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31.
Submarine canyons represent natural conduits for preferential transport of particulate material, including anthropogenic contaminants, from coastal zones directly to the deep sea. To assess related dispersal of natural and anthropogenic lead (Pb), we analyzed Pb concentrations and stable isotope ratios in surface sediments and sediment trap particulate material from the Portuguese margin Nazaré and Setúbal/Lisbon canyons. Geochemical data are integrated with previously obtained data on near-bottom hydrodynamics and processes and pathways of sediment transport. The two canyon systems are located in close geographic proximity to each other, but represent contrasting settings in terms of sediment input and down-canyon sediment transport processes.Concentration–isotope diagrams and three-isotope plots (206Pb/207Pb vs. 208Pb/206Pb) suggest binary mixing between natural and anthropogenic end members. The inferred isotopic signature of pollutant Pb (206Pb/207Pb=1.143 [1.134–1.149, 95% confidence interval]) is most consistent with industrial Pb; ongoing influence from gasoline Pb additives is at most of minor importance. Two proposed natural end members most likely bracket the isotopic signature of natural Pb. Accordingly, binary mixing calculations indicate that on average 20–45% vs. 35–55% of total Pb is derived from anthropogenic sources in the Nazaré and Setúbal–Lisbon canyon systems, respectively. Enhanced anthropogenic influence in the latter area is consistent with its proximity to heavily populated and industrialized areas and with sediment input from the Tagus and Sado rivers, potential major carriers of pollutant particles. In both canyon systems, the anthropogenic component generally decreases with increasing water depth.Isotopic signatures of sediment trap particulate material are generally consistent with surface sediment data at similar water depth, but show large variability in the upper Nazaré canyon and major deviations from surface sediments in the lower canyon. In the lower canyon, Pb isotopic ratios of sediment trap particulate material mostly reflect low pelagic fluxes from the overlying water column, whereas surface sediment signatures are dominated by episodic down-canyon mass transport events. Such gravity flows appear to incorporate older (pre-industrial) material masking the isotopic signature of pollutant Pb. Large variability in the upper canyon reflects continuous sediment resuspension by bottom currents. Stronger average bottom currents are associated with higher 206Pb/207Pb ratios of sediment trap particulate material and hence decreased influence of pollutant Pb. This may reflect preferential resuspension of natural Pb at the canyon floor and/or additional remobilization of older, less-polluted sediment in adjacent areas such as the canyon walls.  相似文献   
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Russian Meteorology and Hydrology - It is shown that the snow stake measurements in central Antarctica systematically underestimate the value of the snow build-up. Two methods for the calculation...  相似文献   
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We present spectroscopy of the molecular shock in the supernova remnant IC 443. The H2 level populations in IC 443 are nearly identical to Orion Peak 1 (Brand et al. 1988; Parmar et al. 1994) and are consistent with a partially dissociative J-shock. The similarity with Orion suggests the shock processes which dominate the emission in both regions are essentially identical.  相似文献   
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Hydrogen peroxide (H2O2) has been suggested as a possible oxidizer of the martian surface. Photochemical models predict a mean column density in the range of 1015-1016 cm−2. However, a stringent upper limit of the H2O2 abundance on Mars (9×1014 cm−2) was derived in February 2001 from ground-based infrared spectroscopy, at a time corresponding to a maximum water vapor abundance in the northern summer (30 pr. μm, Ls=112°). Here we report the detection of H2O2 on Mars in June 2003, and its mapping over the martian disk using the same technique, during the southern spring (Ls=206°) when the global water vapor abundance was ∼10 pr. μm. The spatial distribution of H2O2 shows a maximum in the morning around the sub-solar latitude. The mean H2O2 column density (6×1015 cm−2) is significantly greater than our previous upper limit, pointing to seasonal variations. Our new result is globally consistent with the predictions of photochemical models, and also with submillimeter ground-based measurements obtained in September 2003 (Ls=254°), averaged over the martian disk (Clancy et al., 2004, Icarus 168, 116-121).  相似文献   
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An Erratum has been published for this article in Hydrological Processes 16(5) 2002, 1130–1131. Humid tropical regions are often characterized by extreme variability of fluvial processes. The Rio Terraba drains the largest river basin, covering 4767 km2, in Costa Rica. Mean annual rainfall is 3139±419sd mm and mean annual discharge is 2168±492sd mm (1971–88). Loss of forest cover, high rainfall erosivity and geomorphologic instability all have led to considerable degradation of soil and water resources at local to basin scales. Parametric and non‐parametric statistical methods were used to estimate sediment yields. In the Terraba basin, sediment yields per unit area increase from the headwaters to the basin mouth, and the trend is generally robust towards choice of methods (parametric and LOESS) used. This is in contrast to a general view that deposition typically exceeds sediment delivery with increase in basin size. The specific sediment yield increases from 112±11·4sd t km?2 year?1 (at 317·9 km2 on a major headwater tributary) to 404±141·7sd t km?2 year?1 (at 4766·7 km2) at the basin mouth (1971–92). The analyses of relationships between sediment yields and basin parameters for the Terraba sub‐basins and for a total of 29 basins all over Costa Rica indicate a strong land use effect related to intensive agriculture besides hydro‐climatology. The best explanation for the observed pattern in the Terraba basin is a combined spatial pattern of land use and rainfall erosivity. These were integrated in a soil erosion index that is related to the observed patterns of sediment yield. Estimated sediment delivery ratios increase with basin area. Intensive agriculture in lower‐lying alluvial fans exposed to highly erosive rainfall contributes a large part of the sediment load. The higher elevation regions, although steep in slope, largely remain under forest, pasture, or tree‐crops. High rainfall erosivity (>7400 MJ mm ha?1 h?1 year ?1) is associated with land uses that provide inadequate soil protection. It is also associated with steep, unstable slopes near the basin mouth. Improvements in land use and soil management in the lower‐lying regions exposed to highly erosive rainfall are recommended, and are especially important to basins in which sediment delivery ratio increases downstream with increasing basin area. Copyright © 2001 John Wiley & Sons, Ltd.  相似文献   
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Computer-based risk evaluation methods are practical tools to compare automatically and evaluate contaminated sites. HYDRISK is an example of adequate knowledge-based systems: HYDRISK evaluates hydrogeological properties and chemical criteria relevant to contaminant transport with respect to the necessary remedial actions. It works at a high investigative level and enables geologists and engineers to draw differentiated conclusions for selecting remediation methods for the contaminated site. HYDRISK emphasizes space and time dependent aspects of the contaminant transport. It is supported by a geographic information system (GIS) to display the evaluation results. Some ideas on considering the spatiotemporal variability of relevant parameters by means of geostatistical methods and numerical models will be given.  相似文献   
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The Fourier transform infrared spectra of individual conodonts with various CAI values indicate definite changes in conodont francolite during diagenesis. Steady decarbonation can be observed in the increasing intensity of the band with the wavenumber 2340 an-1, which is assigned to trapped molecular CO2. Carbon dioxide originates from decomposing CO2-3-ions occupying the B-site in francolite. Furthermore, the intensity of the water-deformation band at 1644 cm-1 decreases with higher CAI values. These changes of intensity can be quantified by calculating the maximum extinction (Emax) for the corresponding absorption maxima and correlated with the CAI. Unaltered conodonts have a relative variable water 'content' and very little CO2. Up to a CAI value of 4 conodont francolite continuously expells water and carbon dioxide is trapped. Conodonts with CAI = 5 have similar water 'contents' to CAI = 4 conodonts, but decarbonation continues to take place during this stage of diagenesis.  相似文献   
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