Surface Density Values for the Earth from Satellite and Gravity Observations     

Karl-Rudolf Koch 《Geophysical Journal International》1970,21(1):1-12

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Influence of particle and surface quality on the vitrinite reflectance of dispersed organic matter: Comparative exercise using data from the qualifying system for reflectance analysis working group of ICCP     

A.G. Borrego  C.V. Araujo  A. Balke  B. Cardott  A.C. Cook  P. David  D. Flores  M. Hmor-Vid  W. Hiltmann  W. Kalkreuth  J. Koch  C.J. Kommeren  J. Kus  B. Ligouis  M. Marques  J.G. Mendona Filho  M. Misz  L. Oliveira  W. Pickel  K. Reimer  P. Ranasinghe  I. Surez-Ruiz  A. Vieth 《International Journal of Coal Geology》2006,68(3-4):151-170

The development of a qualifying system for reflectance analysis has been the scope of a working group within the International Committee for Coal and Organic Petrology (ICCP) since 1999, when J. Koch presented a system to qualify vitrinite particles according to their size, proximity to bright components and homogeneity of the surface. After some years of work aimed at improving the classification system using photomicrographs, it was decided to run a round robin exercise on microscopy samples. The classification system tested consists of three qualifiers ranging from excellent to low quality vitrinites with an additional option for unsuitable vitrinites. This paper reports on the results obtained by 22 analysts who were asked to measure random reflectance readings on vitrinite particles assigning to each reading a qualifier. Four samples containing different organic matter types and a variety of vitrinite occurrences have been analysed. Results indicated that the reflectance of particles classified as excellent, good or poor compared to the total average reflectance did not show trends to be systematically lower or higher for the four samples analysed. The differences in reflectance between the qualifiers for any given sample were lower than the scatter of vitrinite reflectance among participants. Overall, satisfactory results were obtained in determining the reflectance of vitrinite in the four samples analysed. This was so for samples having abundant and easy to identify vitrinites (higher plant-derived organic matter) as well as for samples with scarce and difficult to identify particles (samples with dominant marine-derived organic matter). The highest discrepancies were found for the organic-rich oil shales where the selection of the vitrinite population to measure proved to be particularly difficult. Special instructions should be provided for the analysis of this sort of samples. The certainty of identification of the vitrinite associated with the vitrinite reflectance values reported has been assessed through a reliability index which takes into account the number of readings and the coefficient of variation. The same statistical approach as that followed in the ICCP vitrinite reflectance accreditation program for single seam coals has been used for data evaluation. The results indicated low to medium dispersion for 17 out of 22 participants. This, combined with data from other sets of comparative analyses over a long period, is considered an encouraging result for the establishment of an accreditation program on vitrinite reflectance measurements in dispersed organic matter.  相似文献   

Rapid runoff via shallow throughflow and deeper preferential flow in a boreal catchment underlain by frozen silt (Alaska, USA)     

J. C. Koch  S. A. Ewing  R. Striegl  D. M. McKnight 《Hydrogeology Journal》2013,21(1):93-106

In high-latitude catchments where permafrost is present, runoff dynamics are complicated by seasonal active-layer thaw, which may cause a change in the dominant flowpaths as water increasingly contacts mineral soils of low hydraulic conductivity. A 2-year study, conducted in an upland catchment in Alaska (USA) underlain by frozen, well-sorted eolian silt, examined changes in infiltration and runoff with thaw. It was hypothesized that rapid runoff would be maintained by flow through shallow soils during the early summer and deeper preferential flow later in the summer. Seasonal changes in soil moisture, infiltration, and runoff magnitude, location, and chemistry suggest that transport is rapid, even when soils are thawed to their maximum extent. Between June and September, a shift occurred in the location of runoff, consistent with subsurface preferential flow in steep and wet areas. Uranium isotopes suggest that late summer runoff erodes permafrost, indicating that substantial rapid flow may occur along the frozen boundary. Together, throughflow and deep preferential flow may limit upland boreal catchment water and solute storage, and subsequently biogeochemical cycling on seasonal to annual timescales. Deep preferential flow may be important for stream incision, network drainage development, and the release of ancient carbon to ecosystems.  相似文献   

Influence of Shoreline Stabilization Structures on the Nearshore Sedimentary Environment in Mesohaline Chesapeake Bay     

Cindy M. Palinkas  Lawrence P. Sanford  Evamaria W. Koch 《Estuaries and Coasts》2018,41(4):952-965

Shorelines around many estuaries and coastal embayments are rapidly eroding (approximately several meters/year), with more rapid erosion rates expected in the future due to natural and anthropogenic stressors. In response, a variety of techniques have been used to stabilize shorelines, but there are limited quantitative, long-term data available about their effects on the sedimentary environment immediately adjacent to them (i.e., the nearshore). This study evaluated changes in sediment characteristics (mud and organic content) and accumulation rates associated with installation of breakwaters, riprap, and living shorelines with (“hybrid”) and without (“soft”) a structural component. ²¹⁰Pb (half-life 22.3 years) geochronologies were used to identify horizons in core profiles that corresponded to years when structures were built. Sites with naturally eroding shorelines (i.e., no structures) were used as a control group at which any sedimentary changes represent broad environmental trends, in contrast to changes at the protected sites that also include the influence of structures. Observations were placed within the context of modeled wave climate, shoreline-erosion rates, land use, dominant sediment source, and the apparent effect on submersed aquatic vegetation (SAV) inhabiting the nearshore sedimentary environment. The main conclusion of this study is that there was no “one size fits all” answer to anticipated impacts of structures on nearshore sedimentary environments. Instead, specific changes associated with structures depended on individual site characteristics, but could be predicted with multiple linear regression models that included structure type, shoreline-erosion rate, dominant sediment source, and land use. Riprap or breakwater installation had either positive or no obvious impact on SAV at six of seven sites but negatively impacted SAV at one riprapped site. No obvious impacts on SAV were observed at living shoreline sites.  相似文献   

Hydrological Conditions Control P Loading and Aquatic Metabolism in an Oligotrophic, Subtropical Estuary     

Gregory R. Koch  Daniel L. Childers  Peter A. Staehr  René M. Price  Stephen E. Davis  Evelyn E. Gaiser 《Estuaries and Coasts》2012,35(1):292-307

Using high-resolution measures of aquatic ecosystem metabolism and water quality, we investigated the importance of hydrological inputs of phosphorus (P) on ecosystem dynamics in the oligotrophic, P-limited coastal Everglades. Due to low nutrient status and relatively large inputs of terrestrial organic matter, we hypothesized that the ponds in this region would be strongly net heterotrophic and that pond gross primary production (GPP) and respiration (R) would be the greatest during the “dry,” euhaline estuarine season that coincides with increased P availability. Results indicated that metabolism rates were consistently associated with elevated upstream total phosphorus and salinity concentrations. Pulses in aquatic metabolism rates were coupled to the timing of P supply from groundwater upwelling as well as a potential suite of hydrobiogeochemical interactions. We provide evidence that freshwater discharge has observable impacts on aquatic ecosystem function in the oligotrophic estuaries of the Florida Everglades by controlling the availability of P to the ecosystem. Future water management decisions in South Florida must include the impact of changes in water delivery on downstream estuaries.  相似文献   

Gas migration through Opouawe Bank at the Hikurangi margin offshore New Zealand     

Stephanie Koch  Henning Schroeder  Matthias Haeckel  Christian Berndt  Joerg Bialas  Cord Papenberg  Dirk Klaeschen  Andreia Plaza-Faverola 《Geo-Marine Letters》2016,36(3):187-196

This study presents 2D seismic reflection data, seismic velocity analysis, as well as geochemical and isotopic porewater compositions from Opouawe Bank on New Zealand’s Hikurangi subduction margin, providing evidence for essentially pure methane gas seepage. The combination of geochemical information and seismic reflection images is an effective way to investigate the nature of gas migration beneath the seafloor, and to distinguish between water advection and gas ascent. The maximum source depth of the methane that migrates to the seep sites on Opouawe Bank is 1,500–2,100 m below seafloor, generated by low-temperature degradation of organic matter via microbial CO₂ reduction. Seismic velocity analysis enabled identifying a zone of gas accumulation underneath the base of gas hydrate stability (BGHS) below the bank. Besides structurally controlled gas migration along conduits, gas migration also takes place along dipping strata across the BGHS. Gas migration on Opouawe Bank is influenced by anticlinal focusing and by several focusing levels within the gas hydrate stability zone.  相似文献   

Velocity and abundance precisions for future high‐resolution spectroscopic surveys: A study for 4MOST     

E. Caffau  A. Koch  L. Sbordone  P. Sartoretti  C.J. Hansen  F. Royer  N. Leclerc  P. Bonifacio  N. Christlieb  H.‐G. Ludwig  E.K. Grebel  R.S. de Jong  C. Chiappini  J. Walcher  S. Mignot  S. Feltzing  M. Cohen  I. Minchev  A. Helmi  T. Piffl  E. Depagne  O. Schnurr 《Astronomische Nachrichten》2013,334(3):197-216

In preparation for future, large‐scale, multi‐object, high‐resolution spectroscopic surveys of the Galaxy, we present a series of tests of the precision in radial velocity and chemical abundances that any such project can achieve at a 4 m class telescope. We briefly discuss a number of science cases that aim at studying the chemo‐dynamical history of the major Galactic components (bulge, thin and thick disks, and halo) – either as a follow‐up to the Gaia mission or on their own merits. Based on a large grid of synthetic spectra that cover the full range in stellar parameters of typical survey targets, we devise an optimal wavelength range and argue for a moderately high‐resolution spectrograph. As a result, the kinematic precision is not limited by any of these factors, but will practically only suffer from systematic effects, easily reaching uncertainties <1km s^–1. Under realistic survey conditions (namely, considering stars brighter than r = 16 mag with reasonable exposure times) we prefer an ideal resolving power of R ∼20 000 on average, for an overall wavelength range (with a common two‐arm spectrograph design) of [395;456.5] nm and [587;673] nm. We show for the first time on a general basis that it is possible to measure chemical abundance ratios to better than 0.1 dex for many species (Fe, Mg, Si, Ca, Ti, Na, Al, V, Cr, Mn, Co, Ni, Y, Ba, Nd, Eu) and to an accuracy of about 0.2 dex for other species such as Zr, La, and Sr. While our feasibility study was explicitly carried out for the 4MOST facility, the results can be readily applied to and used for any other conceptual design study for high‐resolution spectrographs. (© 2013 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)  相似文献   

The Role of Zooplankton Grazing and Nutrient Loading in the Occurrence of Harmful Cyanobacterial Blooms in Florida Bay,USA     

Jennifer A. Goleski  Florian Koch  Maria A. Marcoval  Charles C. Wall  Frank J. Jochem  Bradley J. Peterson  Christopher J. Gobler 《Estuaries and Coasts》2010,33(5):1202-1215

Florida Bay is Florida’s (USA) largest estuary and has experienced harmful picocyanobacteria blooms for nearly two decades. While nutrient loading is the most commonly cited cause of algal blooms in Florida Bay, the role of zooplankton grazing pressure in bloom occurrence has not been considered. For this study, the spatial and temporal dynamics of cyanobacteria blooms, the microbial food web, microzooplankton and mesozooplankton grazing rates of picoplankton, and the effects of nutrients on plankton groups in Florida Bay were quantified. During the study, cyanobacteria blooms (>3 × 10⁵ cells mL⁻¹) persisted in the eastern and central regions of Florida Bay for more than a year. Locations with elevated abundance of cyanobacteria hosted microzooplankton grazing rates on cyanobacteria that were significantly lower (p < 0.001) and less frequently detectable compared to sites without blooms. Consistent with this observation, cyanobacteria abundances were significantly correlated with ciliates and heterotrophic nanoflagellates at low cyanobacteria densities (p < 0.001) but were not correlated during bloom events. The experimental enrichment of mesozooplankton abundance during blooms yielded a significant decrease in the net growth rate of picoplankton but had the opposite effect when blooms were absent, suggesting that the cascading effect of mesozooplankton grazing on the microbial food web was also altered during blooms. While inorganic nutrient enrichment significantly increased the net growth rates of eukaryotic phytoplankton and heterotrophic bacteria, such nutrient loading had no effect on the net growth rates of cyanobacteria. Hence, this study demonstrates that low rates of zooplankton grazing and low rates of inorganic nutrient loading contribute to the persistence of cyanobacteria blooms in Florida Bay.  相似文献