Diffusion-controlled growth of wollastonite rims between quartz and calcite: comparison between nature and experiment   总被引：2，自引：2，他引：2  

R. Milke  W. Heinrich 《Journal of Metamorphic Geology》2002,20(5):467-480

Growth rates of wollastonite reaction rims between quartz and calcite were experimentally determined at 0.1 and 1 GPa and temperatures from 850 to 1200 °C. Rim growth follows a parabolic rate law indicating that this reaction is diffusion‐controlled. From the rate constants, the D′δ‐values of the rate‐limiting species were derived, i.e. the product of grain boundary diffusion coefficient D′ and the effective grain boundary width, δ. In dry runs at 0.1 GPa, wollastonite grew exclusively on quartz surfaces. From volume considerations it is inferred that (D′_CaOδ)/(D′_SiO2δ)≥1.33, and that SiO₂ diffusion controls rim growth. D′_SiO2δ increases from about 10^?25 to 10^?23 m³ s^?1 as temperature increases from 850 to 1000 °C, yielding an apparent activation energy of 330±36 kJ mol^?1. In runs at 1 GPa, performed in a piston‐cylinder apparatus, there were always small amounts of water present. Here, wollastonite rims always overgrew calcite. Rims around calcite grains in quartz matrix are porous and their growth rates are controlled by a complex diffusion‐advection mechanism. Rim growth on matrix calcite around quartz grains is controlled by grain boundary diffusion, but it is not clear whether CaO or SiO₂ diffusion is rate‐limiting. D′δ increases from about 10^?21 to 10^?20 m³ s^?1 as temperature increases from 1100 to 1200 °C. D′_SiO2δ or D′_CaOδ in rims on calcite is c. 10 times larger than D′_SiO2δ in dry rims at the same temperature. Growth structures of the experimentally produced rims are very similar to contact‐metamorphic wollastonite rims between metachert bands and limestone in the Bufa del Diente aureole, Mexico, whereby noninfiltrated metacherts correspond to dry and brine‐infiltrated metacherts to water‐bearing experiments. However, the observed diffusivities were 4 to 5 orders of magnitude larger during contact‐metamorphism as compared to our experimental results.  相似文献   

Combining trace-element compositions, U–Pb geochronology and Hf isotopes in zircons to unravel complex calcalkaline magma chambers in the Upper Cretaceous Srednogorie zone (Bulgaria)     

I. Peytcheva  A. von Quadt  N. Georgiev  Zh. Ivanov  C.A. Heinrich  M. Frank   《Lithos》2008,104(1-4):405-427

Precise U–Pb geochronology and Hf isotope tracing of zircon is combined with whole-rock geochemical and Sr and Nd isotope data in order to unravel processes affecting mafic to felsic calcalkaline magmas prior to and during their crystallization in crustal magma chambers along the southern border of Central Srednogorie tectonic zone in Bulgaria (SE Europe). ID-TIMS U–Pb dating of single zircons from felsic and mixed/mingled dioritic to gabbroic horizons of single plutons define crystallization ages of around 86.5–86.0, 85.0–84.5 and 82 Ma. Concordia age uncertainties are generally less than 0.3 Ma (0.35%–2σ), and as good as 0.08 Ma (0.1%), when the weighted mean ²⁰⁶Pb/²³⁸U value is used. Such precision allows the distinction of magma replenishment processes if separated by more than 0.6–1.0 Ma and when they are marked by newly saturated zircons. We interpret zircon dates from a single sample that do not overlap to reflect new zircon growth during magma recharge in a long-lived crustal chamber. Mingling/mixing of the basaltic magma with colder granitoid mush at mid- to upper-crustal levels is proposed to explain zircon saturation and fast crystallization of U- and REE-rich zircons in the hybrid gabbro.Major and trace-element distribution and Sr and Nd whole-rock isotope chemistry define island arc affinities for the studied plutons. Slab derived fluids and a sediment component are constrained as enrichment sources for the mantle wedge-derived magma, though Hf isotopes in zircon suggest crustal assimilation was also important. Inherited zircons, and their corresponding ε-Hf, from the hybrid gabbroic rocks trace the lower crust as possible source for enrichment of the mantle magma. These inherited zircons are about 440 Ma old with ε-Hf of − 7 at 82 Ma, whereas newly saturated concordant Upper Cretaceous zircons reveal mantle ε-Hf values of + 7.2 to + 10.1. The upper and middle crusts contribute in the generation of the granitoid rocks. Their zircon inheritance is Lower Palaeozoic or significantly older and crustal dominated with 82–85 Ma corrected ε-Hf values of − 28. The Cretaceous concordant zircons in the granitoids are mantle dominated with a ε-Hf values spreading from + 3.9 to + 7.  相似文献   

Toward a radiometric ice clock: uranium ages of the Dome C ice core     

Sarah Aciego  Bernard Bourdon  Jakob Schwander  Heinrich Baur  Alessandro Forieri 《Quaternary Science Reviews》2011,30(19-20):2389-2397

Ice sheets and deep ice cores have yielded a wealth of paleoclimate information based on continuous dating methods while independent radiometric ages of ice have remained elusive. Here we demonstrate the application of (²³⁴U/²³⁸U) measurements to dating the EPICA Dome C ice core based on the accumulation of ²³⁴U in the ice matrix from recoil during ²³⁸U decay out of dust bound within the ice. Measured (²³⁴U/²³⁸U) activity ratios within the ice generally increase with depth while the surface areas of the dust grains are relatively constant. Using a newly designed device for measuring surface area for small samples, we were able to estimate reliably the recoil efficiency of nuclides from dust to ice. The resulting calculated radiometric ages range between 80 ka and 870 ka. Measured samples in the upper 3100 m fall on the previously published age-depth profile. Samples in the 3200–3255 m section show a marked change from 723–870 ka to 85 ka indicating homogenization of the deep ice prior to resetting of the (²³⁴U/²³⁸U) age in the basal layers. The mechanism for homogenization is likely enhanced lateral ice flow due to high basal melting and geothermal heat flux.  相似文献   

Sedimentology of the December 26, 2004, Sumatra tsunami deposits in eastern India (Tamil Nadu) and Kenya     

Heinrich Bahlburg  Robert Weiss 《International Journal of Earth Sciences》2007,96(6):1195-1209

The December 26, 2004 Sumatra tsunami caused severe damage at the coasts of the Indian ocean. We report results of a sedimentological study of tsunami run-up parameters and the sediments laid down by the tsunami at the coast of Tamil Nadu, India, and between Malindi and Lamu, Kenya. In India, evidence of three tsunami waves is preserved on the beaches in the form of characteristic debris accumulations. We measured the maximum run-up distance at 580 m and the maximum run-up height at 4.85 m. Flow depth over land was at least 3.5 m. The tsunami deposited an up to 30 cm thick blanket of moderately well to well-sorted coarse and medium sand that overlies older beach deposits or soil with an erosional unconformity. The sand sheet thins inland without a decrease of grain-size. The deposits consist frequently of three layers. The lower one may be cross-bedded with foresets dipping landward and indicating deposition during run-up. The overlying two sand layers are graded or parallel-laminated without indicators of current directions. Thus, it remains undecided whether they formed during run-up or return flow. Thin dark laminae rich in heavy minerals frequently mark the contacts between successive layers. Benthic foraminifera indicate an entrainment of sediment by the tsunami from water depths less than ca. 30 m water depth. On the Indian shelf these depths are present at distances of up to 5 km from the coast. In Kenya only one wave is recorded, which attained a run-up height of 3 m at a run-up distance of ca. 35 m from the tidal water line at the time of the tsunami impact. Only one layer of fine sand was deposited by the tsunami. It consists predominantly of heavy minerals supplied to the sea by a nearby river. The sand layer thins landward with a minor decrease in grain-size. Benthic foraminifera indicate an entrainment of sediment by the tsunami from water depths less than ca. 30 m water depth, reaching down potentially to ca. 80 m. The presence of only one tsunami-related sediment layer in Kenya, but three in India, reflects the impact of only one wave at the coast of Kenya, as opposed to several in India. Grain-size distributions in the Indian and Kenyan deposits are mostly normal to slightly positively skewed and indicate that the detritus was entrained by the tsunami from well sorted pre-tsunami deposits in nearshore, swash zone and beach environments.  相似文献   

Microthermometry, Raman and LA-ICP-MS of Fluid Inclusions Constrain on Fluids Chemistry and Evolution of Carlin-Type Gold System, Guizhou, China: Implications for Ore Genesis     

Wen-chao Su　Christoph A. Heinrich　Thomas Pettke　Xing-chun Zhang　Rui-zhong Hu　Bin Xia 《矿物岩石地球化学通报》2006,25(Z1):192

The Shuiyindong and Yata Carlin-type gold deposits, located in Southwestern Guizhou, China, are hosted by Permianbioclastic limestone in the form of stratabound mineralization and Middle Triassic calcareous clastic rocks as fault-controlled mineralization, respectively. In these deposits, quartz crystals in the veins or veinlets associated with mineralization have contained several populations of fluid inclusions with relatively quite big size and clear paragenetic relationship of entrapment. Petrography, microthermometry, Raman and LA-ICPMS of fluid inclusions analyses are used to characterize fluids chemistry and their evolution of Carlin-type system in Guizhou.  相似文献   

Numerical modelling of generation, propagation and run-up of tsunamis caused by oceanic impacts: model strategy and technical solutions   总被引：1，自引：0，他引：1  

Robert Weiss  Kai Wünnemann  Heinrich Bahlburg 《Geophysical Journal International》2006,167(1):77-88

  相似文献   

Golden perch Macquaria ambigua are flexible spawners in the Darling River,Australia     

B.C. Ebner  O. Scholz  B. Gawne 《新西兰海洋与淡水研究杂志》2013,47(2):571-578

The role of flow and floodplains for the recruitment of fishes in the Murray‐Darling Basin, Australia, remains a contentious issue. In this context, the reproductive ecology of golden perch Macquaria ambigua, a widespread, high‐profile angling species with a propensity to produce large numbers of semi‐pelagic eggs remains to be resolved. Back‐calculation of spawning dates from otoliths of juvenile golden perch (Macquaria ambigua) collected in August and November 1997 from the Menindee Lakes on the floodplain of the Darling River, in western New South Wales, Australia, advances understanding of spawning of this species in three ways: (1) golden perch spawned at lower temperatures (≤18.8°C) than has previously been reported from the Murray‐Darling Basin; (2) golden perch in the Menindee Lakes can be derived from spawning in all seasons of the year in contrast to what is apparent in more southerly locations of the Murray‐Darling Basin; and (3) spawning can occur in the absence of floods.  相似文献   

Superconducting cosmic strings in background fields     

O. Heinrich 《Astronomische Nachrichten》1990,311(3):201-201

  相似文献