Genesis of the hydrothermal gold deposits in the Canan area,Lepaguare District,Honduras     

Michele Mattioli  Marco Menichetti  Alberto Renzulli  Lorenzo Toscani  Emma Salvioli-Mariani  Pedro Suarez  Alessandro Murroni 《International Journal of Earth Sciences》2014,103(3):901-928

The Canan area (Honduras) is characterized by a gold-bearing ore deposit that is associated with quartz-veined shear zones. Gold mineralization occurs in low-to medium-grade metamorphic host-rocks (graphitic and sericitic schists). Hydrothermal fluids, which are associated with the emplacement of Cretaceous-Tertiary granodioritic intrusions, are responsible for the formation of quartz veins and the hydrothermal alteration of wall-rocks. Three main altered zones have been detected in the wall-rocks as far as 150 cm from the quartz veins. The distal zone (up to 50-cm thick) contains quartz, chlorite and illite. The intermediate zone is the thickest (up to 80 cm) and is marked by quartz, muscovite, sulphides, kaolinite and native elements such as Au and Ag. The proximal zone, which is close to the quartz veins, is rather thin (up to 25 cm) and contains clay minerals, Al-oxides-hydroxides and sulphides. The transition from the distal to the proximal zone is accompanied by the enrichment of SiO₂ and the depletion of all other major elements, except for Fe₂O_3(tot). Precious metals occur in the highest concentrations in the intermediate zone (Au up to 7.6 ppm and Ag up to 11 ppm). We suggest that gold was transported as a reduced sulphur complex and was precipitated from the hydrothermal solution by the reaction of the sulphur complexes with Fe²⁺ from the alteration of the mafic minerals of the host-rock. Fluid–wall-rock interactions seem to be the main cause of gold mineralization. Genetic relationships with a strike-slip fault system, hydrothermal alteration zones within the metamorphic wall-rocks, and an entire set of geochemical anomalies are consistent with orogenic-type gold deposits of the epizonal class.  相似文献   

Low levels of copper reduce the reproductive success of a mobile invertebrate predator     

Lee KM  Johnston EL 《Marine environmental research》2007,64(3):336-346

Marine organisms that occur in urbanised bays can be exposed to low-level chronic pollution that results in sublethal changes to behavior or reproduction. The effects of low levels of copper on the reproductive success of a mobile invertebrate were assessed. Free living flatworms are common predators of bivalves and barnacles. Flatworms (Stylochus pygmaeus) were exposed to low levels of copper ranging from 0 to 25 microg L(-1) in the presence and absence of their barnacle prey (Balanus variegatus). Flatworms laid fewer egg batches when exposed to copper and the hatching success of the eggs was also reduced. Exposure to 25 microg L(-1) copper for 10 d reduced the reproductive success of flatworms by up to 80%. Results were consistent regardless of the presence or absence of prey (barnacles). Barnacles were only moderately affected by copper but exhibited major avoidance behavior (feeding inhibition) in the presence of flatworm predators. This is the first ecotoxicological study on marine flatworms. Experiments are required to quantify the effects of flatworm predator populations on sessile invertebrate community structure in the field.  相似文献   

Periodic Time-Series Modeling of Environmental Proxy Records with Guaranteed Positive Growth Rate Estimation     

Veerle Beelaerts  Maite Bauwens  Emma Versteegh  Frank Dehairs  Rik Pintelon 《Mathematical Geosciences》2011,43(6):635-662

Identifying a periodic time-series model from environmental records, without imposing the positivity of the growth rate, does not necessarily respect the time order of the data observations. Consequently, subsequent observations, sampled in the environmental archive, can be inversed on the time axis, resulting in a non-physical signal model. In this paper an optimization technique with linear constraints on the signal model parameters is proposed that prevents time inversions. The activation conditions for this constrained optimization are based upon the physical constraint of the growth rate, namely, that it cannot take values smaller than zero. The actual constraints are defined for polynomials and first-order splines as basis functions for the nonlinear contribution in the distance-time relationship. The method is compared with an existing method that eliminates the time inversions, and its noise sensitivity is tested by means of Monte Carlo simulations. Finally, the usefulness of the method is demonstrated on the measurements of the vessel density, in a mangrove tree, Rhizophora mucronata, and the measurement of Mg/Ca ratios, in a bivalve, Mytilus trossulus.  相似文献   

Hydrogeological behaviour of some fault zones in a carbonate aquifer of Southern Italy: an experimentally based model     

Fulvio Celico  Emma Petrella  Pietro Celico 《地学学报》2006,18(5):308-313

Complex flow circulation patterns are likely to be present in fault‐controlled groundwater flow systems, such as carbonate aquifers. Nevertheless, not much information is available for faults in carbonates, and their hydrogeological behaviour is often neglected in conceptual and numerical models. The understanding of this aspect of subsurface fluid flow has been improved in a carbonate aquifer, where hydrogeological investigations at site scale demonstrated the existence of fault zones that act as barriers. The hydraulic conductivity of the fault core is as low as that of siliciclastic rocks that represent the regional aquitard of the carbonate aquifer. Despite the lower permeability, the fault zones allow a significant groundwater flowthrough and a good interdependence of piezometric heads upgradient and downgradient of the faults. Because of this discontinuous heterogeneity, the aquifer looks like a basins‐in‐series system, where seasonal springs can be detected along some fault zones, as a function of groundwater level fluctuations.  相似文献   

Study of the contact binary AK Herculis: Light-curve analysis and orbital period investigation     

Helen Rovithis-Livaniou  Emma Fragoulopoulou  Nick Sergis  Petros Rovithis  Athanassios Kranidiotis 《Astrophysics and Space Science》2001,275(4):337-348

AK Her is a very interesting contact binary exhibiting variable lightcurves and an obvious O'Connell effect, with max I greater than max II. Inthe present work an extensive study of this system is made covering notonly its light curve analysis, but also its orbital period changes in anattempt to give a definite answer regarding the apsidal motion of AK Her.Photoelectric observations of AK Her, obtained between 1985–1987 at theNational Observatory of Athens Greece, are presented, analysed anddiscussed. The light curve analysis was made with the W-D code and thegeometric and photometric elements of the system were derived. TheO'Connell effect was faced with a two dark spot model. Moreover, theorbital period of the system was examined and two periodicities weredetected. Since the first one corresponds to the time interval for whichobservational data exist and the second was found to be half of the first,it turns out that none of them is true. Two other significant results thatcame from the present analysis are that the orbital period of AK Her doesnot follow a sinusoidal variation and that, from the times of minimumlight at primary and secondary eclipses, it seems that there is no apsidalmotion.  相似文献   

Variational interpolation of high-frequency radar surface currents using DIVAnd     

Barth  Alexander  Troupin  Charles  Reyes  Emma  Alvera-Azcárate  Aida  Beckers  Jean-Marie  Tintoré  Joaquín 《Ocean Dynamics》2021,71(3):293-308

Ocean Dynamics - DIVAnd (Data-Interpolating Variational Analysis, in n-dimensions) is a tool to interpolate observations on a regular grid using the variational inverse method. We have extended...  相似文献   

The Kwakshua Watersheds Observatory,central coast of British Columbia,Canada     

Ian J. W. Giesbrecht  William C. Floyd  Suzanne E. Tank  Ken P. Lertzman  Brian P. V. Hunt  Maartje C. Korver  Allison A. Oliver  Ray Brunsting  Paul Sanborn  Santiago G. Gonzalez Arriola  Gordon W. Frazer  Kyra A. St. Pierre  Shawn Hateley  James McPhail  Colby Owen  Stewart Butler  Bryn Fedje  Emma Myers  Lucy Quayle  Emily Haughton  Isabelle Desmarais  Rob White  David J. Levy-Booth  Colleen T. E. Kellogg  Jennifer M. Jackson  William W. Mohn  Steven J. Hallam  Justin Del Bel Belluz 《水文研究》2021,35(6):e14198

The Kwakshua Watersheds Observatory (KWO) is an integrative watersheds observatory on the coastal margin of a rain-dominated bog-forest landscape in British Columbia (BC), Canada. Established in 2013, the goal of the KWO is to understand and model the flux of terrestrial materials from land to sea – the origins, pathways, processes and ecosystem consequences – in the context of long-term environmental change. The KWO consists of seven gauged watersheds and a network of observation sites spanning from land to sea and along drainage gradients within catchments. Time-series datasets include year-round measurements of weather, soil hydrology, streamflow, aquatic biogeochemistry, microbial ecology and nearshore oceanographic conditions. Sensor measurements are recorded every 5 min and water samples are collected approximately monthly. Additional observations are made during high-flow conditions. We used remote sensing to map watershed terrain, drainage networks, soils and terrestrial ecosystems. The watersheds range in size from 3.2 to 12.8 km², with varying catchment characteristics that influence hydrological and biogeochemical responses. Despite local variation, the overall study area is a global hotspot for yields of dissolved organic carbon, dissolved organic nitrogen and dissolved iron at the coastal margin. This observatory helps fill an important gap in the global network of observatories, in terms of spatial location (central coast of BC), climate (temperate oceanic), hydrology (very high runoff, pluvial regime), geology (igneous intrusive, glacially scoured), vegetation (bog rainforest) and soils (large stores of organic carbon).  相似文献   

ECMWF seasonal forecast system 3 and its prediction of sea surface temperature   总被引：1，自引：1，他引：0  

Timothy N. Stockdale  David L. T. Anderson  Magdalena A. Balmaseda  Francisco Doblas-Reyes  Laura Ferranti  Kristian Mogensen  Timothy N. Palmer  Franco Molteni  Frederic Vitart 《Climate Dynamics》2011,37(3-4):455-471

The latest operational version of the ECMWF seasonal forecasting system is described. It shows noticeably improved skill for sea surface temperature (SST) prediction compared with previous versions, particularly with respect to El Nino related variability. Substantial skill is shown for lead times up to 1?year, although at this range the spread in the ensemble forecast implies a loss of predictability large enough to account for most of the forecast error variance, suggesting only moderate scope for improving long range El Nino forecasts. At shorter ranges, particularly 3?C6?months, skill is still substantially below the model-estimated predictability limit. SST forecast skill is higher for more recent periods than earlier ones. Analysis shows that although various factors can affect scores in particular periods, the improvement from 1994 onwards seems to be robust, and is most plausibly due to improvements in the observing system made at that time. The improvement in forecast skill is most evident for 3-month forecasts starting in February, where predictions of NINO3.4 SST from 1994 to present have been almost without fault. It is argued that in situations where the impact of model error is small, the value of improved observational data can be seen most clearly. Significant skill is also shown in the equatorial Indian Ocean, although predictive skill in parts of the tropical Atlantic are relatively poor. SST forecast errors can be especially high in the Southern Ocean.  相似文献   

Antifouling strategies: history and regulation, ecological impacts and mitigation   总被引：3，自引：0，他引：3  

Dafforn KA  Lewis JA  Johnston EL 《Marine pollution bulletin》2011,62(3):453-465

Biofouling increases drag on marine vessels resulting in higher fuel consumption and can also facilitate the transport of harmful non-indigenous species (NIS). Antifouling technologies incorporating biocides (e.g., copper and tributyltin) have been developed to prevent settlement of organisms on vessels, but their widespread use has introduced high levels of contamination into the environment and raised concerns about their toxic effects on marine communities. The recent global ban on tributyltin (1 January 2008) and increasing regulation of copper have prompted research and development of non-toxic paints. This review synthesises existing information regarding the ecological impact of biocides in a wide range of organisms and highlights directions for the management of antifouling paints. We focus particularly on representatives of the recent past (copper and tributyltin) and present (copper and ‘booster’) biocides. We identify knowledge gaps in antifouling research and provide recommendations relating to the regulation and phasing-out of copper.  相似文献   

Mg and Si isotopic fractionation patterns in types B1 and B2 CAIs: Implications for formation under different nebular conditions     

Emma S. Bullock  Kim B. Knight  Frank M. Richter  Noriko T. Kita  Takayuki Ushikubo  Glenn J. MacPherson  Andrew M. Davis  Ruslan A. Mendybaev 《Meteoritics & planetary science》2013,48(8):1440-1458

Magnesium and silicon isotopic profiles across melilite grains in two type B1 and two type B2 calcium‐aluminum‐rich inclusions (CAIs) reveal differing but constant enrichments in heavy isotopes everywhere except ≤1000 μm from the CAI margins. There is no close correlation in the B1s or the B2s between isotopic composition and åkermanite content of the melilite, a measure of progressive igneous crystallization, yet such a correlation might be expected in a type B2: without a melilite mantle (as in B1s) to seal the interior off and prevent further evaporation, the melt would have maintained communication with the external gas. These observations indicate a model in which B1s and B2s solidified under differing conditions. The B2s solidified under lower hydrogen pressures ( ≤ 10^?4 – 10^?5 bars) than did B1s ( > 10^?4 bars), so surface volatilization was slower in the B2s and internal chemical and isotopic equilibrium was maintained over the interval of melilite crystallization. The outermost zones of the CAIs (≤1000 μm from the edge) are not consistently enriched in heavy isotopes relative to the interiors, as might be expected from diffusion‐limited surface evaporation of the melt. In all cases, the magnesium in the CAI margins is lighter than in the interiors. In one case, silicon in the margin also is lighter, but locally in some CAIs, it is isotopically heavier near the surface. If melt evaporation played a role in the formation of these outer zones, a later event in many cases caused isotopic re‐equilibration with an external and isotopically near‐normal reservoir.  相似文献