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91.
The root‐zone moisture replenishment mechanisms are key unknowns required to understand soil hydrological processes and water sources used by plants. Temporal patterns of root‐zone moisture replenishment reflect wetting events that contribute to plant growth and survival and to catchment water yield. In this study, stable oxygen and hydrogen isotopes of twigs and throughfall were continuously monitored to characterize the seasonal variations of the root‐zone moisture replenishment in a native vegetated catchment under Mediterranean climate in South Australia. The two studied hillslopes (the north‐facing slope [NFS] and the south‐facing slope [SFS]) had different environmental conditions with opposite aspects. The twig and throughfall samples were collected every ~20 days over 1 year on both hillslopes. The root‐zone moisture replenishment, defined as percentage of newly replenished root‐zone moisture as a complement to antecedent moisture for plant use, calculated by an isotope balance model, was about zero (±25% for the NFS and ± 15% for the SFS) at the end of the wet season (October), increased to almost 100% (±26% for the NFS and ± 29% for the SFS) after the dry season (April and May), then decreased close to zero (±24% for the NFS and ± 28% for the SFS) in the middle of the following wet season (August). This seasonal pattern of root‐zone moisture replenishment suggests that the very first rainfall events of the wet season were significant for soil moisture replenishment and supported the plants over wet and subsequent dry seasons, and that NFS completed replenishment over a longer time than SFS in the wet season and depleted the root zone moisture quicker in the dry season. The stable oxygen isotope composition of the intraevent samples and twigs further confirms that rain water in the late wet season contributed little to root‐zone moisture. This study highlights the significant role of the very first rain events in the early wet season for ecosystem and provides insights to understanding ecohydrological separation, catchment water yield, and vegetation response to climate changes.  相似文献   
92.
Pyrite (FeS2) is the most abundant sulphide mineral in the Earth's crust, and with its characteristic shape and appearance, is easily one of the most recognizable. Yet, pyrite has a somewhat tarnished reputation with many considering it to be waste material and of little economic importance, never-mind interest. This assessment however, is misleading and a considerable volume of current research focuses upon the unique characteristics and formation of pyrite. Indeed, with its potential for revealing the very foundations of life, as well as maximizing the discovery and exploitation of society's future metallic resources, pyrite may be of much greater interest and benefit than many geologists realize.  相似文献   
93.
We present new Fe and Si isotope ratio data for the Torres del Paine igneous complex in southern Chile. The multi-composition pluton consists of an approximately 1 km vertical exposure of homogenous granite overlying a contemporaneous 250-m-thick mafic gabbro suite. This first-of-its-kind spatially dependent Fe and Si isotope investigation of a convergent margin-related pluton aims to understand the nature of granite and silicic igneous rock formation. Results collected by MC-ICP-MS show a trend of increasing δ56Fe and δ30Si with increasing silica content as well as a systematic increase in δ56Fe away from the mafic base of the pluton. The marginal Torres del Paine granites have heavier Fe isotope signatures (δ56Fe = +0.25 ± 0.02 2se) compared to granites found in the interior pluton (δ56Fe = +0.17 ± 0.02 2se). Cerro Toro country rock values are isotopically light in both Fe and Si isotopic systems (δ56Fe = +0.05 ± 0.02 ‰; δ30Si = ?0.38 ± 0.07 ‰). The variations in the Fe and Si isotopic data cannot be accounted for by local assimilation of the wall rocks, in situ fractional crystallization, late-stage fluid exsolution or some combination of these processes. Instead, we conclude that thermal diffusion or source magma variation is the most likely process producing Fe isotope ratio variations in the Torres del Paine pluton.  相似文献   
94.
The iron stable isotope compositions (δ56Fe) and iron valence states of ultrahigh‐pressure eclogites from Bixiling in the Dabie orogen belt, China, were measured to trace the changes of geochemical conditions during vertical transportation of earth materials, for example, oxygen fugacity. The bulk Fe3+/ΣFe ratios of retrograde eclogites, determined by Mössbauer spectroscopy, are consistently higher than those of fresh eclogites, suggesting oxidation during retrograde metamorphism and fluid infiltration. The studied eclogites (five samples) display limited mid‐ocean ridge basalts (MORB)‐like (~0.10‰) δ56Fe values, which are indistinguishable from their protoliths, that is, gabbro cumulates formed through differentiation of mantle‐derived basaltic magma. This suggests that Fe isotope fractionation during continental subduction is limited. Garnet separates display limited δ56Fe variation ranging from ?0.08 ± 0.07 ‰ to 0.02 ± 0.07‰, whereas coexisting omphacite displays a large variation of δ56Fe values from 0.15 ± 0.07‰ to 0.47 ± 0.07‰. Omphacite also has highly variable Fe3+/ΣFe ratios from 0.367 ± 0.025 to 0.598 ± 0.024, indicating modification after peak metamorphism. Omphacite from retrograde eclogites has elevated Fe3+/ΣFe ratios (0.54–0.60) compared to that from fresh eclogites (~0.37), whereas garnet displays a narrow range of ferric iron content with Fe3+/ΣFe ratios from 0.039 ± 0.013 to 0.065 ± 0.022. The homogenous δ56Fe values and Fe3+/ΣFe ratios of garnet suggest that it survived the retrograde metamorphism and preserved its Fe‐isotopic features and ferric contents of peak metamorphism. Because of similar diffusion rates of Fe and Mg in garnet and omphacite, and constant Δ26Mgomphacite‐garnet values (1.14 ± 0.04‰), equilibrium iron isotope fractionation between garnet and omphacite was probably achieved during peak metamorphism. Elevated Fe3+/ΣFe ratios of omphacite from retrograde eclogites and variant Δ56Feomphacite‐garnet values of the studied eclogites (0.13 ± 0.10‰ to 0.48 ± 0.10‰) indicate that oxidized geofluid infiltration resulted in the elevation of δ56Fe values of omphacite during retrograde metamorphism.  相似文献   
95.
Constraining global average temperatures to 2 °C above pre-industrial levels will probably require global energy system emissions to be halved by 2050 and complete decarbonization by 2100. In the nationally orientated climate policy framework codified under the Paris Agreement, each nation must decide the scale and method of their emissions reduction contribution while remaining consistent with the global carbon budget. This policy process will require engagement amongst a wide range of stakeholders who have very different visions for the physical implementation of deep decarbonization. The Deep Decarbonization Pathways Project (DDPP) has developed a methodology, building on the energy, climate and economics literature, to structure these debates based on the following principles: country-scale analysis to capture specific physical, economic and political circumstances to maximize policy relevance, a long-term perspective to harmonize short-term decisions with the long-term objective and detailed sectoral analysis with transparent representation of emissions drivers through a common accounting framework or ‘dashboard’. These principles are operationalized in the creation of deep decarbonization pathways (DDPs), which involve technically detailed, sector-by-sector maps of each country’s decarbonization transition, backcasting feasible pathways from 2050 end points. This article shows how the sixteen DDPP country teams, covering 74% of global energy system emissions, used this method to collectively restrain emissions to a level consistent with the 2 °C target while maintaining development aspirations and reflecting national circumstances, mainly through efficiency, decarbonization of energy carriers (e.g. electricity, hydrogen, biofuels and synthetic gas) and switching to these carriers. The cross-cutting analysis of country scenarios reveals important enabling conditions for the transformation, pertaining to technology research and development, investment, trade and global and national policies.

Policy relevance

In the nation-focused global climate policy framework codified in the Paris Agreement, the purpose of the DDPP and DDPs is to provide a common method by which global and national governments, business, civil society and researchers in each country can communicate, compare and debate differing concrete visions for deep decarbonization in order to underpin the necessary societal and political consensus to design and implement short-term policy packages that are consistent with long-term global decarbonization.  相似文献   
96.
97.
Dig-limit optimization is an operational decision making problem that significantly affects the value of open-pit mining operations. Traditionally, dig-limits have been drawn by hand and can be defined as classifying practical ore and waste boundaries suiting equipment sizes in a bench. In this paper, an optimization approach based on a genetic algorithm (GA) was developed to approximate optimal dig-limits on a bench, given grade control data, equipment constraints, processing, and mining costs. A case study was conducted on a sample disseminated nickel bench, in a two destination and single ore-type deposit. The results from using the GA are compared to hand-drawn results. The study shows that GA-based approach can be effectively used for dig-limit optimization.  相似文献   
98.
Local communities in the Gudbrandsdalen region in Norway are increasingly exposed to climate-induced hazards such as floods and landslides. A core question is how community members respond to climate change and what factors contribute to more resilient communities. The authors used a contextual approach to analyze data from semi-structured interviews along five dimensions. In Gaustad Muncipality they found that individuals’ motivation to adapt to climate change depended largely on subjective values such as identity, place attachment, cultural values, and social networks among individuals, which means it is crucial that strategic plans for adaptation to climate change at different policy levels are experienced as relevant by community members. While the studied community has experienced heavy floods in river systems and streams, little evidence of adaptation was observed. Instead, they appeared to adopt coping strategies. Landowners may have limited incentives to adapt to climate change due to contraproductive policy measures such as economic compensation for direct losses without requiring improved practices. Effective adaptation to climate change on the local level is likely to require making compensation mechanisms contingent upon landowners showing willingness to change from coping to adaptive practices, as well as a contextualized approach integrating local and scientific forms of knowledge.  相似文献   
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