Sea,freshwater or saltpans? Foraging ecology of terns to assess mercury inputs in a wetland landscape: The Ebro Delta     

Javier Cotin  Manuel García-Tarrasón  Carolina Sanpera  Lluis Jover  Xavier Ruiz 《Estuarine, Coastal and Shelf Science》2011

The Ebro catchment, the largest river basin in Spain, includes various heavily industrialized areas. Among these is the Flix site, where a chemical plant has been operating since the beginning of the 20th century. This extended operational period, together with the construction of a dam next to the factory around 1960, resulted in the accumulation of large amounts of heavily polluted sediments in the adjacent riverbed, many of which are contaminated by mercury. Pollutants from Flix are carried downstream by the Ebro River to its delta. In order to assess the transfer of mercury to the complex river estuary ecosystem, we studied the ecology of the tern community living there as these birds segregate into a range of habitats. For this purpose, first we used stable isotope analysis (SIA) (δ³⁴S, δ¹³C, δ¹⁵N) of eggs to determine the trophic ecology and habitat partitioning of several tern species (Common, Sandwich, Little, Gull-Billed and Whiskered Tern) breeding sympatrically, in order to link their foraging ecology with habitat types. Next we measured mercury concentrations in eggs to monitor the input of this metal into the diverse habitats. With the exception of the Little Tern, the other terns used a restricted habitat range in the Ebro Delta, as shown by C and S isotopes; the Gull-Billed and Whiskered Tern foraged in freshwater habitats, while the Common and Sandwich Tern used marine habitats. This restricted feeding behavior of the Gull-Billed and Common Tern contrasts with previous reports in other breeding sites. The Little Tern, which showed a wide range of isotopic values, was found to be an opportunistic forager but fed mainly in saltpans, a feeding habitat not reported previously for this species in this area. We found that mercury concentrations are related to foraging habitat and diet, and are unexpectedly higher in species feeding on demersal prey in marine habitats and also higher in birds feeding in saltpans than in those feeding in freshwater habitats. The mercury concentrations found in the Little and Common Tern eggs sampled in “Punta de la Banya” may be sufficiently high to endanger breeding success.  相似文献   

Performance enhancement of a GIS-based facility location problem using desktop grid infrastructure     

Andrés García García  Carolina Perpiñá  Carlos de Alfonso  Vicente Hernández 《Earth Science Informatics》2013,6(4):199-207

This paper presents the integration of desktop grid infrastructure with GIS technologies, by proposing a parallel resolution method in a generic distributed environment. A case study focused on a discrete facility location problem, in the biomass area, exemplifies the high amount of computing resources (CPU, memory, HDD) required to solve the spatial problem. A comprehensive analysis is undertaken in order to analyse the behaviour of the grid-enabled GIS system. This analysis, consisting of a set of the experiments on the case study, concludes that the desktop grid infrastructure is able to use a commercial GIS system to solve the spatial problem achieving high speedup and computational resource utilization. Particularly, the results of the experiments showed an increase in speedup of fourteen times using sixteen computers and a computational efficiency greater than 87 % compared with the sequential procedure.  相似文献   

Preservation of high‐P rocks coupled to rock composition and the absence of metamorphic fluids     

Alasdair Skelton  Alexandre Peillod  Johannes Glodny  Iwona Klonowska  Carolina Mnbro  Karin Lodin  Uwe Ring 《Journal of Metamorphic Geology》2019,37(3):359-381

Eclogites, blueschists and greenschists are found in close proximity to one another along a 1‐km coastal section where the Cyclades Blueschist Unit (CBU) is exposed on SE Syros, Greece. Here, we show that the eclogites and blueschists experienced the same metamorphic history: prograde lawsonite blueschist facies metamorphism at 1.2–1.9 GPa and 410–530°C followed, at 43–38 Ma, by peak blueschist/eclogite facies metamorphism at 1.5–2.1 GPa and 520–580°C. We explain co‐existence of eclogites and blueschists by compositional variation probably reflecting original compositional layering. It is also shown that the greenschists record retrogression at 0.34 ± 0.21 GPa and T = 456 ± 68°C. This was spatially associated with a shear zone on a scales of 10–100‐m and veins on a scale of 1–10‐cm. Greenschist facies metamorphism ended at (or shortly after) 27 Ma. We thus infer a period of metamorphic quiescence after eclogite/blueschist facies metamorphism and before greenschist facies retrogression which lasted up to 11–16 million years. We suggest that this reflects an absence of metamorphic fluid flow at that time and conclude that greenschist facies retrogression only occurred when and where metamorphic fluids were present. From a tectonic perspective, our findings are consistent with studies showing that the CBU is (a) a high‐P nappe stack consisting of belts in which high‐P metamorphism and exhumation occurred at different times and (b) affected by greenschist facies metamorphism during the Oligocene, prior to the onset of regional tectonic extension.  相似文献   

Aqueous Surfactant Washing of Residual Oil Contamination from Sandy Soil   总被引：2，自引：0，他引：2  

Carolina C. Ang  Abdul S. Abdul 《Ground Water Monitoring & Remediation》1991,11(2):121-127

A laboratory study was conducted to determine the efficiency of different aqueous concentrations of an alcohol ethoxylate surfactant in washing residual levels of an oil [automatic transmission fluid (ATF)] from sandy soil. Five glass columns packed with the soil were prepared in a manner that simulated conditions leading to residual saturation in an actual oil leak. Each of four columns was washed continuously with 28 pore volumes of solution by pumping either 0.0 percent (water), 0.5 percent, 1.0 percent, or 2.0 percent aqueous surfactant solutions through the columns. The fifth column was washed intermittently with 28 pore volumes of a 1.0 percent surfactant solution. Water washed only 25.5 percent of the ATF from the column soil, while the 0.5 percent, 1 percent, and 2 percent surfactant solutions washed 55 percent, 60 percent, and 72.8 percent of the ATF, respectively. The distribution of the ATF remaining in the column after washing showed that the ATF removed by water was mainly from the outlet side of the column, while the ATF removed by the 2.0 percent surfactant solution was mainly from the inlet side of the column. This observation indicated that different mechanisms were involved; namely, the displacement of oil through the soil-pore space, the dispersion of oil due to reduced surface tension, and the solubilization of oil by surfactant micelles. In the case of water, the displacement of oil was the main washing mechanism, while all three mechanisms were operative during surfactant washing. ATF dispersion and solubilization were improved at higher surfactant concentrations. The column that was washed intermittently to pulse ATF from dead end pores did not show a significant improvement over the column that was continuously washed with the same 1.0 percent surfactant solution. The results show promising potential for application in the field and will be further investigated in a two-dimensional model aquifer.  相似文献   

Abundance and distribution of fluoride concentrations in groundwater: La Ballenera catchment,southeast of Buenos Aires Province,Argentina     

Carolina Calvi  Daniel Martinez  Cristina Dapeña  Florencia Gutheim 《Environmental Earth Sciences》2016,75(6):534

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A grain-size correction for metal pollution indexes in river sediments     

Thomas Vincent Gloaguen  Paula Núbia Soares Dalto Motta  Carolina Fonseca Couto 《国际泥沙研究》2021,36(3):362-372

According to the List of Hazardous Substances of the Agency of the Toxic Substances and Disease Registry(ATSDR 2017),some metallic elements such as Pb or Cd are still considered as the most polluting elements in the world.These elements accumulate in sediments,and there are various methods available that differentiate lithogenic sources from anthropogenic sources.For that,the natural geochemical background is required,however,its definition is far from unanimous:it can be a global or local value,single or statistically estimated value,depending on the studies.Our study is focused on the Suba
e River in the state of Bahia,Northeastern Brazil,which was historically contaminated by lead metallurgy.The river sediments were sampled at 21 locations:one at the discharge point of the plant's rainwater basin,ten upstream,and ten downstream.The total contents of Fe,Ti,Mn,Pb,Zn,Cu,Cr,particle-size distribution,and organic matter were analyzed.The conventional geochemical indexes,i.e.,the pollution degree(mCd),pollution load index,and enrichment factor indicated contamination by Zn,Pb,Cr,and Cu.Then,a new enrichment factor is introduced,assuming that the sediments come from erosion of soils in the watershed.After obtaining the natural concentrations of metals in the clay,silt,and sand fractions of uncontaminated reference soils,we corrected the pollution indexes by calculating a new individual background in each sediment sample,according to its grain size distribution.This new approach provided more precise indexes in the assessment of sediment pollution,by highlighting higher contamination of Zn and Pb(around 50%)and at the same time the absence of Cr and Cu contamination,two metals not involved with the metallurgical activity.  相似文献   

The Na i D resonance lines in main-sequence late-type stars     

Rodrigo F. Díaz  Carolina Cincunegui  Pablo J. D. Mauas 《Monthly notices of the Royal Astronomical Society》2007,378(3):1007-1018

We study the sodium D lines (D1: 5895.92 Å; D2: 5889.95 Å) in late-type dwarf stars. The stars have spectral types between F6 and M5.5 ( B − V between 0.457 and 1.807) and metallicity between  [Fe/H]=−0.82  and 0.6. We obtained medium-resolution echelle spectra using the 2.15-m telescope at the Argentinian observatory Complejo Astronómico El Leoncito (CASLEO). The observations have been performed periodically since 1999. The spectra were calibrated in wavelength and in flux. A definition of the pseudo-continuum level is found for all our observations. We also define a continuum level for calibration purposes. The equivalent width of the D lines is computed in detail for all our spectra and related to the colour index ( B − V ) of the stars. When possible, we perform a careful comparison with previous studies. Finally, we construct a spectral index  ( R '_D)  as the ratio between the flux in the D lines and the bolometric flux. We find that, once corrected for the photospheric contribution, this index can be used as a chromospheric activity indicator in stars with a high level of activity. Additionally, we find that combining some of our results, we obtain a method to calibrate in flux stars of unknown colour.  相似文献   

Using historical source data to understand urban flood risk: a socio-hydrological modelling application at Gregório Creek,Brazil     

Ana Carolina Sarmento Buarque  Namrata Bhattacharya-Mis  Maria Clara Fava  Felipe Augusto Arguello de Souza  Eduardo Mario Mendiondo 《水文科学杂志》2020,65(7):1075-1083

ABSTRACT

The city of São Carlos, state of São Paulo, Brazil, has a historical coexistence between society and floods. Unplanned urbanization in this area is a representative feature of how Brazilian cities have developed, undermining the impact of natural hazards. The Gregório Creek catchment is an enigma of complex dynamics concerning the relationship between humans and water in Brazilian cities. Our hypothesis is that social memory of floods can improve future resilience. In this paper we analyse flood risk dynamics in a small urban catchment, identify the impacts of social memory on building resilience and propose measures to reduce the risk of floods. We applied a socio-hydrological model using data collected from newspapers from 1940 to 2018. The model was able to elucidate human–water processes in the catchment and the historical source data proved to be a useful tool to fill gaps in the data in small urban basins.  相似文献   

Central Chile: An example of quasi-static crustal behavior     

Sergio E.  Barrientos 《Island Arc》1997,6(3):281-287

Abstract Indications of transient crustal displacement associated with the 3 March 1985, M, = 7.8, Central Chile earthquake are evidenced by various observational devices. Almost half a meter of coastal uplift at localities close to the epicentral region was detected by repeated leveling lines. A tide gauge at Valparaiso revealed minor coseismic coastal subsidence (∼ 10 cm) continuously developing after the earthquake. Two limnigraphs, 27 km apart, that were situated at the extremes of Rapel Lake to the south of the leveling line, have recorded continuously the equipotential lake level for more than 10 years, providing a permanent very-long-base tiltmeter. The water level difference at the two limnigraphs as a function of time resembles a ramp function, beginning approximately at the time of the earthquake occurrence and gradually developing over a period of 10 months with a maximum amplitude of 120 mm or 4.4 p radians in tilt. The shape of the time-dependent tilt is mimicked by the sea level signal recorded at Valparaiso, ∼ 100 km away from Rapel Lake, showing a maximum coastal subsidence of 0.6 m. Comparisons of sea level changes produced by the 1971, M, = 7.5, earthquake indicates that they represent rupture in different portions along the seismogenetic region as well as a different rupture mode. Gravity surveys carried out in three different pre- and post-seismic epochs, along the segment of the leveling line which shows major coseismic uplift, indicate that the whole region has subsided, post-seismically, 10 em in 5 years. These observations are interpreted in terms of a variable slip dislocation model. Inversions show that it is the more than 2 m of fault displacement in 10 months of post-seismic movement along the contact between the Nazca and South America plates, which is interpreted to be responsible for the time-dependent elevation changes.  相似文献   

Long term variation in rainfall erosivity in Uruguay: a preliminary Fournier approach     

Carolina Munka  Gabriela Cruz  Ruben Mario Caffera 《GeoJournal》2007,70(4):257-262

In order to explore the consequences of precipitation increase on soil erosion in Uruguay, the monthly Fournier Index (FI) and the annual Modified Fournier Index (MFI) were developed as a preliminary approach, covering consecutive decadal periods from 1931 to 2000. Rainfall data were used from 13 stations distributed all over the country. MFI shows a decrease in the 1940s, an increase during the 1950s, then a little decrease during the 1960s and 1970s and an increase in the 1980s, remaining near these last values during the 1990s. FI behavior in July and October in the last two decades shows a decrease in the Northeast region of the country—the region with highest annual precipitation—and a slight increase over the Southeast—the region with the lowest annual precipitation and the only region with a winter rainfall maximum. For the core months of winter and early spring there is a decline in erosivity in the Northeast, but an increase in the Southeast. January shows erosivity decreasing in the South during the last two decades. In April there is a peak in precipitation variability all across the country. FI shows an early increase during the 1940s in the Northwest, and generally very low values during the 1970s, with the return of high values in the 1990s, especially in the Northern corner. Results pose a challenge in order to improve research on the erosion problem, since the main source of freshwater nationwide remains surface river flow, which is prone to higher turbidity problems in areas of high soil erosion.  相似文献