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21.
22.
Solubility and dissolution rate of silica in acid fluoride solutions   总被引:1,自引:0,他引:1  
We performed 57 batch reactor experiments in acidic fluoride solutions to measure the dissolution rate of quartz. These rate data along with rate data from published studies were fit using multiple linear regression to produce the following non-unique rate law for quartz
where 10−5.13 < aHF < 101.60, −0.28 < pH < 7.18, and 298 < T < 373 K. Similarly, 97 amorphous silica dissolution rate data from published studies were fit by multiple linear regression to produce the following non-unique rate law for amorphous silica
where 10−2.37 < aHF < 101.61, −0.32 < pH < 4.76 and 296 < T < 343 K. Regression of the rates versus other combinations of solution species, e.g.  + H+, F + H+, HF + , HF + F, or  + F, produced equally good fits. Any of these rate laws can be interpreted to mean that the rate-determining step for silica dissolution in fluoride solutions involves a coordinated attack of a Lewis acid, on the bridging O atom and a Lewis base on the Si atom. This allows a redistribution of electrons from the Si–O bond to form a O–H group and a Si–FH group.  相似文献   
23.
The negative effective magnetic pressure instability discovered recently in direct numerical simulations (DNSs) may play a crucial role in the formation of sunspots and active regions in the Sun and stars. This instability is caused by a negative contribution of turbulence to the effective mean Lorentz force (the sum of turbulent and non-turbulent contributions) and results in the formation of large-scale inhomogeneous magnetic structures from an initially uniform magnetic field. Earlier investigations of this instability in DNSs of stably stratified, externally forced, isothermal hydromagnetic turbulence in the regime of large plasma ?? are now extended into the regime of larger scale separation ratios where the number of turbulent eddies in the computational domain is about 30. Strong spontaneous formation of large-scale magnetic structures is seen even without performing any spatial averaging. These structures encompass many turbulent eddies. The characteristic time of the instability is comparable to the turbulent diffusion time, L 2/?? t, where ?? t is the turbulent diffusivity and L is the scale of the domain. DNSs are used to confirm that the effective magnetic pressure does indeed become negative for magnetic field strengths below the equipartition field. The dependence of the effective magnetic pressure on the field strength is characterized by fit parameters that seem to show convergence for larger values of the magnetic Reynolds number.  相似文献   
24.
We have observed a total of 67 pulsars at five frequencies ranging from 243 to 3100 MHz. Observations at the lower frequencies were made at the Giant Metre-Wave Telescope in India and those at higher frequencies at the Parkes Telescope in Australia. We present profiles from 34 of the sample with the best signal-to-noise ratio and the least scattering. The general 'rules' of pulsar profiles are seen in the data; profiles get narrower, the polarization fraction declines and outer components become more prominent as the frequency increases. Many counterexamples to these rules are also observed, and pulsars with complex profiles are especially prone to rule breaking. We hypothesize that the location of pulsar emission within the magnetosphere evolves with time as the pulsar spins down. In highly energetic pulsars, the emission comes from a confined range of high altitudes, in the middle range of spin down energies the emission occurs over a wide range of altitudes whereas in pulsars with low spin-down energies it is confined to low down in the magnetosphere.  相似文献   
25.
Groundwater is a resource under stress. In both developed and developing countries, it has been found that increasing human influence has led to the contamination of the groundwater resource. To understand the magnitude of this problem, a study was conducted in 58 wards within Northern part of Kolkata, India, where water samples from tube wells were collected and analysed on essential drinking water quality parameters, prescribed by WHO. Using Principal component analysis, and Water quality index mapping, the aforementioned results have been interpreted. This has helped to depict that not only is the groundwater unsuitable for drinking, but that the parametric values have a tendency to increase abruptly within the shortest of ranges, indicating urban pollution as the root cause of contamination. This paper shall thus discuss the spatial change in groundwater quality in northern Kolkata and suggest measures which might be implemented to secure a sustainable future for the city.  相似文献   
26.
Interferometric Synthetic Aperture Radar (InSAR), nowadays, is a precise technique for monitoring and detecting ground deformation at a millimetric level over large areas using multi-temporal SAR images. Persistent Scatterer Interferometric SAR (PSInSAR), an advanced version of InSAR, is an effective tool for measuring ground deformation using temporally stable reference points or persistent scatterers. We have applied both PSInSAR and Small Baseline Subset (SBAS) methods, based on the spatial correlation of interferometric phase, to estimate the ground deformation and time-series analysis. In this study, we select Las Vegas, Nevada, USA as our test area to detect the ground deformation along satellite line-of-sight (LOS) during November 1992–September 2000 using 44 C-band SAR images of the European Remote Sensing (ERS-1 and ERS-2) satellites. We observe the ground displacement rate of Las Vegas is in the range of ?19 to 8 mm/year in the same period. We also cross-compare PSInSAR and SBAS using mean LOS velocity and time-series. The comparison shows a correlation coefficient of 0.9467 in the case of mean LOS velocity. Along this study, we validate the ground deformation results from the satellite with the ground water depth of Las Vegas using time-series analysis, and the InSAR measurements show similar patterns with ground water data.  相似文献   
27.
28.
For the purpose of testing our previously described theory of SO2 scavenging a laboratory investigation was carried out in the UCLA 33 m long rainshaft. Drops with radii between 250 and 2500 m were allowed to come to terminal velocity, after which they passed through a chamber of variable length filled with various SO2 concentrations in air. After falling through a gas separating chamber consisting of a fluorocarbon gas the drops were collected and analyzed for their total S content in order to determine the rate of SO 2 absorption.The SO2 concentration in air studied ranged between 1 and 60% (v). Such relatively large concentrations were necessary due to the short times the drops were exposed to SO2 in the present setup. The present experimental results were therefore not used to simulate atmospheric conditions but rather to test our previously derived theory which is applicable to any laboratory or atmospheric condition. Comparison of our studies with the results from our theory applied to our laboratory conditions led to predicted values for the S concentration in the drops which agreed well with those observed if the drops had radii smaller than 500 m. In order to obtain agreement between predicted and observed S concentrations in larger drops, an empirically derived eddy diffusivity for SO2 in water had to be included in the theory to take into account the effect of turbulent mixing inside such large drops.In a subsequent set of experiments, drops initially saturated with S (IV) were allowed to fall through S-free air to determine the rate of SO 2 desorption. The results of these studies also agreed well with the results of our theoretical model, thus justifying the reversibility assumption made in our theoretical models.In a final set of experiments, the effects of oxidation on SO2 absorption was studied by means of drops containing various amounts of H2O2. For comparable exposure times to SO2, the S concentration in drops with H2O2 was found to be up to 10 times higher than the concentration in drops in which no oxidation occurred.  相似文献   
29.
Simple, rapid, and sensitive spectrophotometric methods have been proposed for the determination of cationic surfactants (CS) as cetyltrimethylammonium bromide (CTAB), dodecyltrimethylammonium (DTAB), and cetylpyridinium bromide (CPB). The methods are based on the effects of CSs on the complexes of Al3+ and Be2+ with Chrome Azurol S (CAS). The optimum reaction conditions such as CAS concentration, metal ion concentration, and pH have been studied and found to be 2.0 × 10?4 mol L?1 CAS, 0.5 mg L?1 Al3+ or 0.4 mg L?1 Be2+ and pH 5.4. The analytical characteristics of the methods such as limit of detections, limit of quantifications, and linear ranges have been obtained. CTAB, CPB, and DTAB could be determined by the Al–CAS complex in the ranges of 0.50–40.00, 0.20–10.00, and 0.40–10.00 µmol L?1, and for the Be–CAS complex in the ranges of 0.08–5.00, 0.08–3.00, and 0.20–6.00 µmol L?1, respectively. The limit of the detections of the method for the determination of CTAB, CPB, and DTAB for the Be–CAS complex has been found as 0.025, 0.024, and 0.061 µmol L?1, respectively. The interfering effect of some anions and cations was also tested. The method was applied to the determination of CS CTAB in conditioner shampoo and water samples.  相似文献   
30.
Operational meteorology is perceived as a fuzzy environment in which information is vaguely defined. The mesoscale processes such as fog, stratus and convection are generally dependent on the topography of the place and has always been difficult to forecast for the meteorologists. The main objective of the present study is to introduce the concept of fuzzy inference system (FIS) in the prediction of fog. This approach uses the concept of a pure fuzzy logic system where the fuzzy rule base consists of a collection of fuzzy IF-THEN rules. The fuzzy inference engine uses these fuzzy IF-THEN rules to determine a mapping from fuzzy sets in the input universe of discourse to fuzzy sets in the output universe of discourse based on fuzzy logic principles. Basic weather elements, which affect weather characteristics of fog, are fuzzified. These are then used in fuzzy weather prediction models based on fuzzy inferences. These models are simulated and the crisp results obtained using developed defuzzification strategies are compared with the actual weather data. The basis of methodology is to construct the fuzzy rule base domain from the available daily current weather observations in winter season over New Delhi. The results reveal that dew point spread and rate of change of dew point spread are the most important parameters for the formation of fog. The results further indicate that fog formation over New Delhi are dominant when (i) dew point is greater then 7°C along with dew point spread between 1 and 3°C. (ii) rate of change of dew point spread must be negative and wind speed should be less than 4 knots. This study presents a technique for predicting the probability of fog over New Delhi for 5–6 hours in advance. The skill score indicates that the performance of FIS is appreciably good. The method is found to be promising for operational application.  相似文献   
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