Ruthenium-ion-catalyzed oxidation of asphaltenes and oil-source correlation of heavy oils from the Lunnan and Tahe oilfields in the Tarim Basin, NW China     

马安来张水昌  张大江金之钧马晓娟  陈清棠 《中国地球化学学报》2005,24(1):28-36

The identification of marine source rocks in the Tarim Basin is debated vigorously. The intention of this paper is to investigate the asphahenes in heavy oils from the Lunnan and Tabe oilfields and Well TD2 with ruthenium-ions-catalyzed oxidation technique (RICO), in order to explore its role in oil-oil and oil-source correlations, The RICO products included n-alkanoic acids, α,ω-di-n-alkanoic acids, branched alkanoic acids, tricyclic terpanoic acids, hopanoic acids, gammacerane carboxylic acid , regular sterane carboxylic acids and 4-methylsterane carboxylic acids. The n-alkyl chains and biomarkers bounded on the asphaltenes were of unsusceptibility to biodegradation. The distribution and absolute concentrations of n-alkanoic acids in the RICO products of heavy oils from the Lunnan and Tabe oilfields are different from those of Well TD2. The biomarkers bounded on the asphahenes, especially steranes, have a distribution trend similar to that of the counterparts in saturates. The sterane carboxylic acids and 4-methylsterane carboxylic acids in the RICO products of heavy oils from the Lunnan and Tahe oilfields, dominated by C30 sterane and C31 4-methylsterane carboxylic acids, respectively, are significantly different from those of the heavy oils of Well TD2, whose dominating sterane and 4-methylsterane carboxylic acids are C28 sterane and C29 4-methylsterane acids, respectively. The RICO products of the asphaltenes further indicate that the Middle-Upper Ordovician may be the main source rocks for heavy oils from the Lunnan and Tabe oilfields.  相似文献   

Microorganisms in Lianxian lateritic gold deposit in Guangdong and their effects on leaching of heavy metals     

陈炳辉刘琥琥  毋福海徐文烈 《中国地球化学学报》2005,24(2):144-148

Microorganisms in the lateritic profiles of the Lianxian gold deposit in Guangdong were cultured, isolated and identified. The microorganisms include bacteria such as Bacillus, Enterobacter, Pseudomonas, Lactobacillus, Actinetobacter, Aeromona, Listeria, Agrobacteriura, Cotyttebacteriurn, and Moraxella, fungi such as Penicillium, Alter naria, Cladosporium, Saccharcornyces, Mucor, and the chemoautotrophic Thiobacillu.~. It is shown in a leaching experiment that the microorganisms can accelerate the leaching of Cu, Cd, Zn, and that the G- bacteria are most efficient for leaching Cu, Zn and the G^ bacteria are better for leaching Cd.  相似文献   

Hydrogeochemistry of karst underground waters at shallow depth in Guiyang City, Guizhou Province     

董志芬  朱立军吴攀沈峥  封志勇 《中国地球化学学报》2005,24(2):194-200

The aim of this study is to shed light on the hydrogeochemical characteristics of karst underground waters at shallow depth in Guiyang City, Guizhou Province with an emphasis on the geochemistry of major elements. Guiyang City bears abundant underground waters and it is also an important representative of the karst areas throughout the world. Ca^2 and Mg^2 are the dominant cations, accounting for 81% -99.7% of the total, and HCO3^- and SO4^2- are the dominant anions. Weathering of limestones and dolostones is the most important factor controlling the hydrogeochemistry of underground waters, and weathering of sulfate and evaporite rocks is less important. Moreover, the precipitation and human activities also have a definite influence on the hydrogeoehemistry of underground waters in the region studied.  相似文献   

Hydrological excitations of polar motion, 1993–2002     

J. L. Chen  C. R. Wilson 《Geophysical Journal International》2005,160(3):833-839

  相似文献   

云南东北部拱王山末次冰期   总被引：1，自引：0，他引：1  

张威  崔之久  冯金良  YI Chaolu  YANG Jianqiang 《地理学报(英文版)》2005,15(4):448-458

1 Introduction The Gongwang mountains constitute one of the few high m ountains of irrefutable late Pleistocene glaciation in eastern China. This area is one of the m ost extensively studied Quaternary geologicallocationsin eastern China and the interpret…  相似文献   

Interannual Variability in Pollen Dispersal and Deposition on the Tropical Quelccaya Ice Cap*     

Carl A. Reese  Kam‐biu Liu 《The Professional geographer》2005,57(2):185-197

Pollen collected from snow samples on the Quelccaya Ice Cap in 2000 and 2001 reveals significant interannual variability in pollen assemblage, concentration, and provenance. Samples from 2000, a La Niña year, contain high pollen concentrations and resemble samples from the Andean forests (Yungas) to the east. Samples from 2001, an El Niño year, contain fewer pollen and resemble those from the Altiplano. We suggest that varying wind patterns under different El Niño/Southern Oscillation (ENSO) conditions may affect the processes of pollen transport over the Altiplano and on the ice cap, although confounding variables such as flowering phenology and sublimation should also be considered  相似文献   

The effects of land use on runoff and soil nutrient losses in a gully catchment of the hilly areas： implications for erosion control   总被引：1，自引：0，他引：1  

WANG Jun FU Bojie QIU Yang CHEN Liding CHEN Chen HU Baodong 《地理学报(英文版)》2005,15(4):396-404

1 Introduction Soiland waterlossisoneofthe worldwide environm entalissuesthreatening sustainable land use in semiarid areas.However,soiland water loss is highly variable in space and time,and its variability resultsfrom m any factorsoperating ata wide ran…  相似文献   

Climatic response of thick leaf spruce (Picea crassifolia) tree-ring width at different elevations over Qilian Mountains, northwestern China   总被引：3，自引：0，他引：3  

X. Gou  F. Chen  M. Yang  J. Li  J. Peng  L. Jin 《Journal of Arid Environments》2005,61(4):513-524

Tree-ring cores of thick leaf spruce (Picea crassifolia) taken from four sites at different elevations, in the middle of the Qilian Mountains, in the arid and semi-arid region of northwestern China, were used to develop four tree-ring width chronologies using standard dendrochronological methods. Results indicate that with increasing altitude the chronologies’ year-to-year variations decreased. Hence, the sensitivity of the tree-ring chronologies to climate decreases with altitude. Further analysis showed that the significant limiting factor on tree growth is spring precipitation. Measurements of stomata density and leaf dry weight suggest the species’ ecological adaptation strategy changes with elevation. At high elevation the metabolic rate of thick leaf spruce decreases, thus showing the effect of the climate.  相似文献   

Gas accumulation from oil cracking in the eastern Tarim Basin: A case study of the YN2 gas field     

Wenzhi Zhao  Shuichang Zhang  Feiyu Wang  Jianping Chen  Zhongyao Xiao  Fuqing Song 《Organic Geochemistry》2005,36(12):1602-1616

Oil and gas exploration in eastern Tarim Basin, NW China has been successful in recent years, with several commercial gas accumulations being discovered in a thermally mature to over-mature region. The Yingnan2 (YN2) gas field, situated in the Yingnan structure of the Yingjisu Depression, produces gases that are relatively enriched in nitrogen and C₂₊ alkanes. The δ¹³C₁ (−38.6‰ to −36.2‰) and δ¹³C₂ values (−30.9‰ to −34.7‰) of these gases are characteristic of marine sourced gases with relatively high maturity levels. The distributions of biomarkers in the associated condensates suggest close affinities with the Cambrian–Lower Ordovician source rocks which, in the Yingjisu Sag, are currently over-mature (with 3–4%Ro). Burial and thermal maturity modeling results indicate that paleo-temperatures of the Cambrian–Lower Ordovician source rocks had increased from 90 to 210 °C during the late Caledonian orogeny (458–438 Ma), due to rapid subsidence and sediment loading. By the end of Ordovician, hydrocarbon potential in these source rocks had been largely exhausted. The homogenization temperatures of hydrocarbon fluid inclusions identified from the Jurassic reservoirs of the YN2 gas field suggest a hydrocarbon emplacement time as recent as about 10 Ma, when the maturity levels of Middle–Lower Jurassic source rocks in the study area were too low (<0.7%Ro) to form a large quantity of oil and gas. The presence of abundant diamondoid hydrocarbons in the associated condensates and the relatively heavy isotopic values of the oils indicate that the gases were derived from thermal cracking of early-formed oils. Estimation from the stable carbon isotope ratios of gaseous alkanes suggests that the gases may have been formed at temperatures well above 190 °C. Thus, the oil and gas accumulation history in the study area can be reconstructed as follows: (1) during the late Caledonian orogeny, the Cambrian–Lower Ordovician marine source rocks had gone through the peak oil, wet gas and dry gas generation stages, with the generated oil and gas migrating upwards along faults and fractures to form early oil and gas accumulations in the Middle–Upper Ordovician and Silurian sandstone reservoirs; (2) since the late Yanshanian orogeny, the early oil accumulations have been buried deeper and oil has undergone thermal cracking to form gas; (3) during the late Himalayan orogeny, the seals for the deep reservoirs were breached; and the gas and condensates migrated upward and eventually accumulating in the relatively shallow Jurassic reservoirs.  相似文献   

Land degradation in the source region of the Yellow River, northeast Qinghai-Xizang Plateau: classification and evaluation   总被引：6，自引：0，他引：6  

Jianmin Feng  Tao Wang  Shanzhong Qi  Changwei Xie 《Environmental Geology》2005,47(4):459-466

Land degradation imposes a great threat to the world. It is not merely an environmental issue, but also a social and economic problem. Land desertification is among the main aspects of environment changes in the source region of the Yellow River. Previous studies focused on water resource utilization and soil erosion, but land degradation in the source region of the Yellow River even the whole Qinghai-Xizang Plateau received little attention. Based on the data obtained by field investigation and TM satellite images of 2000, this study provides the classification and evaluation information of the land degradation in the source region of the Yellow River. There are six types of land degradation in this region: water erosion in the northern mountains around the Gonghe Basin, sandy desertification in the Gonghe Basin and Upland Plain Area, aridization in the lower reaches, salinization in the Gonghe Basin, vegetation degradation in the intramontance basin and freezing and thawing erosion in the high mountains. The total degraded area is 34,429.6 km², making up 37.5% of the land in the study area. Finally, land degradation in the source region of the Yellow River was evaluated according to changes in the physical structure and chemical component of soils, land productivity, secondary soil salt and water conditions.  相似文献