Environmental Monitoring and Peat Assessment Using Multivariate Analysis of Regional-Scale Geochemical Data     

Jennifer M. McKinley  Eric Grunsky  Ute Mueller 《Mathematical Geosciences》2018,50(2):235-246

A compositional multivariate approach was used to analyse regional-scale soil geochemical data obtained as part of the Tellus Project generated by the Geological Survey of Northern Ireland. The multi-element total concentration data presented comprise X-ray fluorescence (XRF) analyses of 6862 rural soil samples collected at 20-cm depth on a non-aligned grid at one site per \(2\,\hbox {km}^{2}\). Censored data were imputed using published detection limits. Each soil sample site was assigned to the regional geology map, resulting in spatial data for one categorical variable and 35 continuous variables comprised of individual and amalgamated elements. This paper examines the extent to which soil geochemistry reflects the underlying geology or superficial deposits. Since the soil geochemistry is compositional, log-ratios were computed to adequately evaluate the data using multivariate statistical methods. Principal component analysis (PCA) and minimum/maximum autocorrelation factors (MAF) were used to carry out linear discriminant analysis (LDA) as a means to discover and validate processes related to the geologic assemblages coded as age bracket. Peat cover was introduced as an additional category to measure the ability to predict and monitor fragile ecosystems. Overall prediction accuracies for the age bracket categories were 68.4 % using PCA and 74.7 % using MAF. With inclusion of peat, the accuracy for LDA classification decreased to 65.0 and 69.9 %, respectively. The increase in misclassification due to the presence of peat may reflect degradation of peat-covered areas since the creation of superficial deposit classification.  相似文献   

Composition,Age, and Origin of Cretaceous Granitic Magmatism on the Eastern Chukchi Peninsula     

M.?V.?LuchitskayaEmail author  S.?D.?Sokolov  V.?Pease  E.?Miller  B.?V.?Belyatsky 《Geotectonics》2018,52(3):312-330

New geochronological and isotopic geochemical data are given, which make it possible to recognize two types of granitic rocks on the eastern Chukchi Peninsula. Early Cretaceous Tkachen and Dolina granitic plutons with zircon ages (U–Pb SIMS) of 119–122 and 131–136 Ma are related to the first type. They cut through Devonian–Lower Carboniferous basement rocks and are overlain by the Aptian–Albian Etelkuyum Formation. Basal units of the latter contain fragments of granitic rocks. Late Cretaceous Provideniya and Rumilet granitic plutons, which contain zircons with ages of 94 and 85 Ma (U–Pb SIMS), respectively, belong to the second type. They cut through volcanic–sedimentary rocks of the Etelkuyum and Leurvaam formations pertaining to the Okhotsk–Chukotka Volcanic Belt. In petrographic and geochemical features, the Early Cretaceous granitic rocks of the Tkachen Pluton are commensurable with I-type granites, while Late Cretaceous granite of the Rumilet Pluton is comparable to A₂-type granite. The Sr–Nd isotopic data provide evidence that from the Early Cretaceous Tkachen and Dolina plutons to the Late Cretaceous Provideniya and Rumilet plutons, the degree of crustal assimilation of suprasubduction mantle-derived melts increases up to partial melting of heterogeneous continental crust enriched in rubidium. An unconformity and various degrees of secondary alteration of volcanic–sedimentary rocks have been established in the Okhotsk–Chukotka Volcanic Belt, and this was apparently caused by transition of the tectonic setting from suprasubduction to a transform margin with local extension.  相似文献   

Conodont geothermometry in pyroclastic kimberlite: constraints on emplacement temperatures and cooling histories     

Pell  Jennifer  Russell  James K.  Zhang  Shunxin 《Mineralogy and Petrology》2018,112(2):477-490

Kimberlite pipes from Chidliak, Baffin Island, Nunavut, Canada host surface-derived Paleozoic carbonate xenoliths containing conodonts. Conodonts are phosphatic marine microfossils that experience progressive, cumulative and irreversible colour changes upon heating that are experimentally calibrated as a conodont colour alteration index (CAI). CAI values permit us to estimate the temperatures to which conodont-bearing rocks have been heated. Conodonts have been recovered from 118 samples from 89 carbonate xenoliths collected from 12 of the pipes and CAI values within individual carbonate xenoliths show four types of CAI distributions: (1) CAI values that are uniform throughout the xenolith; (2) lower CAIs in core of a xenolith than the rim; (3) CAIs that increase from one side of the xenolith to the other; and, (4) in one xenolith, higher CAIs in the xenolith core than at the rim. We have used thermal models for post-emplacement conductive cooling of kimberlite pipes and synchronous heating of conodont-bearing xenoliths to establish the temperature–time history of individual xenoliths within the kimberlite bodies. Model results suggest that the time-spans for xenoliths to reach the peak temperatures recorded by CAIs varies from hours for the smallest xenoliths to 2 or 3 years for the largest xenoliths. The thermal modelling shows the first three CAI patterns to be consistent with in situ conductive heating of the xenoliths coupled to the cooling host kimberlite. The fourth pattern remains an anomaly.

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The role of hydrothermal fluids in sedimentation in saline alkaline lakes: Evidence from Nasikie Engida,Kenya Rift Valley     

Robin W. Renaut  R. Bernhart Owen  Tim K. Lowenstein  Gijs De Cort  Emma Mcnulty  Jennifer J. Scott  Anthony Mbuthia 《Sedimentology》2021,68(1):108-134

Saline alkaline lakes that precipitate sodium carbonate evaporites are most common in volcanic terrains in semi‐arid environments. Processes that lead to trona precipitation are poorly understood compared to those in sulphate‐dominated and chloride‐dominated lake brines. Nasikie Engida (Little Magadi) in the southern Kenya Rift shows the initial stages of soda evaporite formation. This small shallow (<2 m deep; 7 km long) lake is recharged by alkaline hot springs and seasonal runoff but unlike neighbouring Lake Magadi is perennial. This study aims to understand modern sedimentary and geochemical processes in Nasikie Engida and to assess the importance of geothermal fluids in evaporite formation. Perennial hot‐spring inflow waters along the northern shoreline evaporate and become saturated with respect to nahcolite and trona, which precipitate in the southern part of the lake, up to 6 km from the hot springs. Nahcolite (NaHCO₃) forms bladed crystals that nucleate on the lake floor. Trona (Na₂CO₃·NaHCO₃·2H₂O) precipitates from more concentrated brines as rafts and as bottom‐nucleated shrubs of acicular crystals that coalesce laterally to form bedded trona. Many processes modify the fluid composition as it evolves. Silica is removed as gels and by early diagenetic reactions and diatoms. Sulphate is depleted by bacterial reduction. Potassium and chloride, of moderate concentration, remain conservative in the brine. Clastic sedimentation is relatively minor because of the predominant hydrothermal inflow. Nahcolite precipitates when and where pCO₂ is high, notably near sublacustrine spring discharge. Results from Nasikie Engida show that hot spring discharge has maintained the lake for at least 2 kyr, and that the evaporite formation is strongly influenced by local discharge of carbon dioxide. Brine evolution and evaporite deposition at Nasikie Engida help to explain conditions under which ancient sodium carbonate evaporites formed, including those in other East African rift basins, the Eocene Green River Formation (western USA), and elsewhere.  相似文献   

Built environment and agricultural value at risk from Hurricane Irma flooding in Florida (USA)     

Miller  Alexander J.  Arias  Mauricio E.  Alvarez  Sergio 《Natural Hazards》2021,109(2):1327-1348

Natural Hazards - Flooding is the most costly type of natural disaster, as well as the most frequent. To provide risk-based flood insurance, providers must be able to accurately determine an...  相似文献   

Variable hangingwall palaeotransport during Silurian and Devonian thrusting in the western Lachlan Fold Belt: Missing gold lodes,synchronous Melbourne Trough sedimentation and Grampians Group fold interference     

J. McL. Miller  L. J. Dugdale  C. J. L. Wilson 《Australian Journal of Earth Sciences》2013,60(6):901-909

The western margin of the Lachlan Fold Belt contains early ductile and brittle structures that formed during northeast‐southwest and east‐west compression, followed by reactivation related to sinistral wrenching. At Stawell all of these structural features (and the associated gold lodes) are dismembered by a complex array of later northwest‐, north‐ and northeast‐dipping faults. Detailed underground structural analysis has identified northwest‐trending mid‐Devonian thrusts (Tabberabberan) that post‐date Early Devonian plutonism and have a top‐to‐the‐southwest transport. Deformation associated with the initial stages of dismemberment occurred along an earlier array of faults that trend southwest‐northeast (or east‐west) and dip to the northwest (or north). The initial transport of the units in the hangingwall of these fault structures was top‐to‐the‐southeast. ‘Missing’ gold lodes were discovered beneath the Magdala orebody by reconstructing a displacement history that involved a combination of transport vectors (top‐to‐the‐southeast and top‐to‐the‐southwest). Fold interference structures in the adjacent Silurian Grampians Group provide further evidence for at least two almost orthogonal shortening regimes, post the mid‐Silurian. Overprinting relationships, and correlation with synchronous sedimentation in the Melbourne Trough, indicates that the early fault structures are mid‐ to late‐Silurian in age (Ludlow: ca 420–414 Ma). These atypical southeast‐vergent structures have regional extent and separate significant northeast‐southwest shortening that occurred in the mid‐Devonian (‘Tabberabberan orogeny’) and Late Ordovician (‘Benambran orogeny’).  相似文献   

Structural and metamorphic evolution of the Moornambool Metamorphic Complex,western Lachlan Fold Belt,southeastern Australia     

G. Phillips  J. McL. Miller  C. J. L. Wilson 《Australian Journal of Earth Sciences》2013,60(5):891-913

The wedge‐shaped Moornambool Metamorphic Complex is bounded by the Coongee Fault to the east and the Moyston Fault to the west. This complex was juxtaposed between stable Delamerian crust to the west and the eastward migrating deformation that occurred in the western Lachlan Fold Belt during the Ordovician and Silurian. The complex comprises Cambrian turbidites and mafic volcanics and is subdivided into a lower greenschist eastern zone and a higher grade amphibolite facies western zone, with sub‐greenschist rocks occurring on either side of the complex. The boundary between the two zones is defined by steeply dipping L‐S tectonites of the Mt Ararat ductile high‐strain zone. Deformation reflects marked structural thickening that produced garnet‐bearing amphibolites followed by exhumation via ductile shearing and brittle faulting. Pressure‐temperature estimates on garnet‐bearing amphibolites in the western zone suggest metamorphic pressures of ～0.7–0.8 GPa and temperatures of ～540–590°C. Metamorphic grade variations suggest that between 15 and 20 km of vertical offset occurs across the east‐dipping Moyston Fault. Bounding fault structures show evidence for early ductile deformation followed by later brittle deformation/reactivation. Ductile deformation within the complex is initially marked by early bedding‐parallel cleavages. Later deformation produced tight to isoclinal D₂ folds and steeply dipping ductile high‐strain zones. The S₂ foliation is the dominant fabric in the complex and is shallowly west‐dipping to flat‐lying in the western zone and steeply west‐dipping in the eastern zone. Peak metamorphism is pre‐ to syn‐D₂. Later ductile deformation reoriented the S₂ foliation, produced S₃ crenulation cleavages across both zones and localised S₄ fabrics. The transition to brittle deformation is defined by the development of east‐ and west‐dipping reverse faults that produce a neutral vergence and not the predominant east‐vergent transport observed throughout the rest of the western Lachlan Fold Belt. Later north‐dipping thrusts overprint these fault structures. The majority of fault transport along ductile and brittle structures occurred prior to the intrusion of the Early Devonian Ararat Granodiorite. Late west‐ and east‐dipping faults represent the final stages of major brittle deformation: these are post plutonism.  相似文献   

Stream nitrate uptake and transient storage over a gradient of geomorphic complexity,north‐central Colorado,USA     

Daniel W. Baker  Brian P. Bledsoe  Jennifer Mueller Price 《水文研究》2012,26(21):3241-3252

The understanding of nutrient uptake in streams is impeded by a limited understanding of how geomorphic setting and flow regime interact with biogeochemical processing. This study investigated these interactions as they relate to transient storage and nitrate uptake in small agricultural and urban streams. Sites were selected across a gradient of channel conditions and management modifications and included three 180‐m long geomorphically distinct reaches on each of two streams in north‐central Colorado. The agricultural stream has been subject to historically variable cattle‐grazing practices, and the urban stream exhibits various levels of stabilisation and planform alteration. Reach‐scale geomorphic complexity was characterised using highly detailed surveys of channel morphology, substrate, hydraulics and habitat units. Breakthrough‐curve modelling of conservative bromide (Br^?) and nonconservative nitrate (NO₃^?) tracer injections characterised transient storage and nitrate uptake along each reach. Longitudinal roughness and flow depth were positively associated with transient storage, which was related to nitrate uptake, thus underscoring the importance of geomorphic influences on stream biogeochemical processes. In addition, changes in geomorphic characteristics due to temporal discharge variation led to complex responses in nitrate uptake. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

Fishing rights and small communities: Alaska halibut IFQ transfer patterns     

Courtney Carothers  Daniel K. Lew  Jennifer Sepez 《Ocean & Coastal Management》2010,53(9):518-523

In the Alaska halibut individual fishing quota (IFQ) fishery, small remote fishing communities (SRFCs) have disproportionately lost fishing rights. Our analysis of quota market participation from 1995 to 1999 confirms that SRFC residents are more likely to sell than buy quota. Alaska Native heritage is another important predictor of quota market behavior. Residents of Alaska Native villages have an increased likelihood of selling quota. Loss of fisheries participation in small indigenous communities can be an unintended consequence of quota systems. Mitigation measures should take into account the social factors that can lead to such a redistribution of fishing rights in privatized access fisheries.  相似文献   

Leveraging modern climatology to increase adaptive capacity across protected area networks     

Jennifer E. Davison  Lisa J. Graumlich  Erika L. Rowland  Gregory T. Pederson  David D. Breshears 《Global Environmental Change》2012,22(1):268-274

Human-driven changes in the global environment pose an increasingly urgent challenge for the management of ecosystems that is made all the more difficult by the uncertain future of both environmental conditions and ecological responses. Land managers need strategies to increase regional adaptive capacity, but relevant and rapid assessment approaches are lacking. To address this need, we developed a method to assess regional protected area networks across biophysically important climatic gradients often linked to biodiversity and ecosystem function. We plot the land of the southwestern United States across axes of historical climate space, and identify landscapes that may serve as strategic additions to current protected area portfolios. Considering climate space is straightforward, and it can be applied using a variety of relevant climate parameters across differing levels of land protection status. The resulting maps identify lands that are climatically distinct from existing protected areas, and may be utilized in combination with other ecological and socio-economic information essential to collaborative landscape-scale decision-making. Alongside other strategies intended to protect species of special concern, natural resources, and other ecosystem services, the methods presented herein provide another important hedging strategy intended to increase the adaptive capacity of protected area networks.  相似文献