Chemical effect of pesticide application on soils: evidence from rare earth elements     

Khadija Semhi  Joëlle Duplay  Gwenaël Imfeld  René Boutin 《Arabian Journal of Geosciences》2018,11(19):590

The main objective of this study is to investigate the distribution of rare earth elements (REEs) in Lolium perenne L. plant species which has been grown on vineyard soils treated with pesticide commonly used in the study area. These plants have been grown on two types of soils: (1) brown calcareous soils developed on loess and (2) brown to calcic brown soils developed on conglomerates. The significant correlation observed between the concentrations of phosphorus and the total amount of REEs, in addition to the enrichment in middle REEs (MREEs), suggests the complexation of REEs with phosphates and organic matter. The soils were enriched in REEs due to pesticide application but the plants were depleted. The ratio of REEs in plant over REEs in soil before application of pesticides is higher than that after application of pesticides. Application of pesticides to crops did not affect the fractionation of REEs neither in leaves nor in roots. No selectivity in uptake of REEs occurred because of pesticides except for Ce and Eu which show a negative anomaly relative to the other REEs.  相似文献   

Geostatistics for Environmental Applications     

Maria João Pereira  Amilcar Soares 《Mathematical Geosciences》2018,50(2):123-125

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The distribution of total and methylmercury concentrations in soils near the Idrija mercury mine, Slovenia, and the dependence of the mercury concentrations on the chemical composition and organic carbon levels of the soil     

Takashi Tomiyasu  Akito Matsuyama  Ryusuke Imura  Hitoshi Kodamatani  Junko Miyamoto  Yuriko Kono  David Kocman  Jo?e Kotnik  Vesna Fajon  Milena Horvat 《Environmental Earth Sciences》2012,65(4):1309-1322

Although the mining activity of the Idrija mine in Slovenia ceased in 1995, a large amount of mining dregs containing high concentrations of mercury remains in the area. The mining dregs were transported with river flow and deposition along the Idrija River. To estimate the dispersion and change in the chemical form of mercury, a total of 28 soil core samples were taken around the river. The individual core samples were separated into layers for the analysis of their chemical composition, carbon contents, total mercury (T-Hg) and methylmercury (MeHg) concentrations. The chemical composition measured by X-ray fluorescence spectrometry was useful to estimate the dispersion of tailings: the fluvial terrace soil had a chemical composition similar to that of the tailings and could be distinguished clearly from the forest soil. The highest T-Hg concentration, 1,100 mg kg⁻¹, was observed in the fluvial terrace soil near the mine. Although the concentration decreased gradually along with distance from the mine, concentrations higher than 200 mg kg⁻¹ of T-Hg were still observed in the fluvial terrace soil approximately 20 km downstream from the mine. In the vertical distribution of T-Hg in the hillslope soil, a higher value was observed in the upper layers, which suggests the recent atmospheric deposition of mercury. The concentration of MeHg was the lowest at the riverside and higher in the hillslope soil, which was the opposite of the T-Hg distribution. The total organic carbon content tracked similarly with the distribution of MeHg and a linear relation with a significantly high correlation coefficient was obtained. The distinction may be related to the different dispersion process of mercury, and the organic carbon contents may be an important factor for MeHg formation.  相似文献   

Material characteristics and deterioration evaluation for the 13th century Korean stone pagoda of Magoksa temple     

Young Hoon Jo  Chan Hee Lee  Yu Gun Chun 《Environmental Earth Sciences》2012,66(3):915-922

This study focused on the quantitative deterioration evaluation for the Magoksa temple stone pagoda of the thirteenth century in Korea, based on the deterioration map by precise observation and ultrasonic velocity measurements. The stone pagoda is composed mainly of fine-grained quartz diorite with some granodiorite used in the second story and dew bowl, and the replacement stone for restoration in the basement is biotite granite. The deterioration map and the 2D contour map projecting ultrasonic velocity showed that the most serious deterioration was to the north face of the pagoda, which has about 81.2% deterioration rate and a low velocity range compared with the other directions. Thus, it is required to prepare conservation schemes to reduce deterioration and reinforce the structure. It is also required to carry out ground exploitation for calculation of load carrying strength and ground strength together with continuous structural monitoring. The results will be important for the stable and long-term conservation of the pagoda and will further serve to establish scientific conservation systems of stone cultural heritages in the future.  相似文献   

Monitoring of CO<Subscript>2</Subscript>-rich waters with low pH and low EC: an analogue study of CO<Subscript>2</Subscript> leakage into shallow aquifers     

Gitak Chae  Soonyoung Yu  Minki Jo  Byoung-Young Choi  Taehee Kim  Dong-Chan Koh  Yoon-Yeol Yun  Seong-Taek Yun  Jeong-Chan Kim 《Environmental Earth Sciences》2016,75(5):390

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Leaching and redistribution of Cu and Pb due to simulated road runoff assessed by column leaching test,chemical analysis,and PHREEQC modeling     

Mohammad Nazrul Islam  Young-Tae Jo  Jeong-Hun Park 《Environmental Earth Sciences》2016,75(12):1041

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Information Gathering in Bayesian Networks Applied to Petroleum Prospecting     

Marie Lilleborge  Ragnar Hauge  Jo Eidsvik 《Mathematical Geosciences》2016,48(3):233-257

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Nitrogen uptake in light versus darkness of the seagrass Zostera noltei: integration with carbon metabolism          下载免费PDF全文

Ana Alexandre  João Silva  Rui Santos 《Marine Ecology》2016,37(5):1050-1056

We conducted a study that shows that light and dark conditions do not affect the uptake rates of ammonium and nitrate by the seagrass Zostera noltei. This is an important advantage over some seaweed species in which these rates are severely reduced at night. In the light, the ammonium uptake rates were initially higher (15 and 20 μmol·g^?1·h^?1) and stabilized at a rate of 5 μmol·g^?1·h^?1 after 1 h, whereas in the dark the rates remained constant at a rate of 10 μmol·g^?1·h^?1 over the first 180 min of incubation. The rates of nitrate uptake in the light were high within the first 120 min of incubation (7.2–11.1 μmol·g^?1·h^?1) and decreased afterwards to lower values (0.8–3.9 μmol·g^?1·h^?1), whereas in the dark the rates fluctuated around 0.0–11.1 μmol·g^?1·h^?1 throughout the whole incubation time (7 h). The soluble sugar content of Z. noltei leaves increased significantly with both ammonium and nitrate incubations in the light, indicating the metabolic outcome of photosynthesis. In the dark, there was no significant variation in either the soluble sugar or in the starch content of leaves, rhizomes or roots in either the ammonium or nitrate incubations. However, the total starch content of plants decreased at night whereas the total soluble sugars increased, suggesting a process of starch catabolism to generate energy with the consequent production of smaller monosaccharide products. The starch content of rhizomes decreased significantly during the light incubations with nitrate but not with ammonium. These results suggest that carbohydrate mobilization is necessary for Z. noltei to account for extra energetic costs needed for the uptake and assimilation of nitrate. Furthermore, our results suggest that nitrate uptake, at least during the day, requires the mobilization of starch whereas the uptake of ammonium does not.  相似文献   

Hydrothermal mineralization along submarine rift zones,Hawaii     

James R. Hein  Ann E. Gibbs  David A. Clague  Michael Torresan 《Marine Georesources & Geotechnology》2013,31(2):177-203

This is the first article to describe mineralization of midplate submarine rift zones and hydrothermal manganese oxide mineralization of midplate volcanic edifices. Hydrothermal Mn oxides were recovered from submarine extensions of two Hawaiian rift zones, along Haleakala and Puna Ridges. These Mn oxides form two types of deposits, metallic stratiform layers in volcaniclastic rocks and cement for clastic rocks; both deposit types are composed of todorokite and bimessite. Thin Fe‐Mn crusts that coat some rocks formed by a combination of hydrogenetic and hydrothermal processes and are composed of δ‐MnO₂. The stratiform layers have high Mn contents (mean 40%) and a large fractionation between Mn and Fe (Fe/Mn = 0.04). Unlike most other hydrothermal Mn oxide deposits, those from Hawaiian rift zones are enriched in the trace metals Zn, Co, Ba, Mo, Sr, V, and especially Ni (mean 0.16%). Metals are derived from three sources: mafic and ultramafic rocks leached by circulating hydrothermal fluids, clastic material (in Mn‐cemented sandstone), and seawater that mixed with the hydrothermal fluids. Mineralization on Haleakala Ridge occurred sometime during the past 200 to 400 ka, when the summit was at a water depth of more than 1,000 m. Hydrothermal circulation was probably driven by heat produced by intrusion of dikces, magma reservoirs, and flow of magma through axial and lateral conduits. The supply of seawater to ridge interiors must be extensive because of their high porosity and permeability. Precipitation of Mn oxide below the seafloor is indicated by its occurrence as cement, growth textures that show mineralizing fluids were introduced from below, and pervasive replacement of original matrix of clastic rocks.  相似文献   

Direct impacts of commercial and recreational fishing on spiny lobster,Panulirus interruptus,populations at Santa Catalina Island,California, United States     

Matthew Iacchei  Patrick Robinson  Kathy Ann Miller 《新西兰海洋与淡水研究杂志》2013,47(6):1201-1214

The California spiny or red rock lobster, Panulirus interruptus, is an ecologically and economically important species that has been exploited since the 1800s. No previous study in California has assessed the impacts of the recreational or commercial lobster harvest. Before the 2003–04 commercial and recreational lobster seasons, we conducted a fishery‐independent trap survey at Santa Catalina Island to document the impact of the lobster fisheries on the size structure, abundance, and sex ratios of mature P. interruptus (>65 mm carapace length (CL)). We concurrently sampled a predominantly commercially fished area, a recreationally fished area, and a 23‐year‐old invertebrate no‐take (INT) reserve. Relative to the INT reserve, legal‐size lobsters in the recreational area were similar in CL, but 31% less abundant. Legal‐size lobsters in the commercial area were 8% smaller and 70% less abundant than those in the INT reserve. The sex ratio of legal‐size lobsters, although near 50:50 in the recreational and INT reserve areas, was male‐dominated (67:33) in the commercial area. Differences in CPUE and mean CL of sub‐legal lobsters in the recreational and commercial areas suggest that factors in addition to harvesting pressure may affect these populations. Total biomass of mature lobsters in the recreational and commercial areas was 92% and 45%, respectively, of biomass in the INT reserve. Fecundity in the recreational and commercial areas was 83% and 42%, respectively, of fecundity in the INT reserve. This study provides preliminary data for future ecological studies and fisheries management evaluations.  相似文献