Cathodoluminescence,fluid inclusion and stable C–O isotope study of tectonic breccias from thrusting plane of a thin-skinned calcareous nappe     

Rastislav Milovský  Alfons van den Kerkhof  Jochen Hoefs  Vratislav Hurai  Walter Prochaska 《International Journal of Earth Sciences》2012,101(2):535-554

Basal hydraulic breccias of alpine thin-skinned Muráň nappe were investigated by means of cathodoluminescence petrography, stable isotope geochemistry and fluid inclusions analysis. Our study reveals an unusual dynamic fluid regime along basal thrust plane during final episode of the nappe emplacement over its metamorphic substratum. Basal thrusting fluids enriched in ¹⁸O, silica, alumina, alkalies and phosphates were generated in the underlying metamorphosed basement at epizonal conditions corresponding to the temperatures of 400–450°C. The fluids fluxed the tectonized nappe base, leached evaporite-bearing formations in hangingwall, whereby becoming oversaturated with sulphates and chlorides. The fluids further modified their composition by dedolomitization and isotopic exchange with the host carbonatic cataclasites. Newly formed mineral assemblage of quartz, phlogopite, albite, potassium feldspar, apatite, dravite tourmaline and anhydrite precipitated from these fluids on cooling down to 180–200°C. Finally, the cataclastic mush was cemented by calcite at ambient anchizonal conditions. Recurrent fluid injections as described above probably enhanced the final motion of the Muráň nappe.  相似文献   

Production and Certification of a Unique Set of Isotope and Delta Reference Materials for Boron Isotope Determination in Geochemical,Environmental and Industrial Materials     

Jochen Vogl  Martin Rosner 《Geostandards and Geoanalytical Research》2012,36(2):161-175

Isotopic reference materials are essential to enable reliable and comparable isotope data. In the case of boron only a very limited number of such materials is available, thus preventing adequate quality control of measurement results and validation of analytical procedures. To address this situation a unique set of two boron isotope reference materials (ERM‐AE102a and ‐AE104a) and three offset δ¹¹B reference materials (ERM‐AE120, ‐AE121 and ‐AE122) were produced and certified. The present article describes the production and certification procedure in detail. The isotopic composition of all the materials was adjusted by mixing boron parent solutions enriched in ¹⁰B or ¹¹B with a boron parent solution having a natural isotopic composition under full gravimetric control. All parent solutions were analysed for their boron concentration as well as their boron isotopic composition by thermal ionisation mass spectrometry (TIMS) using isotope dilution as the calibration technique. For all five reference materials the isotopic composition obtained on the basis of the gravimetric data agreed very well with the isotopic composition obtained from different TIMS techniques. Stability and homogeneity studies that were performed showed no significant influence on the isotopic composition or on the related uncertainties. The three reference materials ERM‐AE120, ERM‐AE121 and ERM‐AE122 are the first reference materials with natural δ¹¹B values not equal to 0‰. The certified δ¹¹B values are ?20.2‰ for ERM‐AE120, 19.9‰ for ERM‐AE121 and 39.7‰ for ERM‐AE122, each with an expanded uncertainty (k = 2) of 0.6‰. These materials were produced to cover about three‐quarters of the known natural boron isotope variation. The ¹⁰B enriched isotope reference materials ERM‐AE102a and ERM‐AE104a were produced for industrial applications utilising ¹⁰B for neutron shielding purposes. The certified ¹⁰B isotope abundances are 0.29995 for ERM‐AE102a and 0.31488 for ERM‐AE104a with expanded uncertainties (k = 2) of 0.00027 and 0.00028, respectively. Together with the formerly certified ERM‐AE101 and ERM‐AE103 a unique set of four isotope reference materials and three offset δ¹¹B reference materials for boron isotope determination are now available from European Reference Materials.  相似文献   

A multi-method approach to quantify groundwater/surface water-interactions in the semi-arid Hailiutu River basin,northwest China   总被引：1，自引：0，他引：1  

Zhi Yang  Yangxiao Zhou  Jochen Wenninger  Stefan Uhlenbrook 《Hydrogeology Journal》2014,22(3):527-541

Identification and quantification of groundwater and surface-water interactions provide important scientific insights for managing groundwater and surface-water conjunctively. This is especially relevant in semi-arid areas where groundwater is often the main source to feed river discharge and to maintain groundwater dependent ecosystems. Multiple field measurements were taken in the semi-arid Bulang sub-catchment, part of the Hailiutu River basin in northwest China, to identify and quantify groundwater and surface-water interactions. Measurements of groundwater levels and stream stages for a 1-year investigation period indicate continuous groundwater discharge to the river. Temperature measurements of stream water, streambed deposits at different depths, and groundwater confirm the upward flow of groundwater to the stream during all seasons. Results of a tracer-based hydrograph separation exercise reveal that, even during heavy rainfall events, groundwater contributes much more to the increased stream discharge than direct surface runoff. Spatially distributed groundwater seepage along the stream was estimated using mass balance equations with electrical conductivity measurements during a constant salt injection experiment. Calculated groundwater seepage rates showed surprisingly large spatial variations for a relatively homogeneous sandy aquifer.  相似文献