Water diffusion in dacitic melt     

Huaiwei Ni  Harald Behrens 《Geochimica et cosmochimica acta》2009,73(12):3642-3655

H₂O diffusion in dacitic melt was investigated at 0.48-0.95 GPa and 786-893 K in a piston-cylinder apparatus. The diffusion couple design was used, in which a nominally dry dacitic glass makes one half and is juxtaposed with a hydrous dacitic glass containing up to ∼8 wt.% total water (H₂O_t). H₂O concentration profiles were measured on quenched glasses with infrared microspectroscopy. The H₂O diffusivity in dacite increases rapidly with water content under experimental conditions, similar to previous measurements at the same temperature but at pressure <0.15 GPa. However, compared with the low-pressure data, H₂O diffusion at high pressure is systematically slower. H₂O diffusion profiles in dacite can be modeled by assuming molecular H₂O (H₂O_m) is the diffusing species. Total H₂O diffusivity D_H2Ot within 786-1798 K, 0-1 GPa, and 0-8 wt.% H₂O_t can be expressed as: where D_H2Ot is in m²/s, T is temperature in K, P is pressure in GPa, K = exp(1.49 − 2634/T) is the equilibrium constant of speciation reaction (H₂O_m+O?2OH) in the melt, X = C/18.015/[C/18.015 + (100 − C)/33.82], C is wt.% of H₂O_t, and 18.015 and 33.82 g/mol correspond to the molar masses of H₂O and anhydrous dacite on a single oxygen basis. Compared to H₂O diffusion in rhyolite, diffusivity in dacite is lower at intermediate temperatures but higher at superliquidus temperatures. This general H₂O diffusivity expression can be applied to a broad range of geological conditions, including both magma chamber processes and volcanic eruption dynamics from conduit to the surface.  相似文献   

Pressure dependence of viscosity of rhyolitic melts     

Hejiu Hui  Youxue Zhang  Piero Del Gaudio  Harald Behrens 《Geochimica et cosmochimica acta》2009,73(12):3680-3693

Viscosity of silicate melts is a critical property for understanding volcanic and igneous processes in the Earth. We investigate the pressure effect on the viscosity of rhyolitic melts using two methods: indirect viscosity inference from hydrous species reaction in melts using a piston cylinder at pressures up to 2.8 GPa and direct viscosity measurement by parallel-plate creep viscometer in an internally-heated pressure vessel at pressures up to 0.4 GPa. Comparison of viscosities of a rhyolitic melt with 0.8 wt% water at 0.4 GPa shows that both methods give consistent results. In the indirect method, viscosities of hydrous rhyolitic melts were inferred based on the kinetics of hydrous species reaction in the melt upon cooling (i.e., the equivalence of rheologically defined glass transition temperature and chemically defined apparent equilibrium temperature). The cooling experiments were carried out in a piston-cylinder apparatus using hydrous rhyolitic samples with 0.8-4 wt% water. Cooling rates of the kinetic experiments varied from 0.1 K/s to 100 K/s; hence the range of viscosity inferred from this method covers 3 orders of magnitude. The data from this method show that viscosity increases with increasing pressure from 1 GPa to 3 GPa for hydrous rhyolitic melts with water content ?0.8 wt% in the high viscosity range. We also measured viscosity of rhyolitic melt with 0.13 wt% water using the parallel-plate viscometer at pressures 0.2 and 0.4 GPa in an internally-heated pressure vessel. The data show that viscosity of rhyolitic melt with 0.13 wt% water decreases with increasing pressure. Combining our new data with literature data, we develop a viscosity model of rhyolitic melts as a function of temperature, pressure and water content.  相似文献   

Pyrometallurgical relics of Pb–Cu–Fe deposits in south-eastern Germany: An exploration tool and a record of mining history     

Harald G. Dill 《Journal of Geochemical Exploration》2009

Pyrometallurgical relics from smelting of iron as well as base metal ores are mineralogically and chemically investigated and dated using the radiocarbon method and optically stimulated luminescence. This study addresses the question whether these pyrometallurgical remains may be used as an exploration tool enabling geologists to discriminate between false and true gossans. Moreover, these investigations make a historical contribution and demonstrate how mining and smelting activities spread across NE Bavaria, Germany.  相似文献   

Atlantic Water flow through the Barents and Kara Seas   总被引：2，自引：0，他引：2  

Ursula Schauer  Harald Loeng  Bert Rudels  Vladimir K. Ozhigin  Wolfgang Dieck 《Deep Sea Research Part I: Oceanographic Research Papers》2002,49(12)

The pathway and transformation of water from the Norwegian Sea across the Barents Sea and through the St. Anna Trough are documented from hydrographic and current measurements of the 1990s. The transport through an array of moorings in the north-eastern Barents Sea was between 0.6 Sv in summer and 2.6 Sv in winter towards the Kara Sea and between zero and 0.3 Sv towards the Barents Sea with a record mean net flow of 1.5 Sv. The westward flow originates in the Fram Strait branch of Atlantic Water at the Eurasian continental slope, while the eastward flow constitutes the Barents Sea branch, continuing from the western Barents Sea opening.About 75% of the eastward flow was colder than 0°C. The flow was strongly sheared, with the highest velocities close to the bottom. A deep layer with almost constant temperature of about −0.5°C throughout the year formed about 50% of the flow to the Kara Sea. This water was a mixture between warm saline Atlantic Water and cold, brine-enriched water generated through freezing and convection in polynyas west of Novaya Zemlya, and possibly also at the Central Bank. Its salinity is lower than that of the Atlantic Water at its entrance to the Barents Sea, because the ice formation occurs in a low salinity surface layer. The released brine increases the salinity and density of the surface layer sufficiently for it to convect, but not necessarily above the salinity of the Atlantic Water. The freshwater west of Novaya Zemlya primarily stems from continental runoff and at the Central Bank probably from ice melt. The amount of fresh water compares to about 22% of the terrestrial freshwater supply to the western Barents Sea. The deep layer continues to the Kara Sea without further change and enters the Nansen Basin at or below the core depth of the warm, saline Fram Strait branch. Because it is colder than 0°C it will not be addressed as Atlantic Water in the Arctic Ocean.In earlier decades, the Atlantic Water advected from Fram Strait was colder by almost 2 K as compared to the 1990s, while the dense Barents Sea water was colder by up to 1 K only in a thin layer at the bottom and the salinity varied significantly. However, also with the resulting higher densities, deep Eurasian Basin water properties were met only in the 1970s. The very low salinities of the Great Salinity Anomaly in 1980 were not discovered in the outflow data. We conclude that the thermal variability of inflowing Atlantic water is damped in the Barents Sea, while the salinity variation is strongly modified through the freshwater conditions and ice growth in the convective area off Novaya Zemlya.  相似文献   

GETEMME—a mission to explore the Martian satellites and the fundamentals of solar system physics     

Jürgen Oberst  Valéry Lainey  Christophe Le Poncin-Lafitte  Veronique Dehant  Pascal Rosenblatt  Stephan Ulamec  Jens Biele  J?rn Spurmann  Ralph Kahle  Volker Klein  Ulrich Schreiber  Anja Schlicht  Nicolas Rambaux  Philippe Laurent  Beno?t Noyelles  Bernard Foulon  Alexander Zakharov  Leonid Gurvits  Denis Uchaev  Scott Murchie  Cheryl Reed  Slava G. Turyshev  Jesus Gil  Mariella Graziano  Konrad Willner  Kai Wickhusen  Andreas Pasewaldt  Marita W?hlisch  Harald Hoffmann 《Experimental Astronomy》2012,34(2):243-271

GETEMME (Gravity, Einstein??s Theory, and Exploration of the Martian Moons?? Environment), a mission which is being proposed in ESA??s Cosmic Vision program, shall be launched for Mars on a Soyuz Fregat in 2020. The spacecraft will initially rendezvous with Phobos and Deimos in order to carry out a comprehensive mapping and characterization of the two satellites and to deploy passive Laser retro-reflectors on their surfaces. In the second stage of the mission, the spacecraft will be transferred into a lower 1500-km Mars orbit, to carry out routine Laser range measurements to the reflectors on Phobos and Deimos. Also, asynchronous two-way Laser ranging measurements between the spacecraft and stations of the ILRS (International Laser Ranging Service) on Earth are foreseen. An onboard accelerometer will ensure a high accuracy for the spacecraft orbit determination. The inversion of all range and accelerometer data will allow us to determine or improve dramatically on a host of dynamic parameters of the Martian satellite system. From the complex motion and rotation of Phobos and Deimos we will obtain clues on internal structures and the origins of the satellites. Also, crucial data on the time-varying gravity field of Mars related to climate variation and internal structure will be obtained. Ranging measurements will also be essential to improve on several parameters in fundamental physics, such as the Post-Newtonian parameter ?? as well as time-rate changes of the gravitational constant and the Lense-Thirring effect. Measurements by GETEMME will firmly embed Mars and its satellites into the Solar System reference frame.  相似文献   

Rheologies and ages of lava flows on Elysium Mons,Mars     

Jan Hendrik Pasckert  Harald Hiesinger  Dennis Reiss 《Icarus》2012,219(1):443-457

We present results of our study of the rheologies and ages of lava flows in the Elysium Mons region of Mars. Previous studies have shown that the geometric dimensions of lava flows reflect rheological properties such as yield strength, effusion rate and viscosity. In this study the rheological properties of lava flows in the Elysium Mons region were determined and compared to the rheologies of the Ascraeus Mons lava flows. We also derived new crater size-frequency distribution measurements (CSFDs) for the Elysium lava flows to identify possible changes in the rheological properties with time. In addition, possible changes in the rheological properties with the distance from the caldera of Elysium Mons were analyzed.In total, 35 lava flows on and around Elysium Mons were mapped, and divided into three groups, lava flows on the flanks of Elysium Mons, in the plains between the three volcanoes Elysium Mons, Hecates and Albor Tholus and lava flows south of Albor Tholus. The rheological properties of 32 of these flows could be determined. Based on our morphometric measurements of each individual lava flow, estimates for the yield strengths, effusion rates, viscosities, and eruption duration of the studied lava flows were made. The yield strengths of the investigated lava flows range from ～3.8 × 10² Pa to ～1.5 × 10⁴ Pa, with an average of ～3.0 × 10³ Pa. These yield strengths are in good agreement with estimates for terrestrial basaltic lava flows. The effusion rates are on average ～747 m³ s^?1, ranging from ～99 to 4450 m³ s^?1. The viscosities are on average ～4.1 × 10⁶ Pa s, with a range of 1.2 × 10⁵ Pa s to 3.1 × 10⁷ Pa s. The eruption durations of the flows were calculated to be between 6 and 183 days, with an average of ～51 days. The determined rheological properties are generally very similar to those of other volcanic regions on Mars, such as on Ascraeus Mons in the Tharsis region. Calculated yield strengths and viscosities point to a basaltic/andesitic composition of the lava flows, similar to basaltic or andesitic a’a lava flows on Earth.Absolute model ages of all 35 lava flows on Elysium Mons were derived from crater size-frequency distribution measurements (CSFD). The derived model ages show a wide variation from about 632 Ma to 3460 Ma. Crater size-frequency distribution measurements of the Elysium Mons caldera show an age of ～1640 Ma, which is consistent with the resurfacing age of Werner (2009). Significant changes of the rheologies with time could not be observed. Similarly, we did not observe systematic changes in ages with increasing distances of lava flows from the Elysium Mons caldera.  相似文献   

Is the soil moisture precipitation feedback enhanced by heterogeneity and dry soils? A comparative study     

Maximilian Graf  Joël Arnault  Benjamin Fersch  Harald Kunstmann 《水文研究》2021,35(9):e14332

The interaction between the land surface and the atmosphere is a crucial driver of atmospheric processes. Soil moisture and precipitation are key components in this feedback. Both variables are intertwined in a cycle, that is, the soil moisture – precipitation feedback for which involved processes and interactions are still discussed. In this study the soil moisture – precipitation feedback is compared for the sempiternal humid Ammer catchment in Southern Germany and for the semiarid to subhumid Sissili catchment in West Africa during the warm season, using precipitation datasets from the Climate Hazards Group InfraRed Precipitation with Station data (CHIRPS), from the German Weather Service (REGNIE) and simulation datasets from the Weather Research and Forecasting (WRF) model and the hydrologically enhanced WRF-Hydro model. WRF and WRF-Hydro differ by their representation of terrestrial water flow. With this setup we want to investigate the strength, sign and variables involved in the soil moisture – precipitation feedback for these two regions. The normalized model spread between the two simulation results shows linkages between precipitation variability and diagnostic variables surface fluxes, moisture flux convergence above the surface and convective available potential energy in both study regions. The soil moisture – precipitation feedback is evaluated with a classification of soil moisture spatial heterogeneity based on the strength of the soil moisture gradients. This allows us to assess the impact of soil moisture anomalies on surface fluxes, moisture flux convergence, convective available potential energy and precipitation. In both regions the amount of precipitation generally increases with soil moisture spatial heterogeneity. For the Ammer region the soil moisture – precipitation feedback has a weak negative sign with more rain near drier patches while it has a positive signal for the Sissili region with more rain over wetter patches. At least for the observed moderate soil moisture values and the spatial scale of the Ammer region, the spatial variability of soil moisture is more important for surface-atmosphere interactions than the actual soil moisture content. Overall, we found that soil moisture heterogeneity can greatly affect the soil moisture – precipitation feedback.  相似文献   

Role of reservoir regulation and groundwater feedback in a simulated ground-soil-vegetation continuum: A long-term regional scale analysis     

Jianhui Wei  Ningpeng Dong  Benjamin Fersch  Joël Arnault  Sven Wagner  Patrick Laux  Zhenyu Zhang  Qianya Yang  Chuanguo Yang  Shasha Shang  Lu Gao  Zhongbo Yu  Harald Kunstmann 《水文研究》2021,35(8):e14341

The regional terrestrial water cycle is strongly altered by human activities. Among them, reservoir regulation is a way to spatially and temporally allocate water resources in a basin for multi-purposes. However, it is still not sufficiently understood how reservoir regulation modifies the regional terrestrial- and subsequently, the atmospheric water cycle. To address this question, the representation of reservoir regulation into the terrestrial component of fully coupled regional Earth system models is required. In this study, an existing process-based reservoir network module is implemented into NOAH-HMS, that is, the terrestrial component of an atmospheric–hydrologic modelling system, namely, the WRF-HMS. It allows to quantitatively differentiate role of reservoir regulation and of groundwater feedback in a simulated ground-soil-vegetation continuum. Our study focuses on the Poyang Lake basin, where the largest freshwater lake of China and reservoirs of different sizes are located. As compared to streamflow observations, the newly extended NOAH-HMS slightly improves the streamflow and streamflow duration curves simulation for the Poyang Lake basin for the period 1979–1986. The inclusion of reservoir regulation leads to major changes in the simulated groundwater recharges and evaporation from reservoirs at local scale, but has minor effects on the simulated soil moisture and surface runoff at basin scale. The performed groundwater feedback sensitivity analysis shows that the strength of the groundwater feedback is not altered by the consideration of reservoir regulation. Furthermore, both reservoir regulation and groundwater feedback modify the partitioning of the simulated evapotranspiration, thus affecting the atmospheric water cycle in the Poyang Lake region. This finding motivates future research with our extended fully coupled atmospheric–hydrologic modelling system by the community.  相似文献   

The variation and controls of mean transit times in Australian headwater catchments     

Ian Cartwright  Uwe Morgenstern  William Howcroft  Harald Hofmann  Robin Armit  Michael Stewart  Chad Burton  Dylan Irvine 《水文研究》2020,34(21):4034-4048

Determining mean transit times in headwater catchments is critical for understanding catchment functioning and understanding their responses to changes in landuse or climate. Determining whether mean transit times (MTTs) correlate with drainage density, slope angle, area, or land cover permits a better understanding of the controls on water flow through catchments and allows first-order predictions of MTTs in other catchments to be made. This study assesses whether there are identifiable controls on MTTs determined using ³H in headwater catchments of southeast Australia. Despite MTTs at baseflow varying from a few years to >100 years, it was difficult to predict MTTs using single or groups of readily-measured catchment attributes. The lack of readily-identifiable correlations hampers the prediction of MTTs in adjacent catchments even where these have similar geology, land use, and topography. The long MTTs of the Australian headwater catchments are probably in part due to the catchments having high storage volumes in deeply-weathered regolith, combined with low recharge rates due to high evapotranspiration. However, the difficulty in estimating storage volumes at the catchment scale hampers the use of this parameter to estimate MTTs. The runoff coefficient (the fraction of rainfall exported via the stream) is probably also controlled by evapotranspiration and recharge rates. Correlations between the runoff coefficient and MTTs in individual catchments allow predictions of MTTs in nearby catchments to be made. MTTs are shorter in high rainfall periods as the catchments wet up and shallow water stores are mobilized. Despite the contribution of younger water, the major ion geochemistry in individual catchments commonly does not correlate with MTTs, probably reflecting heterogeneous reactions and varying degrees of evapotranspiration. Documenting MTTs in catchments with high storage volumes and/or low recharge rates elsewhere is important for understanding MTTs in diverse environments.  相似文献   

A Global Terrestrial Reference Frame from simulated VLBI and SLR data in view of GGOS     

Susanne Glaser  Rolf König  Dimitrios Ampatzidis  Tobias Nilsson  Robert Heinkelmann  Frank Flechtner  Harald Schuh 《Journal of Geodesy》2017,91(7):723-733

In this study, we assess the impact of two combination strategies, namely local ties (LT) and global ties (GT), on the datum realization of Global Terrestrial Reference Frames in view of the Global Geodetic Observing System requiring 1 mm-accuracy. Simulated Very Long Baseline Interferometry (VLBI) and Satellite Laser Ranging (SLR) data over a 7 year time span was used. The LT results show that the geodetic datum can be best transferred if the precision of the LT is at least 1 mm. Investigating different numbers of LT, the lack of co-located sites on the southern hemisphere is evidenced by differences of 9 mm in translation and rotation compared to the solution using all available LT. For the GT, the combination applying all Earth rotation parameters (ERP), such as pole coordinates and UT1-UTC, indicates that the rotation around the Z axis cannot be adequately transferred from VLBI to SLR within the combination. Applying exclusively the pole coordinates as GT, we show that the datum can be transferred with mm-accuracy within the combination. Furthermore, adding artificial stations in Tahiti and Nigeria to the current VLBI network results in an improvement in station positions by 13 and 12%, respectively, and in ERP by 17 and 11%, respectively. Extending to every day VLBI observations leads to 65% better ERP estimates compared to usual twice-weekly VLBI observations.  相似文献