Time–temperature evolution of microtextures and contained fluids in a plutonic alkali feldspar during heating     

Ian Parsons  John D. Fitz Gerald  James K. W. Lee  Tim Ivanic  Ute Golla-Schindler 《Contributions to Mineralogy and Petrology》2010,160(2):155-180

Microtextural changes brought about by heating alkali feldspar crystals from the Shap granite, northern England, at atmospheric pressure, have been studied using transmission and scanning electron microscopy. A typical unheated phenocryst from Shap is composed of about 70 vol% of tweed orthoclase with strain-controlled coherent or semicoherent micro- and crypto-perthitic albite lamellae, with maximum lamellar thicknesses <1 μm. Semicoherent lamellae are encircled by nanotunnel loops in two orientations and cut by pull-apart cracks. The average bulk composition of this microtexture is Ab_27.6Or_71.8An_0.6. The remaining 30 vol% is deuterically coarsened, microporous patch and vein perthite composed of incoherent subgrains of oligoclase, albite and irregular microcline. The largest subgrains are ~3 μm in diameter. Heating times in the laboratory were 12 to 6,792 h and T from 300°C into the melting interval at 1,100°C. Most samples were annealed at constant T but two were heated to simulate an ⁴⁰Ar/³⁹Ar step-heating schedule. Homogenisation of strain-controlled lamellae by Na↔K inter-diffusion was rapid, so that in all run products at >700°C, and after >48 h at 700°C, all such regions were essentially compositionally homogeneous, as indicated by X-ray analyses at fine scale in the transmission electron microscope. Changes in lamellar thickness with time at different T point to an activation energy of ~350 kJmol⁻¹. A lamella which homogenised after 6,800 h at 600°C, therefore, would have required only 0.6 s to do so in the melting interval at 1,100°C. Subgrains in patch perthite homogenised more slowly than coherent lamellae and chemical gradients in patches persisted for >5,000 h at 700°C. Homogenisation T is in agreement with experimentally determined solvi for coherent ordered intergrowths, when a 50–100°C increase in T for An₁ is applied. Homogenisation of lamellae appears to proceed in an unexpected manner: two smooth interfaces, microstructurally sharp, advance from the original interfaces toward the mid-line of each twinned, semicoherent lamella. In places, the homogenisation interfaces have shapes reflecting the local arrangements of nanotunnels or pull-aparts. Analyses confirm that the change in alkali composition is also relatively sharp at these interfaces. Si–Al disordering is far slower than alkali homogenisation so that tweed texture in orthoclase, tartan twinning in irregular microcline, and Albite twins in albite lamellae and patches persisted in all our experiments, including 5,478 h at 700°C, 148 h at 1,000°C and 5 h at 1,100°C, even though the ensemble in each case was chemically homogeneous. Nanotunnels and pull-aparts were modified after only 50 min at 500°C following the simulated ⁴⁰Ar/³⁹Ar step-heating schedule. New features called ‘slots’ developed away from albite lamellae, often with planar traces linking slots to the closest lamella. Slot arrays were often aligned along ghost-like regions of diffraction contrast which may mark the original edges of lamellae. We suggest that the slot arrays result from healing of pull-aparts containing fluid. At 700°C and above, the dominant defects were subspherical ‘bubbles’, which evolved from slots or from regions of deuteric coarsening. The small degree of partial melting observed after 5 h at 1,100°C was often in the vicinity of bubbles. Larger micropores, which formed at subgrain boundaries in patch perthite during deuteric coarsening, retain their shape up to the melting point, as do the subgrain boundaries themselves. It is clear that modification of defects providing potential fast pathways for diffusion in granitic alkali feldspars begins below 500°C and that defect character progressively changes up to, and beyond, the onset of melting.  相似文献   

Isotopic mass dependence of metal cation diffusion coefficients in liquid water     

Ian C. Bourg  Frank M. Richter  Garrison Sposito 《Geochimica et cosmochimica acta》2010,74(8):2249-5818

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The Tarim picrite–basalt–rhyolite suite, a Permian flood basalt from northwest China with contrasting rhyolites produced by fractional crystallization and anatexis     

Wei Tian  Ian H. Campbell  Charlotte M. Allen  Ping Guan  Wenqing Pan  Mimi Chen  Hongjiao Yu  Wenping Zhu 《Contributions to Mineralogy and Petrology》2010,160(3):407-425

We report major and trace element composition, Sr–Nd isotopic and seismological data for a picrite–basalt–rhyolite suite from the northern Tarim uplift (NTU), northwest China. The samples were recovered from 13 boreholes at depths between 5,166 and 6,333 m. The picritic samples have high MgO (14.5–16.8 wt%, volatiles included) enriched in incompatible element and have high ⁸⁷Sr/⁸⁶Sr and low ¹⁴³Nd/¹⁴⁴Nd isotopic ratios (εNd (t) = −5.3; Sr_i = 0.707), resembling the Karoo high-Ti picrites. All the basaltic samples are enriched in TiO₂ (2.1–3.2 wt%, volatiles free), have high FeOt abundances (11.27–15.75 wt%, volatiles free), are enriched in incompatible elements and have high Sr and low Nd isotopic ratios (Sr_i = 0.7049–0.7065; εNd (t) = −4.1 to −0.4). High Nb/La ratios (0.91–1.34) of basalts attest that they are mantle-derived magma with negligible crustal contamination. The rhyolite samples can be subdivided into two coeval groups with overlapping U–Pb zircon ages between 291 ± 4 and 272 ± 2 Ma. Group 1 rhyolites are enriched in Nb and Ta, have similar Nb/La, Nb/U, and Sr–Nd isotopic compositions to the associated basalts, implying that they are formed by fractional crystallization of the basalts. Group 2 rhyolites are depleted in Nb and Ta, have low Nb/La ratios, and have very high Sr and low Nd isotopic ratios, implying that crustal materials have been extensively, if not exclusively, involved in their source. The picrite–basalt–rhyolite suite from the NTU, together with Permian volcanic rocks from elsewhere Tarim basin, constitute a Large Igneous Province (LIP) that is characterized by large areal extent, rapid eruption, OIB-type chemical composition, and eruption of high temperature picritic magma. The Early Permian magmatism, which covered an area >300,000 km², is therefore named the Tarim Flood Basalt.  相似文献   

The mountains that triggered the Late Neoproterozoic increase in oxygen: The Second Great Oxidation Event   总被引：1，自引：0，他引：1  

Ian H. Campbell  Richard J. Squire 《Geochimica et cosmochimica acta》2010,74(15):4187-409

The consensus view is that the O₂ concentration of the Archean atmosphere was very low and that it rose to its present level of 21% in a series of steps, two of which dwarf the others in importance. The first, known as the Great Oxidation Event, occurred at ∼2.4 Ga. It involved an increase in the relative abundance of O₂, which has been estimated at three orders of magnitude, and it is important because it led to the first surface weathering. The second, although less important in relative terms, involved the addition of 9 × 10¹⁷ kg of O₂ to the atmosphere, at least ten times as much as that required to produce the Great Oxidation Event. Its importance lies in the fact that it correlates with the rise of animals in the Ediacaran and Early Cambrian periods. Although it is widely accepted that an increase in atmospheric O₂ facilitated the appearance of animals at ∼575 Ma, followed by the Cambrian Explosion ∼50 Myr later, the cause of this increase remains controversial. We show that the surge in the O₂ level near the Precambrian-Cambrian boundary correlates with major episodes of continent-continent collision associated with Gondwana’s amalgamation, including convergence between East and West Gondwana, which produced the 8000-km-long Transgondwanan Supermountains. The eroded roots of these mountains include the oldest lawsonite-bearing blueschists and eclogites, and ultra high-pressure metamorphic rocks. The sudden appearance of these low-thermal gradient, high-pressure metamorphic rocks implies that the Gondwanan orogenic zones were cooler and stronger than those associated with the assembly of earlier supercontinents and therefore capable of supporting higher mountains.There is a log-linear relationship between relief and erosion rate, and a linear relationship between sedimentation rate and organic C burial. Taken together these two relationships imply a log-linear relationship between relief and C sequestration. We suggest that the Gondwanan supermountains were higher than those produced during the assembly of earlier supercontinents and that rapid erosion of these mountains released a large flux of essential nutrients, including Fe and P, into the rivers and oceans, which triggered an explosion of algae and cyanobacteria. This, in turn, produced a marked increase in the production rate of photosynthetic O₂. Rapid sedimentation during this period promoted high rates of burial of biogenic pyrite and organic matter generated during photosynthesis so that they could not back react with O₂, leading to a sustained increase in atmospheric O₂.  相似文献   

Two cycles of voluminous pyroclastic volcanism and sedimentation related to episodic granite emplacement during the late Archean: Eastern Yilgarn Craton,Western Australia     

Richard J. Squire  Charlotte M. Allen  Ray A.F. Cas  Ian H. Campbell  Richard S. Blewett  Alexander A. Nemchin 《Precambrian Research》2010

The thick piles of late-Archean volcaniclastic sedimentary successions that overlie the voluminous greenstone units of the eastern Yilgarn Craton, Western Australia, record the important transition from the cessation in mafic-ultramafic volcanism to cratonisation between about 2690 and 2655 Ma. Unfortunately, an inability to clearly subdivide the superficially similar sedimentary successions and correlate them between the various geological terranes and domains of the eastern Yilgarn Craton has led to uncertainty about the timing and nature of the region's palaeogeographic and palaeotectonic evolution. Here, we present the results of some 2025 U–Pb laser-ablation-ICP-MS analyses and 323 Sensitive High-Resolution Ion Microprobe (SHRIMP) analyses of detrital zircons from 14 late-Archean felsic clastic successions of the eastern Yilgarn Craton, which have enabled correlation of clastic successions. The results of our data, together with those compiled from previous studies, show that the post-greenstone sedimentary successions include two major cycles that both commenced with voluminous pyroclastic volcanism and ended with widespread exhumation and erosion associated with granite emplacement. Cycle One commences with an influx of rapidly reworked feldspar-rich pyroclastic debris. These units, here-named the Early Black Flag Group, are dominated by a single population of detrital zircons with an average age of 2690–2680 Ma. Thick (up to 2 km) dolerite bodies, such as the Golden Mile Dolerite, intrude the upper parts of the Early Black Flag Group at about 2680 Ma. Incipient development of large granite domes during Cycle One created extensional basins predominantly near their southeastern and northwestern margins (e.g., St Ives, Wallaby, Kanowna Belle and Agnew), into which the Early Black Flag Group and overlying coarse mafic conglomerate facies of the Late Black Flag Group were deposited. The clast compositions and detrital-zircon ages of the late Black Flag Group detritus match closely the nearby and/or stratigraphically underlying successions, thus suggesting relatively local provenance. Cycle Two involved a similar progression to that observed in Cycle One, but the age and composition of the detritus were notably different. Deposition of rapidly reworked quartz-rich pyroclastic deposits dominated by a single detrital-zircon age population of 2670–2660 Ma heralded the beginning of Cycle Two. These coarse-grained quartz-rich units, are name here the Early Merougil Group. The mean ages of the detrital zircons from the Early Merougil Group match closely the age of the peak in high-Ca (quartz-rich) granite magmatism in the Yilgarn Craton and thus probably represent the surface expression of the same event. Successions of the Late Merougil Group are dominated by coarse felsic conglomerate with abundant volcanic quartz. Although the detrital zircons in these successions have a broad spread of age, the principal sub-populations have ages of about 2665 Ma and thus match closely those of the Early Merougil Group. These successions occur most commonly at the northwestern and southeastern margins of the granite batholiths and thus are interpreted to represent resedimented units dominted by the stratigraphically underlying packages of the Early Merougil Group. The Kurrawang Group is the youngest sedimentary units identified in this study and is dominated by polymictic conglomerate with clasts of banded iron formation (BIF), granite and quartzite near the base and quartz-rich sandstone units containing detrital zircons aged up to 3500 Ma near the top. These units record provenance from deeper and/or more-distal sources. We suggest here that the principal driver for the major episodes of volcanism, sedimentation and deformation associated with basin development was the progressive emplacement of large granite batholiths. This interpretation has important implication for palaeogeographic and palaeotectonic evolution of all late-Archean terranes around the world.  相似文献   

Equation of state and pressure-induced structural changes in mirabilite (Na2SO4·10H2O) determined from ab initio density functional theory calculations     

Helen E. A. Brand  A. Dominic Fortes  Ian G. Wood  Lidunka Vočadlo 《Physics and Chemistry of Minerals》2010,37(5):265-282

We have carried out ab initio calculations using density functional theory to determine the bulk elastic properties of mirabilite, Na₂SO₄·10H₂O, and to obtain information on structural trends caused by the application of high pressure up to ~60 GPa. We have found that there are substantial isosymmetric discontinuous structural re-organisations at ~7.7 and ~20 GPa caused by changes in the manner in which the sodium cations are coordinated by water molecules. The low-pressure and intermediate-pressure phases both have sodium in sixfold coordination but in the high-pressure phase the coordination changes from sixfold to sevenfold. These coordination changes force a re-arrangement of the hydrogen-bond network in the crystal. The trend is towards a reduction in the number of hydrogen bonds donated to the sulphate group (from twelve down to six over the range 0–60 GPa) and an increase in hydrogen bonding amongst the Na-coordinated water molecules and the two interstitial water molecules. Ultimately, we observe proton transfers from the interstitial waters (forming OH^? ions) to two of the Na-coordinated waters (forming a pair of H₃O⁺ ions). The equation of state in the athermal limit of the low-pressure phase of mirabilite, parameterised by fitting an integrated form of the third-order Birch-Murnaghan expression to the calculated energy as a function of unit-cell volume, yields the zero-pressure unit-cell volume, V ₀ = 1468.6(9) ų, the incompressibility, K ₀ = 22.21(9) GPa, and the first pressure derivative K ₀′ = (?K/?P)₀ = 5.6(1).  相似文献   

Monitoring the remediation of a near shore waste disposal site in Antarctica using the amphipod Paramoera walkeri and diffusive gradients in thin films (DGTs)     

Stark JS  Johnstone GJ  Palmer AS  Snape I  Larner BL  Riddle MJ 《Marine pollution bulletin》2006,52(12):1595-1610

The water quality of a marine embayment (Brown Bay) was monitored during the remediation of an abandoned waste disposal site at Casey Station, East Antarctica, using a combination of biomonitoring and chemical methods. The Antarctic amphipod Paramoera walkeri, in field mesocosms suspended in the water column, was deployed adjacent to the site and at two reference sites for periods of 14 days, repeated three times during the remediation period (December to February). Diffusive gradients in thin film (DGT) samplers were deployed for the same periods to provide estimates of dissolved metals. No difference in mortality of amphipods was observed between Brown Bay and reference sites. There were significant differences, however, in accumulated metal concentrations between amphipods from Brown Bay and reference sites, with greater concentrations of antimony, copper, cadmium, lead, iron and tin at Brown Bay. The melt water/runoff treatment strategy employed for the remediation was successful in preventing acute toxic effects, but water quality was reduced at Brown Bay, where increased metal bioavailability may have been high enough to induce chronic effects in some biota. DGT samplers were less sensitive than amphipods in detecting differences in metal concentrations between sites, indicating that metals bound to suspended particulates were a potentially significant source of contamination.  相似文献   

Stratigraphy and sedimentology of the Upper Cretaceous to Paleogene Kilwa Group, southern coastal Tanzania   总被引：2，自引：0，他引：2  

Christopher J. Nicholas  Paul N. Pearson  Paul R. Bown  Tom Dunkley Jones  Brian T. Huber  Amina Karega  Jackie A. Lees  Ian K. McMillan  Aoife O&#x;Halloran  Joyce M. Singano  Bridget S. Wade 《Journal of African Earth Sciences》2006,45(4-5):431-466

The geology of southern coastal Tanzania has remained poorly understood since the first comments on its stratigraphy were made over 100 years ago. However, new field surveys combined with shallow drilling along the coast between Kilwa and Lindi are beginning to resolve the depositional history and structural evolution of this region over the past 85 Ma. Here we present the first attempt to synthesize the results of these studies to provide a coherent sedimentological, litho- and sequence stratigraphic framework, including new geological maps, for the Upper Cretaceous and Paleogene of the coastal zone.Santonian to Oligocene sediments crop out along a broad coastal belt south of the Rufiji River from the Kilwa peninsula to Lindi Creek in southern Tanzania. During 55 Ma, over 1 km of a broadly homogeneous, mid to outer shelf clay-dominated succession was deposited across the passive margin, which we define here as the Kilwa Group. This lies disconformably across the shelf on Albian marls and is itself unconformably overlain by shallow water Miocene clays and more recent limestones, sands and gravels. Four formations can be identified within the Kilwa Group on the basis of characteristic secondary lithologies and facies, described here for the first time; the Nangurukuru, Kivinje, Masoko and Pande Formations. These formations include conformable stratigraphic intervals through both the Paleocene–Eocene and Eocene–Oligocene boundaries. Within the Kilwa Group, 12 sequence stratigraphic cycles can be identified at present, demonstrating relatively uniform and continual subsidence across the margin from Santonian to Early Oligocene time. A further major bounding surface is present between the Upper Cretaceous and Paleogene, but this may become partly conformable in the Lindi area. Although the principal lithology in all formations is clay or claystone, there are more permeable intervals containing pervasive coarser siliciclastic sediments and these have yielded traces of crude oil which is likely to have migrated from lower in the succession. The Kilwa Group thus also provides important new evidence for petroleum play development in the southern coastal zone.  相似文献   

Baseline metal concentrations in Paramoera walkeri from East Antarctica     

Palmer AS  Snape I  Stark JS  Johnstone GJ  Townsend AT 《Marine pollution bulletin》2006,52(11):1441-1449

Remediation of the Thala Valley waste disposal site near Casey Station, East Antarctica was conducted in the austral summer of 2003/2004. Biomonitoring of the adjacent marine environment was undertaken using the gammaridean amphipod Paramoera walkeri as a sentinel species [Stark, J.S., Johnstone, G.J., Palmer, A.S., Snape, I., Larner, B.L., Riddle, M.J., in press, . Monitoring the remediation of a near shore waste disposal site in Antarctica using the amphipod Paramoera walkeri and diffusive gradients in thin films (DGTs). Marine Pollution Bulletin and references therein]. Determination of uptake of metals and hypothesis testing for differences that could be attributed to contamination required the establishment of baseline metal concentrations in P. walkeri. Baseline metal concentrations from two reference locations in the Windmill Islands are presented here. P. walkeri was a found to be a sensitive bioaccumulating organism that recorded spatial and temporal variability at the reference sites. Measurement of metals in P. walkeri required the development of a simple digestion procedure that used concentrated nitric acid. For the first time, rare earth metals were determined with additional clean procedures required to measure ultra low concentrations using magnetic sector ICP-MS. Certified and in-house reference materials were employed to ensure method reliability.  相似文献   

Trace metal characterisation of marine sediment reference materials MESS-3 and PACS-2 in dilute HCl extracts     

Townsend AT  Palmer AS  Stark SC  Samson C  Scouller RC  Snape I 《Marine pollution bulletin》2007,54(2):236-239

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