Rotational excitation of protonated hydrogen cyanide (HCNH+) by He atom at low temperature     

Christophe Nkem  Kamel Hammami  Idriss Yacoub Halalaw  Luc Calvin Owono Owono  Nejm-Eddine Jaidane 《Astrophysics and Space Science》2014,349(1):171-179

We report on ab initio coupled-cluster calculations of the interaction potential energy surface for the HCNH⁺–He complex. The aug-cc-pVTZ Gaussian basis, to which is added a set of bond functions placed at mid-distance between HCNH⁺ center of mass and He atom is used. The HCNH⁺ bonds length are set to their values at the equilibrium geometry, i.e., r _e [HC]=1.0780 Å, r _e [CN]=1.1339 Å and r _e [NH]=1.0126 Å. The interaction energy presents a global minimum located $266.9~\mathrm{cm^{-1}}$ below the HCNH⁺–He dissociation limit. Using the interaction potential obtained, we have computed rotational excitation cross sections in the close-coupling approach and downward rate coefficients at low temperature (T≤120 K). It is expected that the data worked out in this study may be beneficial for further astrophysical investigations as well as laboratory experiments.  相似文献   

Analysis of ‘infinitely long’ excavations using finite and boundary elements     

G. Beer  B. A. Poulsen 《国际地质力学数值与分析法杂志》1994,18(6):417-426

The paper deals with the analysis of excavations which are very long and can, for all practical purposes, be considered to be infinitely long. Special infinite finite and boundary elements are developed for the modelling of the infinitely long part of such excavations. Test examples are presented which show the accuracy which can be obtained by using these elements. Finally, examples of application in mining and petroleum engineering are shown.  相似文献   

The spatio-temporal development of Copenhagen’s bicycle infrastructure 1912–2013     

Trine Agervig Carstensen  Anton Stahl Olafsson  Nynne Marie Bech  Thea Schmidt Poulsen  Chunli Zhao 《Geografisk tidskrift / udgivet af Bestyrelsen for Det Kongelige danske geografiske selskab》2015,115(2):142-156

Cycling plays an important role in low-carbon transitions. Around the globe, cities are constructing bicycle infrastructure. The city of Copenhagen has a bicycle-friendly infrastructure celebrated for its fine-meshed network. This study documents the spatio-temporal development of Copenhagen’s bicycle infrastructure and explores how the development corresponds to other processes of urban transformation. The study builds on historical maps of bicycle infrastructure that are digitised into geographical information, which allows for a comprehensive analysis of the formation of the network. In search for identifying drivers, the study analyses the city’s spatial growth pattern, migration pattern, development of road network and changes in the transport culture. Analyses reveal that the bicycle infrastructure expanded at a relatively constant pace during distinct periods of urban transformation, including periods when the city suffered from spatial, economic and demographic decline, and dominance of car traffic. By discussing reasons and demands for constructing bicycle infrastructure, the study identifies four distinct periods in which bicycle infrastructure was constructed to enhance comfort and safety (first cycling city); the flow for cars (car city); urban liveability for soft transport (liveable city); and, finally, to improve the flow for cyclists as part a strategic re-design of urban space (liveable cycling city).  相似文献   

Sediment production and yield from an alluvial gully in northern Queensland,Australia   总被引：1，自引：0，他引：1  

Jeffrey G. Shellberg  Andrew P. Brooks  Calvin W. Rose 《地球表面变化过程与地形》2013,38(15):1765-1778

Sediment production, transport and yield were quantified over various timescales in response to rainfall and runoff within an alluvial gully (7 · 8 ha), which erodes into dispersible sodic soils of a small floodplain catchment (33 ha) along the Mitchell River, northern Australia. Historical air photographs and recent global positioning system (GPS) surveys and LiDAR data documented linear increases in gully area and volume, indicating that sediment supply has been relatively consistent over the historic period. Daily time lapse photography of scarp retreat rates and internal erosion processes also demonstrated that erosion from rainfall and runoff consistently supplied fine washload (< 63 µm) sediment in addition to coarse lags of sand bed material. Empirical measurements of suspended sediment concentrations (10 000 to >100 000 mg/L) and sediment yields (89 to 363 t/ha/yr) were high for both Australian and world data. Total sediment yield estimated from empirical washload and theoretical bed material load was dominated by fine washload (< 63 µm). A lack of hysteresis in suspended sediment rating curves, scarp retreat and sediment yield correlated to rainfall input, and an equilibrium channel outlet slope supported the hypothesis that partially or fully transport‐limited conditions predominated along the alluvial gully outlet channel. This is in contrast to sediment supply‐limited conditions on uneroded floodplains above gully head scarps. While empirical data presented here can support future modelling efforts to predict suspended sediment concentration and yield under the transport limiting situations, additional field data will also be needed to better quantify sediment erosion and transport rates and processes in alluvial gullies at a variety of spatial and temporal scales. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

A synthetic study of geophysics-based modelling of groundwater flow in catchments with a buried valley     

Theis Raaschou Andersen  Søren Erbs Poulsen  Steen Christensen  Flemming Jørgensen 《Hydrogeology Journal》2013,21(2):491-503

Groundwater models simulating flow in buried valleys interacting with regional aquifers are often based on hydrogeological models interpreted from dense geophysical datasets and scarce borehole data. For three simple synthetic cases, it is demonstrated that alternative methods of inversion of transient electro-magnetic (TEM) data can lead to very different interpretations of the hydrogeology inside and surrounding a buried valley. The alternative interpreted hydrogeological models are used in numerical modelling of groundwater flow to a pumping well. It is demonstrated that the alternative models result in quite different groundwater-model predictions of capture zone, recharge area, and groundwater age for the pumping well. It is briefly demonstrated that model calibration against hydraulic head data is not likely to improve the predictions or to identify the structural error of the interpreted hydrogeological models. It is therefore concluded that when TEM-based resistivity models are interpreted to construct the hydrogeological framework of a groundwater model, it must be done cautiously with support from deep borehole information. Too much reliance on geophysical mapping can lead to seriously wrong hydrogeological models and correspondingly wrong groundwater-model predictions.  相似文献   

The erosive growth of hillside gullies          下载免费PDF全文

Calvin W. Rose  Bofu Yu  Douglas P. Ward  Nina E. Saxton  Jon M. Olley  Errol K. Tews 《地球表面变化过程与地形》2014,39(15):1989-2001

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Contrasting definitions for the term ‘karst aquifer’     

Stephen R. H. Worthington  Pierre-Yves Jeannin  E. Calvin AlexanderJr  Gareth J. Davies  Geary M. Schindel 《Hydrogeology Journal》2017,25(5):1237-1240

It is generally considered that karst aquifers have distinctly different properties from other bedrock aquifers. A search of the literature found five definitions that have been proposed to differentiate karst aquifers from non-karstic aquifers. The five definitions are based upon the presence of solution channel networks, hydraulic conductivities >10^?6 m/s, karst landscapes, channels with turbulent flow, and caves. The percentage of unconfined carbonate aquifers that would classify as ‘karst’ ranges from <1 to >50%.  相似文献   

Mapping acidic mine waste with seasonal airborne hyperspectral imagery at varying spatial scales     

Gwendolyn E. Davies  Wendy M. Calvin 《Environmental Earth Sciences》2017,76(12):432

Airborne imaging spectrometer (also known as hyperspectral) remote sensing has been widely used to characterize mineralogy on mine waste surfaces, which is useful for predicting potential sources of acidity and metal leaching. The most successful applications employ fine spatial resolution—20-m pixels or smaller. Future satellite imaging spectrometer sensors are proposed to provide coarser spatial resolution—30- to 60-m pixels. This study examined the ability to map minerals related to acid mine drainage with visible to shortwave infrared hyperspectral imagery at varying spatial scales (2-, 15-, 30-, 60-m pixels) at the Leviathan mine Superfund site, located in the Eastern Sierra Nevada. Mineral maps were produced using spectral angle mapper and matched filtering algorithms. The 15-m images provided comparable maps to the 2-m images. The 30- and 60-m images lost the ability to identify smaller features; however, they were still able to identify high- and low-priority remediation zones at least 75 m in width. Based on our results, we believe 30-m spatial resolution on a satellite hyperspectral sensor will be sufficient for identifying hazardous surfaces at larger mine waste sites and provide important reconnaissance information that can help prioritize detailed ground-based studies.  相似文献   

Role of the bedrock topography in the Quaternary filling of a giant estuarine basin: the Lower St. Lawrence Estuary,Eastern Canada     

Mathieu J. Duchesne  Nicolas Pinet  Karine Bédard  Guillaume St‐Onge  Patrick Lajeunesse  D. Calvin Campbell  Andrée Bolduc 《Basin Research》2010,22(6):933-951

The geometry of estuarine and/or incised‐valley basins and their protected character compared with open sea basins are favourable for the preservation of sedimentary successions. The Lower St. Lawrence Estuary Basin (LSLEB, eastern Canada) is characterized by a thick (>400 m in certain areas) Quaternary succession. High‐ and very high‐resolution seismic reflection data, multibeam bathymetry coverage completed by core and chronostratigraphic data as well as a 3‐D seismic stratigraphic model are used to document the geometrical relationships between the bedrock and the Quaternary units of the LSLEB. The bedrock geometry of LSLEB is characterized by two large troughs that are interpreted as resulting mainly from repeated (?) periods of glacial overdeepening of a pre‐Quaternary drainage system. However, other mechanisms with complex feedback effects such as differential glacio‐isostatic uplift, erosion, sedimentary supply, and subsidence may have contributed to the formation of bedrock troughs. The two large bedrock troughs are mostly filled by ～200 m thick Wisconsinan (Marine Isotopic Stages 2–4) and possibly older sediments. Overlying units recorded the retreat of the Laurentian Ice Sheet during the Late Wisconsinan (Marine Isotopic Stage 2) and estuarine conditions during the Holocene. The strong correlation existing between the bedrock topography and the thickness of the Quaternary succession is indicative of the effectiveness of the LSLEB as a sediment trap.  相似文献   

Pollen sequence from the Chilean Lake District during the Llanquihue glaciation in marine Oxygen Isotope Stages 4–2     

Calvin J. Heusser  Thomas V. Lowell  Linda E. Heusser  Andrs Moreira M.  Simn Moreira M. 《第四纪科学杂志》2000,15(2):115-125

Pollen stratigraphy of a core taken from a fen at Fundo Nueva Braunau (40°17.49′S, 73°04.83′W), situated 2 km beyond the western border of Llanquihue‐age glacial drift, spans an age range from an estimated 60 000–70 000 BP to about 14 000 ¹⁴C yr BP (marine Oxygen Isotope Stages 4–2). The location at present is in the contact zone of Valdivian Evergreen Forest and Lowland Deciduous Beech Forest. Early and late in the pollen record, as indicated by assemblages of southern beech (Nothofagus dombeyi type) and grass (Gramineae), the site was located in Subantarctic Parkland. Intervening assemblages represent expansion of Valdivian–North Patagonian Evergreen Forest (> 49 355 to about 40 000 ¹⁴C yr BP) and North Patagonian Evergreen Forest–Subantarctic Parkland (approximately 40 000 to 30 000 ¹⁴C yr BP). Climate over the time span was under the storm regime of the Southern Westerlies and apparently uninterruptedly wet. When Subantarctic Parkland expanded, cold conditions with summer temperatures estimated at 8–9°C (7°C lower than present) resulted in episodes of glacier maxima. Climate moderated during the period of forest expansion, at which time glaciers were in a state of recession. Contrasting with the continuously wet climate of the Lake District for the period of record, climate in semi‐arid–arid, subtropical Chile underwent extended intervals of precipitation. Data from both the terrestrial and marine realm implicate the Southern Westerlies as the cause of intensified storm activity at lower latitudes. Copyright © 2000 John Wiley & Sons, Ltd.  相似文献