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21.
We report on the petrography and mineralogy of five Yamato polymict eucrites to better constrain the formation and alteration of crustal material on differentiated asteroids. Each sample consists of different lithic clasts that altogether form four dominant textures and therefore appear to originate from closely related petrological areas within Vesta′s crust. The textures range from subophitic to brecciated, porphyritic, and quench‐textured, that differ from section to section. Comparison with literature data for these samples is therefore difficult, which stresses that polymict eucrites are extremely complex in their petrography and investigation of only one thick section may not be representative for the host rock. We also show that sample Y‐793548 consists of more than one lithic unit and must therefore be classified as polymict instead of monomict. The variety and nature of lithic textures in the investigated Yamato meteorites indicate shock events, intense post‐magmatic thermal annealing, and secondary alteration. These postmagmatic features occur in different intensities, varying from clast to clast or among coexisting mineral fragments on a small, local scale. Several clasts within the eucrites studied have been modified by late‐stage alteration processes that caused deposition of Fe‐rich olivine and Fe enrichment along cracks crosscutting pyroxene crystals. However, formation of these secondary phases seems to be independent of the degree of thermal metamorphism observed within every type of clast, which would support a late‐stage metasomatism model for their formation.  相似文献   
22.
In Allende, a very complex compound chondrule (Allende compound chondrule; ACC) was found consisting of at least 16 subchondrules (14 siblings and 2 independents). Its overall texture can roughly be described as a barred olivine object (BO). The BO texture is similar in all siblings, but does not exist in the two independents, which appear as relatively compact olivine‐rich units. Because of secondary alteration of pristine Allende components and the ACC in particular, only limited predictions can be made concerning the original compositions of the colliding melt droplets. Based on textural and mineralogical characteristics, the siblings must have been formed on a very short time scale in a dense, local environment. This is also supported by oxygen isotope systematics showing similar compositions for all 16 subchondrules. Furthermore, the ACC subchondrules are isotopically distinct from typical Allende chondrules, indicating formation in or reaction with a more 16O‐poor reservoir. We modeled constraints on the particle density required at the ACC formation location, using textural, mineral‐chemical, and isotopic observations on this multicompound chondrule to define melt droplet collision conditions. In this context, we discuss the possible relationship between the formation of complex chondrules and the formation of macrochondrules and cluster chondrites. While macrochondrules may have formed under similar or related conditions as complex chondrules, cluster chondrites certainly require different formation conditions. Cluster chondrites represent a mixture of viscously deformed, seemingly young chondrules of different chemical and textural types and a population of older chondrules. Concerning the formation of ACC calculations suggest the existence of very local, kilometer‐sized, and super‐dense chondrule‐forming regions with extremely high solid‐to‐gas mass ratios of 1000 or more.  相似文献   
23.
We analyze the well-observed flare and coronal mass ejection (CME) from 1 October 2011 (SOL2011-10-01T09:18) covering the complete chain of effects – from Sun to Earth – to better understand the dynamic evolution of the CME and its embedded magnetic field. We study in detail the solar surface and atmosphere associated with the flare and CME using the Solar Dynamics Observatory (SDO) and ground-based instruments. We also track the CME signature off-limb with combined extreme ultraviolet (EUV) and white-light data from the Solar Terrestrial Relations Observatory (STEREO). By applying the graduated cylindrical shell (GCS) reconstruction method and total mass to stereoscopic STEREO-SOHO (Solar and Heliospheric Observatory) coronagraph data, we track the temporal and spatial evolution of the CME in the interplanetary space and derive its geometry and 3D mass. We combine the GCS and Lundquist model results to derive the axial flux and helicity of the magnetic cloud (MC) from in situ measurements from Wind. This is compared to nonlinear force-free (NLFF) model results, as well as to the reconnected magnetic flux derived from the flare ribbons (flare reconnection flux) and the magnetic flux encompassed by the associated dimming (dimming flux). We find that magnetic reconnection processes were already ongoing before the start of the impulsive flare phase, adding magnetic flux to the flux rope before its final eruption. The dimming flux increases by more than 25% after the end of the flare, indicating that magnetic flux is still added to the flux rope after eruption. Hence, the derived flare reconnection flux is most probably a lower limit for estimating the magnetic flux within the flux rope. We find that the magnetic helicity and axial magnetic flux are lower in the interplanetary space by ~?50% and 75%, respectively, possibly indicating an erosion process. A CME mass increase of 10% is observed over a range of \({\sim}\,4\,\mbox{--}\,20~\mathrm{R}_{\odot }\). The temporal evolution of the CME-associated core-dimming regions supports the scenario that fast outflows might supply additional mass to the rear part of the CME.  相似文献   
24.
Expansion in the world's human population and economic development will increase future demand for fish products. As global fisheries yield is constrained by ecosystems productivity and management effectiveness, per capita fish consumption can only be maintained or increased if aquaculture makes an increasing contribution to the volume and stability of global fish supplies. Here, we use predictions of changes in global and regional climate (according to IPCC emissions scenario A1B), marine ecosystem and fisheries production estimates from high resolution regional models, human population size estimates from United Nations prospects, fishmeal and oil price estimations, and projections of the technological development in aquaculture feed technology, to investigate the feasibility of sustaining current and increased per capita fish consumption rates in 2050. We conclude that meeting current and larger consumption rates is feasible, despite a growing population and the impacts of climate change on potential fisheries production, but only if fish resources are managed sustainably and the animal feeds industry reduces its reliance on wild fish. Ineffective fisheries management and rising fishmeal prices driven by greater demand could, however, compromise future aquaculture production and the availability of fish products.  相似文献   
25.
Exchange of groundwater and lake water with typically quite different chemical composition is an important driver for biogeochemical processes at the groundwater‐lake interface, which can affect the water quality of lakes. This is of particular relevance in mine lakes where anoxic and slightly acidic groundwater mixes with oxic and acidic lake water (pH < 3). To identify links between groundwater‐lake exchange rates and acid neutralization processes in the sediments, exchange rates were quantified and related to pore‐water pH, sulfate and iron concentrations as well as sulfate reduction rates within the sediment. Seepage rates measured with seepage meters (?2.5 to 5.8 L m‐2 d‐1) were in reasonable agreement with rates inverted from modeled chloride profiles (?1.8 to 8.1 L m‐2 d‐1). Large‐scale exchange patterns were defined by the (hydro)geologic setting but superimposed by smaller scale variations caused by variability in sediment texture. Sites characterized by groundwater upwelling (flow into the lake) and sites where flow alternated between upwelling and downwelling were identified. Observed chloride profiles at the alternating sites reflected the transient flow regime. Seepage direction, as well as seepage rate, were found to influence pH, sulfate and iron profiles and the associated sulfate reduction rates. Under alternating conditions proton‐consuming processes, for example, sulfate reduction, were slowed. In the uppermost layer of the sediment (max. 5 cm), sulfate reduction rates were significantly higher at upwelling (>330 nmol g‐1 d‐1) compared to alternating sites (<220 nmol g‐1 d‐1). Although differences in sulfate reduction rates could not be explained solely by different flux rates, they were clearly related to the prevailing groundwater‐lake exchange patterns and the associated pH conditions. Our findings strongly suggest that groundwater‐lake exchange has significant effects on the biogeochemical processes that are coupled to sulfate reduction such as acidity retention and precipitation of iron sulfides. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   
26.
Surface sediment samples at 89 locations and 300-cm cores from 43 sites in the Mississippi Sound were examined for evidence of pollutant impact upon this coastal environment. Chemical variables determined were total organic carbon, Kjeldahl nitrogen, phenols, and hydrocarbons. Values of these pollutant indicators were about the same or lower in Gulf of Mexico samples compared to Missippi Sound sediments and considerably lower than those from rivers and bays emptying into the sound, indicating limited impact from sites of pollutant sources into the sound. Concentrations of sedimentary pollutants peaked in the Pascagoula River where levels of total organic carbon (TOC), Kjeldahl nitrogen (TKN), phenols, and hydrocarbons exceeded sound values by one to three orders of magnitude. Analysis of cores shows pollutant intrusion to sediment strata predating industrial development. The level of pollution varies from site to site but fortunately is only serious at localized sites within the sound.  相似文献   
27.
Julia Mambo  Emma Archer 《Area》2007,39(3):380-391
The lack of reliable baseline information on land degradation is a hindrance towards its monitoring and mitigation. Of particular interest is the identification of areas susceptible to degradation. In this study, remote sensing and GIS technologies were applied to detect and map susceptibility to land degradation in Buhera district, in Save catchment, Zimbabwe. Data used included Landsat TM and ETM imagery for 1992 and 2002, agro-ecological zones, vegetation cover and population density. The study identified five preliminary categories of degradation susceptibility ranging from very high to low.  相似文献   
28.
A series of experiments and petrographic analyses have been run to determine the pre-eruption phase equilibria and ascent dynamics of dacitic lavas composing Black Butte, a dome complex on the flank of Mount Shasta, California. Major and trace element analyses indicate that the Black Butte magma shared a common parent with contemporaneously erupted magmas at the Shasta summit. The Black Butte lava phenocryst phase assemblage (20 v.%) consists of amphibole, plagioclase (core An77.5), and Fe–Ti oxides in a fine-grained (< 0.5 mm) groundmass of plagioclase, pyroxene, Fe–Ti oxides, amphibole, and cristobalite. The phenocryst assemblage and crystal compositions are reproduced experimentally between 890 °C and 910 °C, ≥ 300 MPa, XH2O = 1, and oxygen fugacity = NNO + 1. This study has quantified the extent of three crystallization processes occurring in the Black Butte dacite that can be used to discern ascent processes. Magma ascent rate was quantified using the widths of amphibole breakdown rims in natural samples, using an experimental calibration of rim development in a similar magma at relevant conditions. The majority of rims are 34 ± 10 μm thick, suggesting a time-integrated magma ascent rate of 0.004–0.006 m/s among all four dome lobes. This is comparable to values for effusive samples from the 1980 Mount St. Helens eruption and slightly faster than those estimated at Montserrat. A gap between the compositions of plagioclase phenocryst cores and microlites suggests that while phenocryst growth was continuous throughout ascent, microlite formation did not occur until significantly into ascent. The duration of crystallization is estimated using the magma reservoir depth and ascent rate, as determined from phase equilibria and amphibole rim widths, respectively. Textural analysis of the natural plagioclase crystals yields maximum growth rates of plagioclase phenocryst rims and groundmass microlites of 8.7 × 10− 8 and 2.5 × 10− 8 mm/s, respectively. These rates are comparable to values determined from time-sequenced samples of dacite erupted effusively from Mount St. Helens during 1980 and indicate that syneruptive crystallization processes were important during the Black Butte eruptive cycle.  相似文献   
29.
Previous research by our group (e.g., [Chem. Geol. 132 (1996) 25; Geochim. Cosmochim. Acta 64 (2000) 1363]) has shown that an aerobic Pseudomonas mendocina bacterium enhances Fe(hydr)oxide dissolution in order to obtain Fe under Fe-limited conditions. The P. mendocina is incapable of utilizing Fe as a terminal electron acceptor and requires several orders of magnitude lower Fe concentrations than do dissimilatory Fe reducing bacteria. The research reported here compared the effects of the P. mendocina on dissolution of well and poorly ordered Clay Minerals Society Source Clay kaolinites KGa-1b and KGa-2, respectively, under Fe-limited conditions. KGa-1b and KGa-2 contain 0.04 and 0.94 bulk wt.% Fe, respectively, and their surface Fe/Si atomic RATIOS=0.008 and 0.012. Following strong cleaning of the kaolinites in 5.8 M HCl at 85 °C, the surface Fe/Si atomic ratios decreased to 0.004 and 0.008, respectively. Both kaolinites also developed a Si-enriched surface precipitate upon strong cleaning.

Because the P. mendocina take up Fe, we could not measure Fe release from the kaolinite directly, but rather had to monitor it indirectly by comparing microbial populations sizes under Fe-limited growth conditions. We found that microbial growth on uncleaned, weakly cleaned, and strongly cleaned kaolinites increased with the amount of Fe readily available to organic ligands as estimated by dissolution in 0.001 M oxalate (pH 3). This suggests that it is the amount of readily accessible Fe that controls Fe acquisition and hence microbial growth. The trend is based on only a relatively small range of kaolinite Fe contents, and the research thus needs to be expanded to include kaolinites with a broader range of bulk and surface Fe concentrations.

Significant enhancement of Al release was observed in the presence of the bacteria, along with generally some enhancement of Si release. This enhancement of kaolinite dissolution could be related to an observed pH increase from 7–8 to 9 in the presence of the bacteria and/or to production of Al chelating agents. The P. mendocina produce a variety of organic exudates, including siderophores [Chem. Geol. 132 (1996) 25; Geomicrobiology (2001b)], and further studies into the effects of the siderophores on Al complexation and on kaolinite dissolution are ongoing.  相似文献   

30.
26 of the 59 living species of scleractinian corals found in Western Atlantic and Caribbean waters, less than 68 metres deep, and two fungiid genera from the Pacific are analysed in terms of their behaviour, sediment rejecting properties, functional morphology and distribution patterns.The contrasting behaviour and skeletal structure of the two solitary fungiids provides evidence for the construction of a theoretical mechanical model which is applied to the subsequent interpretation of the more complex colonial reef corals from the Atlantic province.Regional distribution patterns, growth forms and calical orientations of the Atlantic species and their associated sediment types were noted in dives across transects in extreme environments in the Caribbean. Representative samples were then selected from the five functional ecological niches in the Florida keys, and subjected to inundations of sized and painted carbonate sand particles in the laboratory. The coral was filmed before the sedimentary influx, on impact and during rejection. The skeletons were then extracted and dissected to construct a mechanical model compatible with their behavioural functions.There are four means of sediment rejection: distension by the stomodeal up-take of water, tentacular action, ciliary beat, and mucus entanglement. Differences in sediment rejection are ascribed to two factors (1) variations in the polyps' distensional capacity, and (2) the geometry of the calice.A theoretical model of characteristic scleractinian distribution patterns on an Atlantic patch reef mirrors regional distribution patterns. The sediment rejecting experiments are used as additional evidence for interpreting other behavioural activities of greater consequence e.g. food gathering and the removal of excrement.Theoretical models are described for the relationship of calical form to polypal function and calcical orientation to distribution patterns on the corallum; and also variations in growth form. Ecological distributions, in local patch reef and regional occurrences, are outlined in terms of the recent scleractinian corals of the Atlantic province. These models are tested against some rugose and tabulate coral distributions in the Irish Carboniferous.
Zusammenfassung 26 der 59 Korallenarten (Scleractinia), die im westlichen Atlantik und der Karibischen See in weniger als 68 m Wassertiefe leben, und 2 Fungia-Gattungen des Pazifiks werden auf Verhalten, Fähigkeit Sediment abzuschütteln und funktioneller Morphologie untersucht. Aufgrund der Gegensätze in Verhalten und Skelettstruktur der beiden Fungia-Einzelkorallen wird ein theoretisches Modell erarbeitet, das dann auf die komplizierteren koloniebildenden Korallen angewandt wird.Regionale Verteilung, Wuchsformen und Kelchorientierung der atlantischen Korallen und die dazugehörigen Sedimente wurden in Tauchgängen in extremen Bereichen der Karibischen See erfaßt. Repräsentative Korallen-Exemplare wurden dann von fünf ökologisch definierten Bereichen der Florida Keys gesammelt und im Labor mit sortierten und gefärbten Karbonatsandkörnern überschüttet. Die Korallen wurden vor dem Experiment, während des Schüttens und des Abschüttelns gefilmt. Danach wurden die Skelette herauspräpariert und ein mechanisches Modell entwickelt, das die verhaltensbedingten Funktionen berücksichtigt.Das Sediment wird mit Hilfe von vier Mechanismen abgeschütteln: Ausdehnung der Weichteile durch Aufnahme von Wasser, Tentakelbewegungen, Ziliarbewegungen und Schleimumwicklung. Unterschiede in der Fähigkeit, Sediment abzuschütteln, wurden auf 1. Unterschiede in der Fähigkeit des Polypen, sich auszudehnen, und 2. Unterschiede in der Kelchform zurückgeführt.Ein theoretisches Modell der Korallenverteilung auf einem isolierten Riff spiegelt die Grundzüge regionaler Verteilung wider. Die Sedimentabschüttel-Experimente ergeben zusätzliche Anhaltspunkte für die Interpretation anderer Verrichtungen von größerer Bedeutung, z. B. Nahrungsaufnahme und Entfernung von Exkrementen. Theoretische Modelle für das Verhältnis von Kelchform zu Polypenfunktion und von Kelchorientierung zur Position auf dem Korallenstock und zu Wuchformunterschieden werden beschrieben.Ökologische Verteilungen, lokal und regional, werden anhand der rezenten Korallen des Atlantiks aufgezeigt. Diese Modelle werden dann am Beispiel der Verteilung rugosen und tabulaten Korallen im Karbon Irlands getestet.

Résumé 26 espèces vivantes de coraux scléractiniens sur 59, furent découvertes dans l'Atlantique-Ouest et les eaux des Caraïbes, à moins de 68 m de fond; 2 genera fungiid du Pacifique sont analysés en fonction de leur comportement, des propriétés de rejet des sédiments dont ils font preuve, de leur morphologie fonctionelle et de leurs reséaux de distribution.Le contraste dans le compartement et dans la structure squelettique des deux fungiids solitaires, justifie la construction d'un modèle théorique mécanique qui est appliqué à l'interprétation suivante des coraux de récif coloniaux et plus complexes que l'on trouve dans la région atlantique.Les réseaux de distribution régionale, les formes de croissances d'orientations calicales de l'espèce atlantique et les types de sédiments qui leur sont associés, ont été remarqués lors de plongées aux environs extrêmes de la mer Caraïbe. Des échantillons représentatifs ont ensuite été sélectionnés dans les cinq niches écologiques fonctionelles des cayes de Floride. Puis ont été soumis, en laboratoire à des inondations de particules de sable carbonaté taillées et teintes. Le corail a été filmé avant l'entrée des sédiments, pendant l'opération et pendant le rejet. Les squelettes, ont ensuite été extraits et disséqués pour construire un modèle mécanique compatible avec leurs fonctions de compartement.Il existe quatre modes de rejet des sédiments: dilatation par absorbsion stomodéal d'eau, action tentaculaire, action ciliaire et enveloppement de mucus.Les différences dans le rejet de sédiments sont imputables a deux facteurs (1) les variations de la capacité dimensionelle du polype et (2) la géométrie du calice. Un modèle théorique des réseaux le distribution scléractiniènne, charactéristique sur un petit récif atlantique, réflecte des sébeaux de distribution régionale. Les expériences sur le rejet de sédiments, sont utilisées comme preuve supplémentaire à l'interprétation d'autres activités de comportement, comme par exemple, la recherche de nourriture ou l'émission d'éxcréments.Les modèles théoriques sont décrits pour permettre le rapport entre la forme calicale et la fonction polypale, plus entre l'orientation calicale et les résaux de distribution sur le corallum, ainsi que pour étudier les variations dans les formes de croissance. L'étude des coraux scléractiniens récents de la province atlantique, permet d'établir une ébauche de leur répartition écologique, aussi bien sur les petits récifs locaux qu'au niveau des incidences régionales. Les modèles sont également testés grace à des répartitions de coraux rugueux et tabulates dans le Carbonifière Irlandais.

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