likely transformation of smectite into illite. Caprock quality is controlled by the primary quantity of illite-muscovite in the sediment and also by the localised extent of chlorite and quartz cementation. Deposition in an estuarine environment led to highly heterogeneous distribution of primary and diagenetic minerals, and thus caprock quality, between and within the samples. 相似文献
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We propose a mechanism to explain suggested links between seismic activity and ionospheric changes detected overhead. Specifically, we explain changes in the natural extremely low-frequency (ELF) radio noise recently observed in the topside ionosphere aboard the DEMETER satellite at night, before major earthquakes. Our mechanism utilises increased electrical conductivity of surface layer air before a major earthquake, which reduces the surface-ionosphere electrical resistance. This increases the vertical fair weather current, and (to maintain continuity of electron flow) lowers the ionosphere. Magnitudes of crucial parameters are estimated and found to be consistent with observations. Natural variability in ionospheric and atmospheric electrical properties is evaluated, and may be overcome using a hybrid detection approach. Suggested experiments to investigate the mechanism involve measuring the cut-off frequency of ELF “tweeks”, the amplitude and phase of very low frequency radio waves in the Earth–ionosphere waveguide, or medium frequency radar, incoherent scatter or rocket studies of the lower ionospheric electron density. 相似文献
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Christian Tueckmantel Quentin J. Fisher Carlos A. Grattoni Andrew C. Aplin 《Marine and Petroleum Geology》2012,29(1):129-142
Understanding the impact of faults on fluid flow in the subsurface is important for the extraction of oil, gas and groundwater as well as the geological storage of waste products. We address two problems present in current industry-standard workflows for fault seal analysis that may lead to fault rocks not being represented adequately in computational fluid flow models. Firstly, fluid flow properties of fault rocks are often measured only for small-scale faults with throws not exceeding a few centimetres. Large seismic-scale faults (throws >20 m) are likely to act as baffles or conduits to flow but they are seldom recovered from subsurface cores and consequently fault rock data for them is sparse. Secondly, experimental two-phase fluid flow data is lacking for fault rocks and, consequently, uncertainties exist when modelling flow across faults in the presence of two or more immiscible phases. We present a data set encompassing both single- and two-phase fluid flow properties of fault and host rocks from the 90-Fathom fault and its damage zone at Cullercoats Bay, NE England. Measurements were made on low-throw single and zones of deformation bands as well as on slip-surface cataclasites present along the ～120 m throw main fault. Samples were analysed using SEM and X-ray tomography prior to petrophysical measurements. We show that single deformation bands, deformation band zones and slip-surface cataclasites exhibit dissimilar single- and two-phase fluid flow properties. This is due to grain-size reduction being more pronounced in slip-surface cataclasites and changes in microstructure being fault-parallel for deformation bands but mostly fault-perpendicular for slip-surface cataclasites. A trend of fault rocks with low absolute permeabilities exhibiting lower relative permeabilities than more permeable rocks at the same capillary pressure is evident. 相似文献
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Ferromanganese oxide deposits from the Central Pacific Ocean,II. Nodules and associated sediments 总被引：1，自引：0，他引：1
Bulk chemical, mineralogical and selective leach analyses have been made on a suite of abyssal ferromanganese nodules and associated sediments from the S.W. equatorial Pacific Ocean. Compositional relations between nodules, sediment oxyhydroxides and nearby ferromanganese encrustations are drawn assuming that the crusts represent purely hydrogenetic ferromanganese material. Crusts, δMnO2-rich nodules and sediment oxyhydroxides are compositionally similar and distinct from diagenetic todorokitebearing nodules. Compared to Fe-Mn crusts, sediment oxyhydroxides are however slightly enriched, relative to Mn and Ni, in Fe, Cu, Zn, Ti and Al, and depleted in Co and Pb, reflecting processes of non-hydrogenous element supply and diagenesis. δMnO2 nodules exhibit compositions intermediate between Fe-Mn crusts and sediment oxyhydroxides and thus are considered to accrete oxides from both the water column and associated sediments.Deep ocean vertical element fluxes associated with large organic aggregates, biogenic calcite, silica and soft parts have been calculated for the study area. Fluxes associated with organic aggregates are one to three orders of magnitude greater than those associated with the other phases considered, are in good agreement with element accumulation rates in sediments, and are up to four orders of magnitude greater than element accumulation rates in nodules. Metal release from labile biogenic material in surface sediments can qualitatively explain the differences between the composition of Fe-Mn crusts and sediment oxyhydroxides.Todorokite-rich diagenetic nodules are confined to an eastwards widening equatorial wedge. It is proposed that todorokite precipitates directly from interstitial waters. Since the transition metal chemistry of interstitial waters is controlled dominantly by reactions involving the breakdown of organic carbon, the supply and degradation rate of organic material is a critical factor in the formation of diagenetic nodules. The wide range of (trace metal/Mn) ratios observed in marine todorokite reflects a balance between the release of trace metals from labile biogenic phases and the reductive remobilisation of Mn oxide, both of which are related to the breakdown of organic carbon. 相似文献
15.
Andrew C. Aplin 《Earth and Planetary Science Letters》1984,71(1):13-22
Analyses have been made of the REE contents of a suite of hydrogenous δMnO2-rich ferromanganese encrustations obtained from a variety of depths (1000–4700 m) on the Line Islands Archipelago. The crusts form a coherent sample group, the REE contents of which are distinctly higher than those of diagenetic nodules. Crusts from 1 to 2 km depth exhibit higher Mn/Fe ratios and are approximately 50% REE depleted with respect to crusts below ～ 2 km. Furthermore, the shale-normalised patterns of the REE fall into the same depth-related categories. Crusts from depths greater than 2000–2500 m exhibit slight heavy REE depletion relative to intermediate REE whilst crusts from above that level exhibit more fractionated, heavy-REE-enriched patterns.To explain these depth-related processes, it is proposed that Mn and Fe oxides exhibit distinct behaviour with respect to REE scavenging. Between ～ 1 and 2 km, higher Mn/Fe ratios in the crusts are considered to be caused by an enhanced supply of Mn2+ —by diffusion and advection from nearshore sediments—which is adsorbed by and occludes existing oxide flocs. At these depths, oxides therefore tend to exhibit predominantly Mn oxide adsorptive properties. Consideration of the REE patterns shows that Fe oxides must be enriched overall in REE relative to Mn oxides and exhibit a flat shale-normalised REE pattern, whilst Mn oxide exhibits a heavy-REE-enriched pattern.Comparison of dissolved REE depth profiles with the crust data enables a qualitative appraisal of the application of scavenging models to the oxide-REE system. The data are not simply described by either equilibrium or irreversible adsorption models alone. It is concluded that whilst oxides may play a general role in creating the LREE depleted seawater pattern, they have little effect on individual vertical profiles, except close to points where fresh oxides precipitate. 相似文献
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Paul R. T. Newby Paul Aplin Simon J. Buckley Jim H. Chandler Jane E. Drummond David A. Holland Samantha J. Lavender Pauline E. Miller Jon P. Mills Henny Mills A. Stewart Walker Peter A. Woodsford 《The Photogrammetric Record》2009,24(125):66-102
The XXIst International Congress of Photogrammetry and Remote Sensing was held at the Beijing International Convention Centre, China, from 3rd to 11th July 2008. Reports are given on the Congress as a whole, including the General Assembly, some Technical Commission activities and the Congress Exhibition. Papers from the Congress are published in Volume XXXVII of the International Archives of the Photogrammetry, Remote Sensing and Spatial Information Sciences. 相似文献
18.
Chemical and mineralogical analyses of a well-controlled suite of ferromanganese encrustations from the Line Islands Archipelago (Central Pacific) suggest that they represent purely hydrogenous deposits—i.e. they have formed through the slow accumulation of trace metal-enriched oxides directly from the water-column. Mineralogically they consist predominantly of δMnO2 and amorphous FeOOHxH2O. Compositionally, they are similar to δMnO2 nodules from adjoining basinal areas but are enriched in both Mn (mean = 20.4%, max = 29.3%) and Co (mean = 0.55%, max = 1.57%). δMnO2 is the most important trace metal bearing phase; strong associations are noted between it and Co, Mo, Ni, Zn, and Cd, whilst only Be is associated specifically with FeOOH. V, Sr and Pb are partitioned between the authigenic oxide phases, whilst Ti most probably occurs as TiO2xH2O. Cu is contained in both aluminosilicate contaminant phases and Fe oxide phases. These relations are considered to reflect the differing scavenging behaviour of Mn and Fe oxides in the water column.Crusts from ~1–2 km are enriched in Mn and the Mn-related elements and exhibit higher ratios than deeper crusts, which are compositionally constant. The higher ratios may result from a supply of Mn from continental borderland sediments at these depths, which is transported horizontally by advective-diffusive processes. Since manganophile elements are enriched relative to Mn in the 1–2 km crusts, it is considered that the supply of Mn is scavenged by existing oxides, is oxidised and effectively occludes them. A higher proportion of oxide particles thus exhibit Mn oxide scavenging properties in the 1–2 km depth zone. The increased vertical flux of Mn resulting from the supply at ~1–2 km is not reflected by higher ratios in deeper crusts, so that the vertical flux of oxides is not simply related to the standing crop. The ratios of the crusts thus reflect the composition of suspended oxides at similar depths. 相似文献
19.
Measurement of partition coefficients of phenol and cresols in gas-charged crude oil/water systems 总被引：1，自引：0，他引：1
An instrument has been constructed for monitoring the partition coefficients of phenol and cresols between crude oil and water under sub-surface conditions. The device has the capacity for introducing methane gas into crude oil, thereby allowing measurements under live oil (solution gas-containing) conditions. The partition coefficients of phenol and cresols have been measured in crude oil: water substrates under “live” oil and “dead” oil (without solution gas) conditions over a temperature range 25–150 °C. Over the range investigated it is seen that the introduction of gas (crude oil saturated at 100 bar with methane) into the system resulted in an approximate doubling of partition coefficients compared to the equivalent dead oil: brine systems. The partition coefficient data obtained using the device may be employed in a number of petroleum exploration and production activities such as the determination of residual oil saturation of a water-flooded petroleum reservoir. Partition coefficient measurements may help in predicting toxic organic solute loadings in oilfield discharge waters. 相似文献
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