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Atmospheric dimethyl sulfide (DMS) and sulfur dioxide (SO2) concentrations were measured at Baring Head, New Zealandduring February and March 2000. Anti-correlated DMS and SO2 diurnalcycles, consistent with the photochemical production of SO2 from DMS, were observed in clean southerly air off the ocean. The data is used to infer a yield of SO2 from DMS oxidation. The estimated yields are highly dependent on assumptions about the DMS oxidation rate. Fitting the measured data in a photochemical box model using model-generated OH levels and the Hynes et al. (1986) DMS + OH rate constant suggests that theSO2 yield is 50–100%, similar to current estimates for the tropical Pacific.However, the observed amplitude of the DMS diurnal cycle suggests that the oxidation rate is higher than that used by the model, and therefore, that theSO2 yield is lower in the range of 20–40%.  相似文献   
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The flow of lava into the ocean at the shoreline of Kilauea Volcano during the ongoing Pu’u O’o eruption has allowed a detailed study of the geochemical interaction between lava and seawater. This paper focuses on the chemistry of the major and minor elements in the fluids that resulted from this interaction. The elemental enrichments in these fluids are dominated by three processes: (1) evaporation of water from seawater, which creates solutions enriched in the major elements found in seawater, (2) congruent dissolution of the basalt glass matrix, which is limited by the solubility of some of the elements in seawater, and (3) removal of volatile phases from the lava on contact with seawater.Using a simple model of volatile emanation (using published emanation coefficients) and congruent dissolution, we are able to explain the concentrations observed for the majority of elements in precipitation from the steam plume at the shoreline lava entry and in water allowed to interact with molten lava in controlled experiments. Fe, Al, Ti, and some of the rare earth elements (REEs) in precipitation samples from the steam plume at the lava entry were > 10,000-times enriched over their ambient seawater concentrations, suggesting that these elements may be useful for identifying submarine eruptions. The flux of elements from the Kilauea ocean lava entry is greater than that from a typical midocean ridge hydrothermal vent field for Al, Cd, Co, and the REEs, whereas the opposite is true for the remainder of the elements studied.  相似文献   
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Effective timescales of coupling within fluvial systems   总被引:1,自引:0,他引:1  
This paper presents a review of the coupling concept in fluvial geomorphology, based mainly on previously published work. Coupling mechanisms link the components of the fluvial system, controlling sediment transport down the system and the propagation of the effects of base-level change up the system. They can be viewed at several scales: at the local scale involving within-hillslope coupling, hillslope-to-channel coupling, and within-channels, tributary junction and reach-to-reach coupling. At larger scales, coupling can be considered as zonal coupling, between major zones of the system or as regional coupling, relating to complete drainage basins. These trends are illustrated particularly by the examples of hillslope-to-channel coupling in the Howgill Fells, northwest England, badland systems in southeast Spain, alluvial fans in Spain, USA and UAE, and base-level-induced dissection of Neogene sedimentary basins in southeast Spain. As the spatial scales increase, so do the timescales involved. Effective temporal scales relate to magnitude and frequency characteristics, recovery time and propagation time, the relative importance changing with the spatial scale. For downsystem coupling at the local scale, the first two are important, with propagation time increasing in importance in larger systems, especially in those involving upsystem coupling related to base-level change. The effective timescales range from the individual event, with a return period of decades, through decadal to century timescales for downsystem coupling, to tens to hundreds of thousands of years for the basinwide response to base-level change. The effective timescales influence the relative importance of factors controlling landform development.  相似文献   
25.
Preliminary results are given from an excimer 157 nm laser ablation multiple-collector inductively coupled plasma-mass spectrometer (LA-MC-ICP-MS), used for the isotopic measurements of solid materials. Elements of geological interest with different volatilities such as Pb and U (e.g. zircon geochronology) and Cu and Zn (as examples of geochemical/biochemical tracers) were analysed. The range of ablation rates of 20-150 nm s-1 enabled us to ablate the sample down to a depth of 45 μm for a 50 μm diameter pit. The Cu and Zn isotopic measurements gave values that were very stable with, on average, a 0.01 % standard error, comparable with that achieved in liquid mode measurements.  相似文献   
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This paper discusses some of the ways that international students, particularly those from East Asia, are involved in the transformation of urban space in Auckland City. Using existing economic reports, local media accounts and the author's initial observations, the paper identifies how the embodied and linguistic practices of international students are involved in the changing landscapes of Auckland's inner city. This cursory reading serves to identify a research agenda and to reflect upon some key theoretical textxs. The insights of Arjun Appadurai, Michael Peter Smith and Ulrich Beck are used to suggest that the changes in Auckland, whilst certainly local, are also influenced fry factors that emerge from beyond the borders of international students' origin communities, cities and nations.  相似文献   
29.
A high-resolution record of Pb deposition in Rhode Island over the past 250 yr was constructed using a sediment core from the anoxic Pettaquamscutt River basin. The sedimentary Pb concentration record shows the well-described maximum associated with leaded gasoline usage in the United States. Diminished Pb variability during recorded periods of local industrial activity (1735 to 1847) supports the greater importance of regional atmospheric lead transport vs. local inputs. The Pb isotopic composition at this site shows a clear maximum in anthropogenic 206Pb/207Pb in the mid-1800s. Similar peaks have also been observed in sediments from Chesapeake Bay and the Great Lakes, suggesting a common source. Possible causes for this event include mining and smelting of Pb ores in the Upper Mississippi Valley district, which accounted for almost all Pb production in the United States in that period. The timing of this event can provide an important stratigraphic marker for sediments deposited in the past 200 yr in the Northeastern United States. The downcore profile of anthropogenic 206Pb/207Pb provides a classic example of how changes in the mixture of ores for production of tetraethyl lead caused a regional-scale shift in the sedimentary record, and suggests that coal could have played a secondary role in Pb emissions after 1920.  相似文献   
30.
We explored the submarine portions of the Enriquillo–Plantain Garden Fault zone (EPGFZ) and the Septentrional–Oriente Fault zone (SOFZ) along the Northern Caribbean plate boundary using high‐resolution multibeam echo‐sounding and shallow seismic reflection. The bathymetric data shed light on poorly documented or previously unknown submarine fault zones running over 200 km between Haiti and Jamaica (EPGFZ) and 300 km between the Dominican Republic and Cuba (SOFZ). The primary plate‐boundary structures are a series of strike‐slip fault segments associated with pressure ridges, restraining bends, step overs and dogleg offsets indicating very active tectonics. Several distinct segments 50–100 km long cut across pre‐existing structures inherited from former tectonic regimes or bypass recent morphologies formed under the current strike‐slip regime. Along the most recent trace of the SOFZ, we measured a strike‐slip offset of 16.5 km, which indicates steady activity for the past ~1.8 Ma if its current GPS‐derived motion of 9.8 ± 2 mm a?1 has remained stable during the entire Quaternary.  相似文献   
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