Evidence of subduction and crust–mantle mixing from a single diamond     

Daniel J. Schulze  Ben Harte  John W. Valley  Dominic M.DeR. Channer 《Lithos》2004,77(1-4):349-358

Cathodoluminescence (CL) imaging of polished sections of a diamond from the Guaniamo region of Venezuela suggests a history of the diamond involving two periods of growth separated by a period of resorption and possibly brittle deformation. In situ electron probe analysis of multiple eclogitic garnet inclusions reveals a correlation between garnet composition and location in the stone. An early-formed garnet in the diamond core has higher Ca/(Ca+Mg) and lower Mg/(Mg+Fe) values than later garnets associated with the second period of diamond growth. This variation conforms to an extensive trend of variation in the suite of eclogitic garnets extracted from Venezuelan diamonds. The diamond is zoned in carbon isotope composition (in situ secondary ion mass spectrometry, SIMS, data). The core compositions (δ¹³C PDB), corresponding to the first stage of growth, average −17.7‰. The second period of growth is apparently in two sub-sets of CL zones with mean values of −13.0‰ and −7.9‰. Nitrogen contents of diamond are low (30–300 atomic ppm) and do not correlate with carbon isotope composition. Oxygen isotope ratios of the garnet inclusions are elevated substantially above those expected for “common mantle”; δ¹⁸O VSMOW of early garnet is approximately +10.5‰ and two late garnets average +8.8‰. The evolutionary trend of magnesium enrichment in garnet is unlikely to represent igneous fractionation. The stable isotope data are consistent with diamond formation in subducted meta-basic rocks that had interacted with sea water at low temperatures at or near the sea floor and contained a substantial biogenic carbon component. During or following subduction, diamonds continued to form in an evolving system that was progressively modified by interaction with mantle material.  相似文献   

Wave propagation and soil–structure interaction on a cliff crest during the 1999 Athens Earthquake     

Dominic Assimaki  Eduardo Kausel  George Gazetas   《Soil Dynamics and Earthquake Engineering》2005,25(7-10):513-527

During the 1999 Athens Earthquake the town of Adàmes, located on the eastern cliff of the Kifissos river canyon, experienced unexpectedly heavy damage. Despite the significant amplification potential of the slope geometry, topography effects cannot alone explain the uneven damage distribution within a 300 m zone behind the crest, characterized by a rather uniform structural quality. This paper illustrates the important role of soil stratigraphy, material heterogeneity, and soil–structure interaction on the characteristics of ground surface motion. For this purpose, we first perform elastic two-dimensional wave propagation analyses utilizing available geotechnical and seismological data, and validate our results by comparison with aftershock recordings. We then conduct non-linear time-domain simulations that include spatial variability of soil properties and soil–structure interaction effects, to reveal their additive contribution in the topographic motion aggravation.  相似文献   

Mass Spectrometry and reverse phase HPLC techniques for the identification of degraded fossil pigments in lake sediments and their application in palaeolimnology   总被引：3，自引：0，他引：3  

Dominic A. Hodgson  Simon W. Wright  Noel Davies 《Journal of Paleolimnology》1997,18(4):335-350

Accurate identification of fossil pigments is essential if they are to be used as biomarker compounds in palaeolimnological studies. In recent years High Performance Liquid Chromatography (HPLC) has greatly enhanced the efficiency with which fossil pigments can be characterised and quantified. Using HPLC, undegraded pigments are typically identified through retention times, absorbance spectra and co-chromatography with authentic reference standards. However, lake sediments may also contain degraded pigments for which there are often no standards, and which may be difficult to identify using HPLC alone. In this study, we submitted HPLC fractions of fossil pigments and pigment derivatives collected from a meromictic lake in south west Tasmania, to a combination of Mass Spectrometry (MS) techniques including Electron Impact (EI) and static Liquid Secondary Ion MS (LSIMS) to identify their molecular ion characteristics and organic chemical composition. Mass Spectrometry permitted the detection of specific mass ions which were used to verify the identity of pigments and their derivatives. These included five carotenoids, chlorophyll a and derivatives, three previously described bacteriochlorophyll c derivatives with molecular weights of 770, 784, and 802, and two undescribed derivatives of bacteriochlorophyll c with molecular weights of 766 and 788. With these improved identifications we speculate on the pathways and modes of pigment degradation in the lake and asses the value of the degraded pigments as biomarkers. The use of MS permitted the identification of a greater number of signature pigments of algal and bacterial communities thus increasing the palaeolimnological value of the sediments. These methods are best applied in fossil pigment studies where there are a large number of unknown pigments and pigment degradation products, and where there are no authentic standards for co-chromatography. Practical suggestions for pigment MS are included in the discussion.  相似文献   

Alkoxyquinoline O-dealkylation: A new fluorimetric assay for hydrocarbon-induced cytochrome P450 in fish     

M. Danny Burke  Douglas Brown  Richard T. Mayer  Dominic F.J. Houlihan 《Marine environmental research》1995,39(1-4)

The O-dealkylation of a new series of substrates, the alkoxyquinolines, provides a new easy fluorimetric assay for measuring the induction of cytochrome P450 by polycyclic aromatic hydrocarbons and drilling mud oil in fish. Expression of the results as a ratio between the inducible butyloxyquinoline O-dealkylation (BuQOD) activity and the non-inducible benzyloxyquinoline O-dealkylation (BeQOD) activity (i.e. the ‘BuQOD:-BeQOD quotient’) maximises the degree of induction measured and minimises the degree of inter-animal variation.  相似文献   

Paleolimnological records reveal biotic homogenization driven by eutrophication in tropical reservoirs     

Simone Wengrat  Andre A. Padial  Erik Jeppesen  Thomas A. Davidson  Luciane Fontana  Sandra Costa-Böddeker  Denise C. Bicudo 《Journal of Paleolimnology》2018,60(2):299-309

Biodiversity changes in response to eutrophication, climate variability and species invasions. These pressures have been shown to reduce community heterogeneity at various scales; however, how productivity drives homogenization patterns in a community of primary producers, such as diatoms, has not been studied. Using a dataset with good temporal resolution, obtained from cores collected from seven tropical reservoirs, we evaluated patterns of spatial and temporal homogenization, i.e. the trends in temporal α-diversity and spatial β-diversity (change in community composition), of diatom assemblages over the past 60–100 years. The paleolimnological records allowed us to study biodiversity trends since the initial community (reservoir construction) in those systems with low anthropogenic impact and also those undergoing eutrophication. No clear trend of spatial β-diversity change over time was found when all reservoirs were analyzed together. However, when only eutrophic reservoirs were considered, a marked decrease in the spatial β-diversity occurred, suggesting that eutrophication leads to homogenization of the diatom assemblage. These findings were reinforced by the lack of change in β-diversity when the age of the reservoirs was standardized, indicating that the reservoirs’ ontogeny did not influence the spatial β-diversity trend and β-diversity did not increase even in the reservoirs with low anthropogenic impact. In addition, the results showed a decrease of α-diversity over time for almost all the eutrophic reservoirs, as well as a decrease in the total species pool for the reservoirs, although periphytic diatoms may be favored by the appearance and sometimes mass development of floating macrophytes in warm, shallow eutrophic reservoirs. This study supports the role of eutrophication as one of the main drivers of diatom assemblage homogenization in tropical reservoirs, with a significant loss of species over time.  相似文献   

The impact of flood action groups on the uptake of flood management measures     

Ruth Dittrich  Anita Wreford  Adam Butler  Dominic Moran 《Climatic change》2016,138(3-4):471-489

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Discriminant analysis for the prediction of sand mass distribution in a holding pond using deposition thickness model of a single grain-sized particle     

Jeremy Andy Dominic  Ahmad Zaharin Aris  Wan Nor Azmin Sulaiman  Wan Zakaria Wan Md Tahir 《Environmental Earth Sciences》2016,75(9):812

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Amazon Expeditions: My Quest for the Ice-Age Equator - By Paul Colinvaux     

Sonia L  Fontana 《The Geographical journal》2009,175(1):87-87

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Beach profile evolution as an inverse problem     

Harshinie Karunarathna  Dominic E. Reeve  Mark Spivack   《Continental Shelf Research》2009,29(18):2234-2239

Beach evolution models are normally applied in a prognostic fashion, with parameters and boundary conditions estimated from previous experience or other forecasts. Here, we use observations of beach profiles to solve a beach profile evolution equation in an inverse manner to determine model parameters and source function. The data used to demonstrate the method are from Christchurch Bay in Dorset, UK. It was found that there is a significant contribution from diffusive processes to the morphodynamic evolution of the beach profiles and that the development and disappearance of near-shore coastal features such as upper beach berms and inter- and sub-tidal bars are well captured by the source function in the governing equation.  相似文献   

The formation of flocculated clay laminae in the sediments of a meromictic lake     

Dominic A. Hodgson 《Journal of Paleolimnology》1999,21(3):263-269

Sediments of Lake Fidler, a meromictic lake in south-west Tasmania, contain distinctive laminae. In order to determine their composition and formation, these laminae were studied using a combination of X- ray analysis, scanning electron microscopy, X-ray diffraction and vibrational spectrometry. Results indicated that the laminae were composed of clay originating from the adjacent Gordon River estuary. The clay was also found as part of the general sediment matrix of the core. The evidence indicates that the laminae are formed during incursions of brackish water from the adjacent Gordon River estuary into Lake Fidler which cause the flocculation of clay minerals in the water column. These clay minerals then sink rapidly to the sediments to form laminae. Although the formation of these laminae pre-dates meromixis, their mode of formation corroborates the theory that meromixis is maintained ectogenically by periodic inflows of brackish water replenishing monimolimnetic salts.  相似文献