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Positron annihilation lifetime spectroscopy (PALS) has been used to study the vacancy-type defects in fine-particle goethites (α-FeOOH). The PALS spectra reveal three components. The intermediate lifetime component (τ2, I2) is attributed to positrons trapped at vacancy defects. The relative intensity of the intermediate lifetime component, I2, increases significantly with decreasing Néel temperature, and this increase is attributed to increasing concentration of vacancy defects. These results support a model of magnetic ordering of clusters arising from a high concentration of iron vacancies which reduces the Néel temperature in these fine-particle goethites.  相似文献   
225.
Emission of nitrous oxide from temperate forest soils into the atmosphere   总被引:5,自引:0,他引:5  
N2O emission rates were measured during a 13-month period from July 1981 till August 1982 with a frequency of once every two weeks at six different forest sites in the vicinity of Mainz, Germany. The sites were selected on the basis of soil types typical for many of the Central European forest ecosystems. The individual N2O emission rates showed a high degree of temporal and spatial variabilities which, however, were not significantly correlated to variabilities in soil moisture content or soil temperatures. However, the N2O emission rates followed a general seasonal trend with relatively high values during spring and fall. These maxima coincided with relatively high soil moisture contents, but may also have been influenced by the leaf fall in autumn. In addition, there was a brief episode of relatively high N2O emission rates immediately after thawing of the winter snow. The individual N2O emission rates measured during the whole season ranged between 1 and 92 g N2O-N m–2 h–1. The average values were in the range of 3–11 g N2O-N m–2 h–1 and those with a 50% probability were in the range of 2–8 g N2O-N m–2 h–1. The total source strength of temperate forest soils for atmospheric N2O may be in the range of 0.7–1.5 Tg N yr–1.  相似文献   
226.
Complex massive sulfide ores (»black smokers«) as well as mineralized basalts and unconsolidated sediments were sampled during the German research expedition »Garimas 1« in the eastern portions of the Galapagos Rift at 85 50' W longitude. The massive sulfide ores are characterized by a porous, layered, compositional texture with typical colloidal and/or gel textures. Local occurrences of organism remains (worm tubes), which are embedded in the ore, were also found. The composition of the massive sulfide ores exhibits a considerable range, from iron sulfide ores (pyrite, melnikovite-pyrite, marcasite) to copper-rich ores (chalcopyrite), and/or zinc-dominated ores (sphalerite, wurtzite, schalenblende). Additional new types of hydrothermal mineralizations were found, which consist primarily of manganese hydroxide, limonite or Fe-rich smectite (Fe-rich »protosmectite«) together with limonite and opaline silica. Hydrothermally altered basalts may be characterized by significant sulfide contents (primarily pyrite) and, locally, by hematite. Sediments in the vicinity of the »black smokers« frequently contain fragments of complex massive sulfide ores. With increasing distance from the »black smokers« these massive sulfide fragments exhibit complete replacement and pseudomorphism by limonite. Some replacement and pseudomorphism of microorganisms in unconsolidated sediments by limonitic material is also observed. In places, the unconsolidated sediments contain manganese hydroxide mineralizations of hydrothermal origin.
Zusammenfassung Anlä\lich der deutschen Forschungsfahrt »Garimas 1« wurden im östlichen Teil des Galápagos-Riftes bei 85 50' W vor allem komplexe massive Sulfiderze (»Schwarze Raucher« — »Black Smokers«) gewonnen, daneben au\erdem vererzte Basalte sowie unverf estigte Sedimente. Die massiven Sulfiderze sind durch einen porösen, lagig bis krustigschaligen Aufbau gekennzeichnet und weisen charakteristische Kolloidalgefüge bzw. Geltexturen auf. Stellenweise liegen Organismenreste (z. B. Wurmröhren), eingebettet in Erz, vor. Die Zusammensetzung der jeweiligen massiven Sulfiderze schwankt erheblich und reicht von praktisch nur aus Eisensulfid (Pyrit, Melnikovitpyrit, Markasit) beste-henden Bildungen bis zu solchen, die reich an Kupfersulfid (Kupferkies) und/oder Zinksulfid (Zinkblende, Wurtzit, Schalenblende) sind. Als weitere und neue Typen hydrothermaler Bildungen bzw. von »Schwarzen Rauchern« konnten hydrothermale Mineralisationen nachgewiesen werden, die vorherrschend entweder aus Manganhydroxid, aus Limonit oder aus eisenreichem Montmorillonit (Fe-reicher »Protosmektit«) mit Limonit und amorphem SiO2 bestehen. Die alterierten Basalte können stellenweise durch eine reichliche Sulfidführung (vor allem Pyrit) ausgezeichnet sein, wobei gelegentlich auch Eisenglanz beibricht. Die Sedimente aus der Nachbarschaft der »Schwarzen Raucher« enthalten öfters zahlreiche Bruchstücke der komplexen Massivsulfiderze. Diese Sulfiderz-Bruchstücke lassen häufig mit zunehmender Entfernung von den »Schwarzen Rauchern« starke bis völlige Verdrängung und Pseudomorphosierung durch Limonit erkennen. Die in diesen Lockersedimenten vorliegenden rezenten Mikroorganismen zeigen stellenweise Verdrängung und Pseudomorphosierung durch Limonit. In den Lockersedimenten treten Ausscheidungen von Manganhydroxid hydrothermaler Herkunft auf.

Résumé Dans la partie est de la dorsale des Galapagos, par 85 50' de longitude ouest, l'expédition allemande »GARIMAS I« a récolté des minerais sulfurés complexes massifs (minerais de »fumeurs noirs«), ainsi que des basaltes minéralisés et des échantillons de sédiments meubles. Les sulfures massifs présentent un aspect poreux lité à écailleux et montrent des structures colloÏdales caractéristiques. Localement des traces d'organismes (p. ex. des trous de vers) sont inclues dans le minéral. Les sulfures massifs présentent diverses compositions depuis des formations constituées uniquement de sulfures de Fe (pyrite, pyrite »colloÏdale«, marcasite) jusqu'à d'autres qui sont riches en sulfures de cuivre (chalcopyrite) et/ou de zinc (blende, wurtzite, blende zonaire). De plus, d'autres minéralisations hydrothermales, nouvelles dans l'environnement des fumeurs noirs, ont été mises en évidence: elles sont constituées soit d'oxydes et hydroxydes de Mn, soit de limonite ou de montmorillonite riche en fer (»protosmectite« ferreuse) avec de la limonite et silice amorphe. Les basaltes hydrothermalisés peuvent montrer localement une teneur élevée en sulfure (surtout de la pyrite) éventuellement accompagné d'hématite. Les sédiments recueillis au voisinage des fumeurs noirs renferment souvent de nombreux fragments de sulfures complexes massifs. Au fur et à mesure qu'on s'éloigne des fumeurs, ces fragments sont progressivement et mÊme complètement pseudomorphosés en limonite. Cette pseudomorphose limonitique affecte également, par endroits, les micro-organismes récents inclus dans les sédiments meubles. Dans ces derniers ont lieu des formations d'hydroxydes de manganèse d'origine hydrothermale.

- Garimas I 8550 — = Black Smokers -, . , - , , . , .: , . , . . , , , = , / ( , , ). , . . , , , . , , - . , , , , . , .
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227.
Least-squares estimation of storativity and transmissivity from pumping-test data has been concerned with finding the lowest point on a mathematical surface. Since there is no guarantee that such surfaces do not contain local minima, the accuracy of the estimate may be dependent upon the selection of “good” initial values.

An improved estimation procedure can be obtained by converting the two-dimensional minimisation problem into an equivalent form in one dimension. The resulting line function can then be easily evaluated through any given feasible interval. This approach avoids the requirement of initial estimates and always returns the true estimates after a single computation sequence.

Examples are given of the application of the method to both drawdown and recovery data, together with a simple model for the determination of estimation error.  相似文献   

228.
Lead isotopes of K-feldspars from five granites of the SE-Schwarzwald and from metamorphites are positively correlated in 207/204 as well- as 208/204- vs. 206/204-diagrams. The linear alignments may be due to correlated laststage lead isotope evolution (lead-lead isochron) and result in a secondary isochron model age of nearly 3 Ga for the Southern Schwarzwald basement. This calculation implies a long-lasting undisturbed lead isotope evolution in the Schwarzwald basement since the Archaean. This is not supported however by geochronological studies. On the other hand the data together with U/Pb-analyses of whole rock samples from metamorphites are consistent with pre-Hercynian mantle lead addition to the basement. This presumably happened during early Paleozoic polymetamorphism. The interpretation of the lead isotope correlations as mantle-crust mixing lines needs a rather homogeneous pre-Hercynian mantle lead of the MORB-type, delivered to the crust probably in part by ascending volatile phases. Thus geodynamical models are supported which involve subduction of oceanic crust or mantle pluming during the early Paleozoic. In Part I of this report, the trends in Schwarzwald lead isotopes are discussed as secondary isochrons and as mixing lines. Constraints are derived for a pre-Hercynian mantlecrust interaction and for lead redistribution by the Hercynian basement activation.  相似文献   
229.
Summary A simple procedure is presented to eliminate the influence of tidal oscillation from hydrographic measurements. This is done with a transformation from a co-ordinate system fixed in space to a co-ordinate system fixed in time using results of a numerical tidal model. The procedure is applied to a hydrographic survey in the German Bight. The hydrographic structure transformed onto a co-ordinate system fixed in time is much more similar to the structure obtained by satellite pictures and shows dynamical processes much clearer than in a co-ordinate system fixed in space.
Gezeitenkorrektur von hydrographischen Messungen
Zusammenfassung In dieser Arbeit wird ein Verfahren vorgestellt, das hydrographische Messungen vom Einfluß periodischer Variationen durch die Gezeiten bereinigt. Dies geschieht unter Benutzung von Ergebnissen eines numerischen Modells durch eine Transformation einer gemessenen hydrographischen Struktur von einem ortsfesten in ein zeitfestes System. Dieses Verfahren wird auf eine hydrographische Aufnahme der Deutschen Bucht angewandt. Die auf ein zeitfestes Koordinatensystem transformierte hydrographische Messung zeigt sehr viel Ähnlichkeit mit einer synoptischen Messung, die bei einem Satellitenüberflug gewonnen wurde. Bestimmte dynamische Prozesse in der Deutschen Bucht lassen sich zudem im zeitfesten Koordinatensystem besser erkennen als im ortsfesten Koordinatensystem.

Correction de l'influence de la marée sur les mesures hydrologiques
Résumé L'article présente une méthode simple pour éliminer l'influence de la marée sur les mesures hydrologiques. Cela est obtenu par le passage d'un système de coordonnées fixe dans l'espace à un système de coordonnées fixe dans le temps utilisant les résultats d'un modèle numérique de marée. La méthode est appliquée à un levé hydrologique dans la Baie Allemande. La structure hydrologique obtenue dans un système de coordonnées fixe dans le temps est beaucoup plus proche de celle qui est obtenue par les images satellites et décrit le processus dynamique beaucoup plus clairement que dans un système de coordonnées fixe dans l'espace.
  相似文献   
230.
Recent patterns of geologic unrest in long Valley caldera in east-central California emphasize that this large, silicic volcanic system and the adjacent, geologically youthful Inyo-Mono Craters volcanic chain are still active and capable of producing locally hazardous volcanic eruptions. A series of four magnitude -6 earthquakes in May 1980 called attention to this current episode of unrest, and subsequent activity has included numerous earthquake swarms in the south moat of the caldera accompanied by inflation of the resurgent dome by more than 50 cm over the last five years. The seismicity associated with this unrest is currently monitored by a network of 31 telemetered seismic stations with an automatic processing system that yelds hypocentral locations and earthquake magnitudes in near-real time. Deformation of the ground is monitored by a) a series of overlapping trilateration networks that provide coverage ranging from annual measurements of regional deformation to daily measurements of deformation local to the active, southern section of the caldera, b) a regional network of level lines surveyed annually, c) a regional network of precise gravity stations occupied annually, d) local, L-shaped level figures surveyed every few months, and e) a network of fourteen borehole tiltmeter clusters (two instruments in each cluster) and a borehole dilatometer, the telemetered signals from which provide continuous data on deformation rates. Additional telemetered data provide continuous information on fluctuations in the local magnetic field, hydrogen gas emission rates at three sites, and water level and temperatures in three wells. Continuous data on disharge rates and temperatures from hot springs and fumaroles are collected by several on-site recorders within the caldera, and samples for liquid and gas chemistry are collected several times per year from selected hot springs and fumaroles.  相似文献   
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