Mineralogy,geochemistry and petrogenesis of the Khopoli mafic intrusion,Deccan Traps,India     

Ciro Cucciniello  Ashwini Kumar Choudhary  Alberto Zanetti  Hetu C. Sheth  Shreyas Vichare  Rohan Pereira 《Mineralogy and Petrology》2014,108(3):333-351

The Khopoli intrusion, exposed at the base of the Thakurvadi Formation of the Deccan Traps in the Western Ghats, India, is composed of olivine gabbro with 50–55 % modal olivine, 20–25 % plagioclase, 10–15 % clinopyroxene, 5–10 % low-Ca pyroxene, and <5 % Fe-Ti oxides. It represents a cumulate rock from which trapped interstitial liquid was almost completely expelled. The Khopoli olivine gabbros have high MgO (23.5–26.9 wt.%), Ni (733–883 ppm) and Cr (1,432–1,048 ppm), and low concentrations of incompatible elements including the rare earth elements (REE). The compositions of the most primitive cumulus olivine and clinopyroxene indicate that the parental magma of the Khopoli intrusion was an evolved basaltic melt (Mg# 49–58). Calculated parental melt compositions in equilibrium with clinopyroxene are moderately enriched in the light REE and show many similarities with Deccan tholeiitic basalts of the Bushe, Khandala and Thakurvadi Formations. Nd-Sr isotopic compositions of Khopoli olivine gabbros (εNd_t?=??9.0 to ?12.7; ⁸⁷Sr/⁸⁶Sr?=?0.7088–0.7285) indicate crustal contamination. AFC modelling suggests that the Khopoli olivine gabbros were derived from a Thakurvadi or Khandala-like basaltic melt with variable degrees of crustal contamination. Unlike the commonly alkalic, pre- and post-volcanic intrusions known in the Deccan Traps, the Khopoli intrusion provides a window to the shallow subvolcanic architecture and magmatic processes associated with the main tholeiitic flood basalt sequence. Measured true density values of the Khopoli olivine gabbros are as high as 3.06 g/cm³, and such high-level olivine-rich intrusions in flood basalt provinces can also explain geophysical observations such as high gravity anomalies and high seismic velocity crustal horizons.  相似文献   

Carbon capture and sequestration versus carbon capture utilisation and storage for enhanced oil recovery   总被引：1，自引：1，他引：0  

Bob Harrison  Gioia Falcone 《Acta Geotechnica》2014,9(1):29-38

There are 74 integrated carbon capture projects worldwide currently listed by the Global CCS Institute, including the few already running and those still at the identification, evaluation, definition or execution stage for operation by 2018. Significant funding programmes have recently been launched by the European Commission (NER300 in November 2011) and by the UK Department of Energy and Climate Change (CCS Commercialisation Programme in April 2012) for commercial demonstration projects leading to innovation across the CCS/CCUS technology chain to reduce energy system costs. In their calls for proposals, these programmes were open to both CCS and CCUS projects. However, there are significant technical and commercial differences between projects for enhanced oil recovery and those for permanent storage of carbon dioxide in saline aquifers or in depleted hydrocarbon reservoirs, the same way that there exist more complexities and limitations for offshore implementation. Such differences are accompanied by different levels of field verification of the various storage and utilisation concepts, with permanent sequestration having only a more recent history and smaller-scale implementation. In this scenario, the need for appropriate due diligence workflows and screening criteria to assess the technical viability and the deliverability of different CCS/CCUS projects remains crucial, vis-à-vis the high component costs, efficiency penalties, reservoir uncertainties and the many challenges related to full chain integration (from carbon dioxide capture to underground sequestration). Based on information in the public domain, this paper reviews the current status of offshore CCS/CCUS implementation worldwide and discusses screening criteria for use by governments, operators and investors alike.  相似文献   

Geology,mineralogy and geochemistry of the Kekem dyke swarm (Western Cameroon): Insights into Paleozoic–Mesozoic magmatism and geodynamic implications     

Depesquidoux Tchato Tchaptchet  Nicole Armelle Simeni Wambo  Noël Aimé Keutchafo Kouamo  Jean-Pierre Tchouankoué  Ciro Cucciniello 《Comptes Rendus Geoscience》2017,349(4):175-185

The broadly N70°–90°E-trending dykes swarm at Kekem cut across the Paleoproterozoic-to-Achean terranes of West Cameroon remobilized during the Pan-African orogeny. They are picrite basalts and basalts with tholeiitic/transitional affinity, as shown by mineralogical and geochemical data, with variable major and trace element contents, MgO ranges from 7.3 to 12.4 wt.%, Cr from 190 to 411 ppm, Ni from 15 to 234 ppm. All the dykes are light REE enriched with La_N/Yb_N values of 5.3–8.1, suggesting a co-magmatic origin. They originated from a 2.8% partial melting of a spinel-mantle source with no or little crustal input. The geochemical features of Kekem dykes are similar to those of Paleozoic and Mesozoic dykes recorded in North and Central Africa, suggesting multiple reactivations of pre-existing fractures that resulted in the fragmentation of western Gondwana and the opening of Central and South Atlantic Oceans.  相似文献