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Na/K, Na/Ca and Na/Mg exchange isotherms were performed on the fine fraction (<2 μm) of Imt-2 illite samples at a total normality of about 0.005 mol/L in anionic chloride medium. The derived selectivity coefficients for Na/K, Na/Ca and Na/Mg were found to vary as a function of the exchanger composition and compared well with the data collected in the literature for similar experimental conditions. Two models were built to reproduce the data: the first was a multi(2)-site model with constant Gaines and Thomas selectivity coefficients; the second was a one-site model taking into account surface species activity coefficients. The results of the models were in rather good agreement with both our data and literature data. The multi-site model proved to be efficient in predicting the exchanger composition as a function of the Na/Ca/Mg/K concentrations in solution, whereas the one-site model proved to be a better approach to derive the Na/Ca/Mg/K concentrations in solution based on the knowledge of the exchanger composition and the total normality of the solution. The interest of this approach is illustrated by the need for major cation solute concentration predictions in compacted clay for the characterization of nuclear deep disposal host rock repositories.  相似文献   
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New geochronological analyses (U–Pb SIMS zircon ages) have yielded ages of 552 ± 5 Ma for the Bou Madine rhyolitic dome (Ougnat, eastern Anti-Atlas), 543 ± 9 Ma for the Tachkakacht rhyolitic dyke (Saghro–Imiter, eastern Anti-Atlas), and 531 ± 5 Ma for the Aghbar trachytic sill (Bou Azzer, central Anti-Atlas). Inherited zircon cores from the Aghbar trachytic sill and from the Bou Madine rhyolitic dome have been shown to be of Statherian age (ca. 1600–1800 Ma) and Palæoproterozoic (>2100 Ma) age, respectively, suggesting that a significantly older protolith underlies the Pan-African rocks in the Central and Eastern Anti-Atlas. Granodiorites and rhyolites from the Saghro–Imiter area have similar low 87Sr/86Sr (0.702–0.706) and 143Nd/144Nd (0.5116–0.5119) initial ratios, suggesting a mixture of mantle and lower crust sources. This can also be inferred from the low 187Os/188Os ratios obtained on pyrite crystals from the rhyolites.A recently published lithostratigraphic framework has been combined with these new geochemical and geochronological data, and those from the literature to produce a new reconstruction of the complex orogenic front that developed at the northern edge of the Eburnian West African craton during Pan-African times. Three Neoproterozoic magmatic series can be distinguished in the Anti-Atlas belt, i.e., high-K calc-alkaline granites, high-K calc-alkaline to shoshonitic rhyolites and andesites, and alkaline-shoshonitic trachytes and syenites, which have been dated at 595–570, 570–545 and 530 Ma, respectively.The accretion of the Pan-African Anti-Atlas belt to the West African super continent (WAC) was a four-stage event, involving extension, subduction, moderate collision and extension. The calc-alkaline magmatism of the subduction stage was associated with large-scale base metal and gold mineralisation. Metallogenic activity was greatest during the final extensional stage, at the Precambrian–Cambrian boundary. It is characterised by world-class precious metal deposits, base–metal porphyry and SEDEX-type occurrences.  相似文献   
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Environmental parameters and gross sedimentation rates (GSR) were monitored at a fixed site located in the Bay of Banyuls-sur-Mer (NW Mediterranean), between March 1997 and April 1998, together with the main biochemical characteristics of both sedimenting and sedimented particulate organic matter (POM). Three storms which occurred during this time period resulted in natural sediment resuspension. This is indicated by the corresponding increase in GSR and a decrease in the enzymatically hydrolysable amino acids/totally hydrolysable amino acids ratio (EHAA/THAA), within the sedimenting POM. Only the strongest storm resulted in (1) a transitory increase in fine-grained particles, (2) concomitant increases in organic carbon, carbohydrates, lipids and THAA, and (3) a decrease in the EHAA/THAA ratio in surficial sediments. For most of the assayed parameters, the values recorded after the December 1997 storm corresponded to extremes for the whole period under study. This emphasises the role of storms in controlling the characteristics of sedimented and sedimenting POM.Ten sediment types, with contrasting biochemical characteristics, were selected for experiments; these were based on the results of the monitoring survey and were used during adsorption and absorption experiments involving 14C tetrachlorobiphenyl (TCB). Adsorption rates differed significantly between the sediment types, but did not correlate with any of the assayed biochemical parameters. Absorption efficiency by the mussel Mytilus galloprovincialis also differed between the sediment types; it correlated positively with all the assayed biochemical parameters, except lipids. Comparison between the magnitudes of the increase in GSR, together with the decrease in absorption efficiency during resuspension events, suggests that resuspension tends to enhance the transfer of organic pollutants in the benthic food chain.  相似文献   
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Early and late Holocene water-level changes in Lake Annecy, France, were reconstructed from a sediment sequence from Annecy. Two early Holocene successive rises in lake level at ca. 8900-8700 BP are recorded. Another increase in lake level, beginning at ca. 780 BP, is documented. The higher lake-level conditions in Lake Annecy during the 9th millennium BP, i.e. between the Preboreal oscillation and the 8200 yr event, appear to coincide with a more widespread cooling period which has been recorded in western Europe, in the Greenland ice-sheet and the North Atlantic ocean. The rise in lake level at ca. 780 BP can be related to the early Little Ice Age.  相似文献   
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Four hundred inoceramids have been collected in the geological site at Tercis, where the Campanian–Maastrichtian boundary has been recently defined. At Tercis, a distinct drop of the adult size of inoceramids is observed between levels 111 and 117 and two turnovers of faunal composition were documented between levels 94 and 96 and between levels 111 and 117; the latter interval encompasses the stage boundary. The recognised inoceramid assemblages are very close to those known from North America, allowing better correlation than before between the two domains in the interval 77–70 Ma. The presence of these faunas perfectly located in the section leads to consider the Tercis section as the best known reference for this fossil group, the surprisingly good correlative potential of which has still to be considered in many areas.  相似文献   
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Lithostratigraphy, physicochemical stratigraphy, biostratigraphy, and geochronology of the 77–70 Ma old series bracketing the Campanian–Maastrichtian boundary have been investigated by 70 experts. For the first time, direct relationships between macro- and microfossils have been established, as well as direct and indirect relationships between chemo-physical and biostratigraphical tools. A combination of criteria for selecting the boundary level, duration estimates, uncertainties on durations and on the location of biohorizons have been considered; new chronostratigraphic units are proposed. The geological site at Tercis is accepted by the Commission on Stratigraphy as the international reference for the stratigraphy of the studied interval. To cite this article: G.S. Odin, C. R. Geoscience 334 (2002) 409–414.  相似文献   
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