First attempts towards an integrative concept for the ecological assessment of groundwater ecosystems   总被引：1，自引：0，他引：1  

Christian Steube  Simone Richter  Christian Griebler 《Hydrogeology Journal》2009,17(1):23-35

Healthy aquifers deliver important ecosystem services, e.g. the purification of infiltrating water and the storage of high-quality water over decades in significant quantities. The functioning of terrestrial and surface aquatic ecosystems directly depends on groundwater and vice versa. Nowadays, legislation has started to consider groundwater not only as a resource but as a living ecosystem. The assessment of ecosystems requires consideration of ecological criteria, which, so far, are not available for groundwater systems. In the framework of a project supported by the German Federal Environment Agency (UBA), a first concept for the ecological assessment of groundwater ecosystems is developed. Steps to be taken are introduced, with a strong focus on microbes as potential bioindicators. These include (1) the typology of groundwater ecosystems, (2) the derivation of natural background values, (3) the identification of potential bioindicators, and (4) the development of an assessment model. First successes and difficulties associated with these challenges, e.g. the lack of simple correlations between abiotic and biotic variables, are discussed on the basis of a data set from a local and regional aquifer in NE Germany. The need for collaboration between ecologists, hydrogeologists and geochemists, as well as the application of modern approaches such as multivariate statistics, is emphasized.  相似文献   

Ambient pressure thermal desorption spectroscopy (AP-TDS) of NiO/SiO2 catalysts     

M. Städter  K. Müller  F. Rachow  M. Richter  D. Schmeißer 《Environmental Earth Sciences》2013,70(8):3779-3784

The Sabatier reaction is a key process in the “power-to-gas” application which is considered to contribute to future chemical energy storage systems. In this contribution we focus on the catalytic active sites of a NiO catalyst supported on SiO₂ (NiO/SiO₂) which is commonly used in the Sabatier reaction. A novel technique for the characterization of the active sites is presented and discussed using thermal desorption spectroscopy at ambient pressure. This analytical tool is operated under reaction conditions and allows element specific measurements during the catalytic process of CO₂ reforming towards methane. Beside the desorption experiments, XPS and XAS measurements of pristine and catalytically used samples are performed to determine the influence of the Sabatier reaction conditions on the surface structure of the catalyst.  相似文献   

Regularized derivatives of potential fields and their role in semi-automated interpretation methods   总被引：2，自引：0，他引：2  

R. Pa&#;teka  F.P. Richter  R. Karcol  K. Brazda  M. Hajach 《Geophysical Prospecting》2009,57(4):507-516

Evaluation of higher derivatives (gradients) of potential fields plays an important role in geophysical interpretation (qualitative and/or quantitative), as has been demonstrated in many approaches and methods. On the other hand, numerical evaluation of higher derivatives is an unstable process – it has the tendency to enlarge the noise content in the original data (to degrade the signal-to-noise ratio). One way to stabilize higher derivative evaluation is the utilization of the Tikhonov regularization. In the submitted contribution we present the derivation of the regularized derivative filter in the Fourier domain as a minimization task by means of using the classical calculus of variations. A very important part of the presented approach is the selection of the optimum regularization parameter – we are using the analysis of the C-norm function (constructed from the difference between two adjacent solutions, obtained for different values of regularization parameter). We show the influence of regularized derivatives on the properties of the classical 3D Euler deconvolution algorithm and apply it to high-sensitivity magnetometry data obtained from an unexploded ordnance detection survey. The solution obtained with regularized derivatives gives better focused depth-estimates, which are closer to the real position of sources (verified by excavation of unexploded projectiles).  相似文献   

Hydrodynamics and sediment dynamics in the German Bight. A focus on observations and numerical modelling in the East Frisian Wadden Sea     

Joanna Staneva  Emil V. Stanev  Jörg-Olaf Wolff  Thomas H. Badewien  Rainer Reuter  Burghard Flemming  Alexander Bartholomä  Karsten Bolding 《Continental Shelf Research》2009

This work deals with analysis of hydrographic observations and results of numerical simulations. The data base includes acoustic Doppler current profilers (ADCP) observations, continuous measurements on data stations and satellite data originating from the medium resolution imaging spectrometer (MERIS) onboard the European Space Agency (ESA) satellite ENVISAT with a spatial resolution of 300 m. Numerical simulations use nested models with horizontal resolutions ranging from 1 km in the German Bight to 200 m in the East Frisian Wadden Sea coupled with a suspended matter transport model. Modern satellite observations have now a comparable horizontal resolution with high-resolution numerical model of the entire area of the East Frisian Wadden Sea allowing to describe and validate new and so far unknown patterns of sediment distribution. The two data sets are consistent and reveal an oscillatory behaviour of sediment pools to the north of the back-barrier basins and clear propagation patterns of tidally driven suspended particulate matter outflow into the North Sea. The good agreement between observations and simulations is convincing evidence that the model simulates the basic dynamics and sediment transport processes, which motivates its further use in hindcasting, as well as in the initial steps towards forecasting circulation and sediment dynamics in the coastal zone.  相似文献   

Two-color photometry of the cluster of galaxies A 2634     

A. T. Kalloglyan  G. Richter  W. Thänert  E. G. Nikogosyan 《Astrophysics》1987,27(3):581-587

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Photometry of the perseus cluster of galaxies A 426     

A. G. Egikyan  A. T. Kalloglyan  G. Richter  W. Thanert 《Astrophysics》1985,23(1):377-385

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Inertial Effects on the Vertical Transport of Suspended Particles in a Turbulent Boundary Layer     

David Richter  Marcelo Chamecki 《Boundary-Layer Meteorology》2018,167(2):235-256

In many atmospheric flows, a dispersed phase is actively suspended by turbulence, whose competition with gravitational settling ultimately dictates its vertical distribution. Examples of dispersed phases include snow, sea-spray droplets, dust, or sand, where individual elements of much larger density than the surrounding air are carried by turbulent motions after emission from the surface. In cases where the particle is assumed to deviate from local fluid motions only by its gravitational settling (i.e., they are inertialess), traditional flux balances predict a power-law dependence of particle concentration with height. It is unclear, however, how particle inertia influences this relationship, and this question is the focus of this work. Direct numerical simulations are conducted of turbulent open-channel flow, laden with Lagrangian particles of specified inertia; in this way the study focuses on the turbulent transport which occurs in the lowest few meters of the planetary boundary layer, in regions critical for connecting emission fluxes to the fluxes felt by the full-scale boundary layer. Simulations over a wide range of particle Stokes number, while holding the dimensionless settling velocity constant, are performed to understand the role of particle inertia on vertical dispersion. It is found that particles deviate from their inertialess behaviour in ways that are not easily captured by traditional theory; concentrations are reduced with increasing Stokes number. Furthermore, a similarity-based eddy diffusivity for particle concentration fails as particles experience inertial acceleration, precluding a closed-form solution for particle concentration as in the case of inertialess particles. The primary consequence of this result is that typical flux parametrizations connecting surface emission models (e.g., saltation models or sea-spray generation functions) to elevated boundary conditions may overestimate particle concentrations due to the reduced vertical transport caused by inertia in between; likewise particle emission may be underestimated if inferred from concentration measurements aloft.  相似文献   

The provenance of Australian uranium ore concentrates by elemental and isotopic analysis     

Elizabeth Keegan  Stephan Richter  Ian Kelly  Henri Wong  Patricia Gadd  Heinz Kuehn  Adolfo Alonso-Munoz 《Applied Geochemistry》2008

Elemental and isotopic ratio analyses of U ore concentrate samples, from the 3 operating U mining facilities in Australia, were carried out to determine if significant variations exist between their products, thereby allowing the U ore concentrate’s origin to be identified. Elemental analyses were conducted using inductively coupled plasma mass spectrometry (ICP-MS) and X-ray fluorescence spectrometry (XRF). Lead isotope ratios were measured using ICP-MS and U isotope analyses were conducted using thermal ionisation mass spectrometry (TIMS). Minute quantities of sample, such as that obtained from a swipe, were also examined for elemental concentrations using secondary ion mass spectrometry (SIMS). The results of multivariate statistical analysis show clear patterns in the trace elemental composition of the processed U ores, indicating that it is possible to use this feature as a unique identifier of an Australian U ore concentrate’s source. Secondary ion mass spectrometry analyses also allow individual particles to be differentiated using this ‘fingerprinting’ technique. Isotope ratios determined using TIMS reveal that there is a significant difference in the n(²³⁴U)/n(²³⁸U) isotope ratio between the U ore concentrate from each mine.  相似文献   

Magnesium isotope fractionation in silicate melts by chemical and thermal diffusion   总被引：3，自引：0，他引：3  

Frank M. Richter  E. Bruce Watson  Fang-Zhen Teng 《Geochimica et cosmochimica acta》2008,72(1):206-220

Two types of laboratory experiments were used to quantify magnesium isotopic fractionations associated with chemical and thermal (Soret) diffusion in silicate liquids. Chemical diffusion couples juxtaposing a molten natural basalt (SUNY MORB) and a molten natural rhyolite (Lake County Obsidian) were run in a piston cylinder apparatus and used to determine the isotopic fractionation of magnesium as it diffused from molten basalt to molten rhyolite. The thermal diffusion experiments were also run in a piston cylinder apparatus but with a sample made entirely of molten SUNY MORB displaced from the hotspot of the assembly furnace so that the sample would have a temperature difference of about 100-200 °C from one end to the other. The chemical diffusion experiments showed fractionations of ²⁶Mg/²⁴Mg by as much as 7‰, which resulted in an estimate for the mass dependence of the self-diffusion coefficients of the magnesium isotopes corresponding to D_26Mg/D_24Mg=(24/26)^β with β = 0.05. The thermal diffusion experiments showed that a temperature difference of about 100 °C resulted in the MgO, CaO, and FeO components of the basalt becoming slightly enriched by about 1 wt% in the colder end while SiO₂ was enriched by several wt% in the hotter end. The temperature gradient also fractionated the magnesium isotopes. A temperature difference of about 150 °C produced an 8‰ enrichment of ²⁶Mg/²⁴Mg at the colder end relative to the hotter end. The magnesium isotopic fractionation as a function of temperature in molten basalt corresponds to 3.6 × 10⁻²‰/°C/amu.  相似文献   

Talc-chlorite-amphibole felses of the KTB pilot hole,Oberpfalz, Bavaria: Protolith characteristics and phase relationships     

S. Matthes  M. Okrusch  U. Schüssler  P. Richter  K. von Gehlen  Ch. Röhr 《Mineralogy and Petrology》1995,52(1-2):25-59

Summary The metagabbro-amphibolite sequences in the KTB pilot hole contain intercalations of talc-chlorite-amphibole felses (or hosbachites), which show transitional contacts to the adjacent metagabbros. The hosbachites are characterized by relics of a primary igneous texture and still contain igneous minerals like clinopyroxene, biotite and pseudomorphs after olivine, while brown Ca-amphibole was presumably formed in a late-magmatic stage. The geological, textural, mineralogical and geochemical evidence indicates that the hösbachites were derived from ultramafic cumulates, differentiated from a basaltic magma, either in the inner parts of dolerite sills or in small gabbro intrusions. A pervasive metamorphic overprint under medium-pressure, amphibolite-facies conditions which was accompanied by penetrative deformation led to assemblages with green Ca-amphibole ± anthophyllite ± cummingtonite ± tremolite/actinolite + clinochlore + talc + olivine + ilmenite ± Cr-bearing spinel + sulfides. Phase relationships are consistent with a prograde P-T path leading to the formation of anthophyllite from olivine + talc at peak metamorphic temperatures of 640–700°C, at assumed pressures of 8-10 kbar, similar to those derived from mineral assemblages in the adjacent metabasites and metasediments. High-pressure relics locally present in coronitic metagabbros and retrograded eclogites of the KTB pilot hole were not recognized in the hosbachites. A retrograde overprint under greenschist-facies conditions led to the total replacement of igneous or metamorphic olivine by aggregates of antigorite + magnetite, chloritization of biotite and the formation of late tremolite/ actinolite.

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Zusammenfassung Talk- Chlorit-Amphibol-Felse der KTB-Vorbohrung, Oberpfalz: Eduktcharakteristik und Phasenbeziehungen Die Metagabbro-Amphibolit-Folge in der KTB-Vorbohrung enthält Einschaltungen von Talk-Chlorit-Amphibol-Felsen (Hosbachite), die graduelle Übergänge zu den benachbarten Metagabbros aufweisen. Die Hosbachite sind durch Relikte von primären magmatischen Gefügen gekennzeichnet and führen noch magmatische Mineralrelikte wie Klinopyroxen, Biotit and Pseudomorphosen nach Olivin, während brauner CaAmphibol wahrscheinlich spdtmagmatisch gebildet wurde. Verbandsverhältnisse, Reliktgefüge und Reliktminerale sowie Haupt- und Spurenelement-Geochemie sprechen dafür, daß die Hosbachite auf ultramafische Kumulate zurückgehen, die aus einem basischen Magma differenziert wurden, and zwar entweder im Innern von doleritischen Lagergängen oder in kleinen Gabbro-Intrusionen.Eine durchgreifende metamorphe Überprägung unter Bedingungen der Mitteldruck Amphibolitfazies, die von einer penetrativen Deformation begleitet war, fuhrte zu Mineralparagenesen mit grünern Ca-Amphibol ± Anthophyllit ± Cummingtonit + Tremolit/Aktinolith + Klinochlor + Talk + Olivin + Ilmenit + Cr-haltigem Spinell + Sulfiden.Die Phasenbeziehungen weisen darauf hin, daß sich im Zuge eines prograden P-TPfades Anthophyllit aus der Paragenese Olivin + Talk bildete. Als P-T-Bedingungen beim Hbhepunkt der Metamorphose können Temperaturen von 640–700°C in einem angenommenen Druckbereich von 8-10 kbar abgeschätzt wurden, ähnlich wie sie auch aus den Mineralparagenesen in den angrenzenden Metabasiten and Metasedimenten der KTB-Vorbohrung ableitbar sind. Hochdruckrelikte, die gelegentlich in koronitischen Metagabbros and retrograd überprägten Eklogiten der KTB-Vorbohrung auftreten, wurden in den Hösbachiten nicht gefunden. Eine retrograde Überprägung unter grünschieferfaziellen Bedingungen führte zu einer vollständigen Verdrängung von magmatischem und metamorphem Olivin durch Aggregate von Antigorit + Magnetit, zur Chloritisierung von Biotit und zur Bildung einer späten Generation von Tremolit/ Aktinolith.

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