Voltammetric estimation of iron(III) thermodynamic stability constants for catecholate siderophores isolated from marine bacteria and cyanobacteria     

Brent L. Lewis  Pamela D. Holt  Steven W. Taylor  Steven W. Wilhelm  Charles G. Trick  Alison Butler  George W. Luther  III 《Marine Chemistry》1995,50(1-4)

Thermodynamic stability constants have been estimated for the complexation of iron(III) with catecholate-type siderophores isolated from the marine bacterium Alteromonas luteoviolacea and from the marine cyanobacterium Synechococcus sp. PCC 7002. Stability constants were determined utilizing the “chelate scale” of Taylor et al. (1994). The scale is based upon a linear relationship between the reduction potentials and the pH-independent thermodynamic stability constants for known iron(III) complexes. Log K values for the alterobactin B ferric iron complex are 43.6 ± 1.5 at pH 8.2 and 37.6 ± 1.2 at pH 6, consistent with a shift from bis-catecholate to monosalicylate/monocatecholate iron coordination with decreasing pH. Synechococcus isolates PCC 7002 Nos. 1 and 3 formed iron(III) complexes with stability constants of approximately 38.1 ± 1.2 and 42.3 ± 1.5, respectively. The binding strengths of the iron(III) complexes examined in this study are quite high, suggesting that catecholate siderophores may play a role in the solubilization and biological uptake of iron in the marine environment.  相似文献   

Evaluation of drift current parameters using an analytical model     

N. V. Dmitriev  A. L. Kazakov 《Physical Oceanography》1996,7(6):419-426

The paper is concerned with the evaluation of the drift current parameters derived through the use of an analytical model. In this model, effective when stratification is stable and indifferent, the vertical turbulence coefficient profile is prescribed by the power function, and hydrodynamic quantities are prescribed using the external parameters of the problem (wind stress, the Coriolis parameter, and the dimensionless stratification parameter). Model data are compared with the observations of the upper mixed layer in the vicinity of the oceanic Station C, conducted during one year. It is shown that, under the spring-summer-time warming conditions, the model at issue is capable of adequately simulating the upper ocean layer dynamics. Translated by Vladimir A. Puchkin.  相似文献   

Theory and evaluation of formation pressures: A pressure detection reference handbook : EXLOG Series of Petroleum Geology and Engineering Handbooks D. Reidel Publishing Co/International Human Resources Development Corporation     

D. G. Roberts 《Marine and Petroleum Geology》1986,3(4)

  相似文献   

Determination of characteristics of atmospheric motions from satellite multiwave remote sensing data     

A. F. Nerushev  E. K. Kramchaninova  V. I. Solov’ev 《Izvestiya Atmospheric and Oceanic Physics》2007,43(4):442-450

A method of determination of atmospheric dynamic characteristics from the data of remote sensing from a geostationary satellite is described. The method is based on the use of inhomogeneities in the concentration field of a conservative additive as tracers and on the application of correlation-extreme algorithms. Unlike the common methods used abroad, this method is able to determine not only the vector field of wind velocity but also the coefficient of turbulent diffusion and vorticity. Results of computations of the fields of the horizontal component of wind velocity and the effective coefficient of horizontal mesoscale turbulent diffusion from the Meteosat-8 SEVIRI water-vapor channel data are presented. It is shown that the average values of the effective coefficient of mesoscale horizontal turbulent diffusion in the areas with a predominantly turbulized air-mass motion are 1.5 times greater than in the areas where a laminar motion dominates. Specific features of the calculated values of the upper-troposphere dynamic characteristics in different stages of the North Atlantic TC Helene (September 2006) are analyzed.  相似文献   

Effects of cold eddy on phytoplankton production and assemblages in Luzon strait bordering the South China Sea   总被引：6，自引：0，他引：6  

Yuh-Ling Lee Chen  Houng-Yung Chen  I. -I. Lin  Ming-An Lee  Jeng Chang 《Journal of Oceanography》2007,63(4):671-683

The biochemical effects of a cold-core eddy that was shed from the Kuroshio Current at the Luzon Strait bordering the South China Sea (SCS) were studied in late spring, a relatively unproductive season in the SCS. The extent of the eddy was determined by time-series images of SeaWiFS ocean color, AVHRR sea surface temperature, and TOPEX/Jason-1 sea surface height anomaly. Nutrient budgets, nitrate-based new production, primary production, and phytoplankton assemblages were compared between the eddy and its surrounding Kuroshio and SCS waters. The enhanced productivity in the eddy was comparable to wintertime productivity in the SCS basin, which is supported by upwelled subsurface nitrate under the prevailing Northeastern Monsoon. There were more Synechococcus, pico-eucaryotes, and diatoms, but less Trichodesmium in the surface water inside the eddy than outside. Prochlorococcus and Richelia intracellularis showed no spatial differences. Water column-integrated primary production (IPP) inside the eddy was 2–3 times that outside the eddy in the SCS (1.09 vs. 0.59 g C m⁻²d⁻¹), as was nitrate-based new production (INP) (0.67 vs. 0.25 g C m⁻²d⁻¹). INP in the eddy was 6 times that in the Kuroshio (0.12 g C m⁻²d⁻¹). IPP and INP in the eddy were higher than the maximum production values ever measured in the SCS basin. Surface chlorophyll a concentration (0.40 mg m⁻³) in the eddy equaled the maximum concentration registered for the SCS basin and was higher than the wintertime average (0.29 ± 0.04 mg m⁻³). INP was 3.5 times as great and IPP was doubled in the eddy compared to the wintertime SCS basin. As cold core eddies form intermittently all year round as the Kuroshio invades the SCS, their effects on phytoplankton productivity and assemblages are likely to have important influences on the biogeochemical cycle of the region.  相似文献   

Differences in ratios of stable isotopes of nitrogen in long-finned pilot whales (Globicephala melas) in the western and eastern North Atlantic   总被引：1，自引：0，他引：1  

Abend  Alan G.; Smith  Tim D. 《ICES Journal of Marine Science》1995,52(5):837-841

  相似文献   

Biological processes and environmental factors regulating the dynamics of the Norwegian Skagerrak cod populations since 1919   总被引：1，自引：1，他引：1  

Fromentin  Jean-Marc; Gjosaeter  Jakob; Bjornstad  Ottar N.; Stenseth  N. Chr. 《ICES Journal of Marine Science》2000,57(2):330-338

  相似文献   

Macrobenthic community structure and disturbance assessment in Gialova Lagoon, Ionian Sea   总被引：5，自引：0，他引：5  

Koutsoubas  D.; Dounas  C.; Arvanitidis  C.; Kornilios  S.; Petihakis  G.; Triantafyllou  G.; Eleftheriou  A. 《ICES Journal of Marine Science》2000,57(5):1472-1480

  相似文献   

The dynamic method of calculating currents and analysis of the vertical kinematic structure     

N. P. Bulgakov  S. N. Bulgakov 《Physical Oceanography》1996,7(6):427-435

The basic relations of the classical dyamic method have been complemented with the condition allowing for the non-monotonicity of the vertical kinematic structure. The elements of the multi-layered system of geostrophic currents have been found to correlate over depth with seawater density and hydrostatic pressure distribution. An example of the analysis of the vertical structure of currents, involving specific hydrological data, is given. Translated by Vladimir A. Puchkin.  相似文献   

Recent and Late Holocene environments on the southeastern shelf of the Laptev Sea as inferred from microfossil data     

A. G. Matul  T. A. Khusid  V. V. Mukhina  M. P. Chekhovskaya  S. A. Safarova 《Oceanology》2007,47(1):80-90

The study of diatoms and benthic foraminifers from the southeastern shelf of the Laptev Sea shows that their most diverse and abundant recent assemblages populate the peripheral underwater part of the Lena River delta representing the marginal filter of the sea. This area is characterized by an intense interaction between the fresh waters of the Siberian rivers and the basin seawater, the Atlantic one included. Local Late Holocene (～last 2300 years) environments reflect the main regional and global paleoclimatic changes, the Medieval Warm Period (～600–1100 years B.P.) and the Little Ice Age (～100–600 years B.P.) inclusive. In addition, the composition and distribution of planktonic foraminifers implies a strong influence of the Atlantic water during the Holocene optimum ～5100–6200 years B.P.  相似文献