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11.
Iron isotopes constrain biologic and abiologic processes in banded iron formation genesis 总被引:10,自引:0,他引:10
The voluminous 2.5 Ga banded iron formations (BIFs) from the Hamersley Basin (Australia) and Transvaal Craton (South Africa) record an extensive period of Fe redox cycling. The major Fe-bearing minerals in the Hamersley-Transvaal BIFs, magnetite and siderite, did not form in Fe isotope equilibrium, but instead reflect distinct formation pathways. The near-zero average δ56Fe values for magnetite record a strong inheritance from Fe3+ oxide/hydroxide precursors that formed in the upper water column through complete or near-complete oxidation. Transformation of the Fe3+ oxide/hydroxide precursors to magnetite occurred through several diagenetic processes that produced a range of δ56Fe values: (1) addition of marine hydrothermal , (2) complete reduction by bacterial dissimilatory iron reduction (DIR), and (3) interaction with excess that had low δ56Fe values and was produced by DIR. Most siderite has slightly negative δ56Fe values of ∼ −0.5‰ that indicate equilibrium with Late Archean seawater, although some very negative δ56Fe values may record DIR. Support for an important role of DIR in siderite formation in BIFs comes from previously published C isotope data on siderite, which may be explained as a mixture of C from bacterial and seawater sources.Several factors likely contributed to the important role that DIR played in BIF formation, including high rates of ferric oxide/hydroxide formation in the upper water column, delivery of organic carbon produced by photosynthesis, and low clastic input. We infer that DIR-driven Fe redox cycling was much more important at this time than in modern marine systems. The low pyrite contents of magnetite- and siderite-facies BIFs suggests that bacterial sulfate reduction was minor, at least in the environments of BIF formation, and the absence of sulfide was important in preserving magnetite and siderite in the BIFs, minerals that are poorly preserved in the modern marine record. The paucity of negative δ56Fe values in older (Early Archean) and younger (Early Proterozoic) BIFs suggests that the extensive 2.5 Ga Hamersley-Transvaal BIFs may record a period of maximum expansion of DIR in Earth’s history. 相似文献
12.
13.
Glutathione S-transferase activity was measured in the hepatic cytosol front Dissostichus mawsoni and Pagothenia borchgrevinki. Activity measures with 1-chloro-2,4-dinitrobenzene as substrate were 11·2 and 16·7 μmol/min/g tissue respectively. Little or no activity was detected when p-nitrobenzyl chloride or 3,4-dichloro-1-nitrobenzene were used as substrate. The hepatic glutathione S-transferases from D. mawsoni were partially purified using gel filtration and chromatofocusing. Three peaks of activity were resolved. The major isozyme (158-fold purification) eluting at pH7·1 appeared to be catalytically a homodimer. The isozyme was highly inhibited by triphenyltin chloride (IC50 = 0·1 μ) while inhibition constants for Cibicron Blue 3GA, bromosulphophalein and hematin were 1·1, 20 and 34 μ respectively. 相似文献
14.
An improved Ewing heat probe frame 总被引:3,自引:0,他引:3
The standard Ewing heat probe frame has been improved through the design of a new takedown model whose parts are held together by lynch pins. When a 600 lb (272 kg) unit of this type is taken apart, the heaviest single piece of the dismantled unit weighs only 75 lb (34 kg).This makes it feasible for one person to handle, transport, and assemble the new unit. A central, main support member of a heat probe using this frame can be suspended over the side of a research vessel while the heavier temperature recorder and ballast weights are attached by means of the quickaction lynch pins. This makes it possible to use this device on relatively small vessels which are not designed for coring work, having a minimum of free deck space and without launching platforms or hydraulic A-frame booms. 相似文献
15.
16.
Clark Jeffries 《Astrophysics and Space Science》1996,238(2):201-215
The goal of this paper is to account for the complete observed rotation curves of disk galaxies without dark matter. To attain that goal, use is made of a conservation law from stability theory of linear waves, leading to a vector-based theory of gravitation. In the theory, galactic centers are sites of strong gravitational fields. The new theory predicts extra matter at the center of disk galaxies, which is well-known to be consistent with intergalactic dynamics. For given disk radiusr
0 and edge tangential speedv, the greater the deviation of a rotation curve from linear (solid disk rotation), the greater the mass of the galaxy as a multiple of Newtonian massr
0v2/G, up to a factor of about 1000. In an approximate calculation it turns out that disk density (r) (in kg m–2) is proportional to 1/r for typical rotation curves. Rotation is characterized by two constants which in turn are determined by the edge speed and mass distribution. Not just any curve shape can be so obtained; in fact, the theoretically possible curves correspond to observed curves. 相似文献
17.
Brian L. Beard L. Gordon Medaris Jr Clark M. Johnson Emil Jelínek J. Tonika Lee R. Riciputi 《International Journal of Earth Sciences》1995,84(3):552-567
The Mariánské Lázn complex (MLC) is located in the Bohemian Massif along the north-western margin of the Teplá-Barrandian microplate and consists of metagabbro, amphibolite and eclogite, with subordinate amounts of serpentinite, felsic gneiss and calcsilicate rocks. The MLC is interpreted as a metaophiolite complex that marks the suture zone between the Saxothuringian rocks to the north-west and the Teplá-Barrandian microplate to the south-east. Sm-Nd geochronology of garnet-omphacite pairs from two eclogite samples yields ages of 377±7, and 367±4 Ma. Samples of eclogite and amphibolite do not define a whole rock Sm-Nd isochron, even though there is a large range in Sm/Nd ratio, implying that the suite of samples may not be cogenetic. Eclogites do not have correlated
Nd values and initial 87Sr/86Sr ratios. Five of the eight eclogite samples have high
Nd values (+10.2 to +7.1) consistent with derivation from a MORB-like source, but variable 87Sr/86Sr ratios (0.7033 to 0.7059) which probably reflect hydrothermal seawater alteration. Three other eclogite samples have lower Nd values (+ 5.4 to –0.8) and widely variable 87Sr/86Sr ratios (0.7033 to 0.7096). Such low Nd values are inconsistent with derivation from a MORB, source and may reflect a subduction or oceanic island basalt component in their source. The MLC is an important petrotectonic element in the Bohemian Massif, providing evidence for Cambro-Ordovician formation of oceanic crust and interaction with seawater, Late Devonian (Frasnian-Famennian) high- and medium-pressure metamorphism related to closure of a Saxothuringian ocean basin, Early Carboniferous (Viséan) thrusting of the Teplá terrane over Saxothuringian rocks and Late Viséan extension. 相似文献
18.
Roger N. Clark 《Icarus》1979,40(1):94-103
As planetary reflectance measurements are extended into the infrared, the emitted thermal radiation becomes larger than the reflected solar component. This paper describes a method for removal of the thermal component from planetary reflectance measurements and discusses the limitations involved. Examples are shown for the case of lunar observations where the temperature and emissivity are known and for Mercury where it is assumed the temperature and emissivity are unknown. 相似文献
19.
A crystal-chemical classification of borate structures with emphasis on hydrated borates 总被引:1,自引:0,他引:1
The rules governing formation of hydrated borate polyanions that were proposed by C.L. Christ in 1960 are critically reviewed and new rules added on the basis of recent crystal structure determinations. Principles and classifications previously published by others are also critically reviewed briefly. The fundamental building blocks from which borate polyanions can be constructed are defined on the basis of the number n of boron atoms, and the fully hydrated polyanions are illustrated. Known structures are grouped accordingly, and a shorthand notation using n and symbols Δ = triangle, T = tetrahedron is introduced so that the polyanions can be easily characterized. For example, 3:Δ+2T describes [B3O3(OH)5]2?. Correct structural formulas are assigned borates with known structures whereas borates of unknown structure are grouped separately. 相似文献
20.
The total solar eclipse of February 26, 1979 was monitored at far infrared wavelengths from the NASA Lear Jet Observatory flying at 12.9 km in the eclipse shadow. The resultant eclipse curve for radiation within a bandwidth of 20 cm–1 centered upon 25 cm–1 (400 m) was measured and analysed at an equivalent angular resolution of 1 arc sec over a 100 arc sec region adjacent to the limb to provide information on the intensity distribution of continuum radiation close to this limb. The curve has been compared to predictions derived from models of the solar atmosphere for the specific geometry of this eclipse, and is shown to match most closely that derived from a uniform distribution of radiation across the disk. This is in distinct contrast to the result obtained in the only other comparable experiment, carried out over Africa in 1973 from a supersonic Concorde aircraft, in which an intense but narrow spike of far infrared radiation at the extreme solar limb was inferred from the data. The absence also in the present observations of the significant limb brightening predicted by the HSRA model (in which homogeneity within the source region is assumed) is in substantial agreement with lower resolution results from mountain altitudes. This result is interpreted as further evidence for the presence in the Sun's lower chromosphere of significant inhomogeneity with a scale size of at least 1000 km at this depth. 相似文献