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101.
102.
The ages of subcontinental lithospheric mantle beneath the North China and South China cratons are less well-constrained than the overlying crust. We report Re–Os isotope systematics of mantle xenoliths entrained in Paleozoic kimberlites and Mesozoic basalts from eastern China. Peridotite xenoliths from the Fuxian and Mengyin Paleozoic diamondiferous kimberlites in the North China Craton give Archean Re depletion ages of 2.6–3.2 Ga and melt depletion ages of 2.9–3.4 Ga. No obvious differences in Re and Os abundances, Os isotopic ratios and model ages are observed between spinel-facies and garnet-facies peridotites from both kimberlite localities. The Re–Os isotopic data, together with the PGE concentrations, demonstrate that beneath the Archean continental crust of the eastern North China Craton, Archean lithospheric mantle of spinel- to diamond-facies existed without apparent compositional stratification during the Paleozoic. The Mesozoic and Cenozoic basalt-borne peridotite and pyroxenite xenoliths, on the other hand, show geochemical features indicating metasomatic enrichment, along with a large range of the Re–Os isotopic model ages from Proterozoic to Phanerozoic. These features indicate that lithospheric transformation or refertilization through melt-peridotite interaction could be the primary mechanism for compositional changes during the Phanerozoic, rather than delamination or thermal-mechanical erosion, despite the potential of these latter processes to play an important role for the loss of garnet-facies mantle. A fresh garnet lherzolite xenolith from the Yangtze Block has a Re depletion age of ∼1.04 Ga, much younger than overlying Archean crustal rocks but the same Re depletion ages as spinel lherzolite xenoliths from adjacent Mesozoic basalts, indicating Neoproterozoic resetting of the Re–Os system in the South China Craton.  相似文献   
103.
104.
One of the reasons the processes resulting in As release to groundwater in southern Asia remain poorly understood is the high degree of spatial variability of physical and chemical properties in shallow aquifers. In an attempt to overcome this difficulty, a simple device that collects groundwater and sediment as a slurry from precisely the same interval was developed in Bangladesh. Recently published results from Bangladesh and India relying on the needle-sampler are augmented here with new data from 37 intervals of grey aquifer material of likely Holocene age in Vietnam and Nepal. A total of 145 samples of filtered groundwater ranging in depth from 3 to 36 m that were analyzed for As (1–1000 μg/L), Fe (0.01–40 mg/L), Mn (0.2–4 mg/L) and S (0.04–14 mg/L) are compared. The P-extractable (0.01–36 mg/kg) and HCl-extractable As (0.04–36 mg/kg) content of the particulate phase was determined in the same suite of samples, in addition to Fe(II)/Fe ratios (0.2–1.0) in the acid-leachable fraction of the particulate phase. Needle-sampler data from Bangladesh indicated a relationship between dissolved As in groundwater and P-extractable As in the particulate phase that was interpreted as an indication of adsorptive equilibrium, under sufficiently reducing conditions, across 3 orders of magnitude in concentrations according to a distribution coefficient of 4 mL/g. The more recent observations from India, Vietnam and Nepal show groundwater As concentrations that are often an order of magnitude lower at a given level of P-extractable As compared to Bangladesh, even if only the subset of particularly reducing intervals characterized by leachable Fe(II)/Fe >0.5 and dissolved Fe >0.2 mg/L are considered. Without attempting to explain why As appears to be particularly mobile in reducing aquifers of Bangladesh compared to the other regions, the consequences of increasing the distribution coefficient for As between the particulate and dissolved phase to 40 mL/g for the flushing of shallow aquifers of their initial As content are explored.  相似文献   
105.
106.
Microbial Fe reduction is widely believed to be the primary mechanism of As release from aquifer sands in Bangladesh, but alternative explanations have been proposed. Long-term incubation studies using natural aquifer material are one way to address such divergent views. This study addresses two issues related to this approach: (1) the need for suitable abiotic controls and (2) the spatial variability of the composition of aquifer sands. Four sterilization techniques were examined using orange-colored Pleistocene sediment from Bangladesh and artificial groundwater over 8 months. Acetate (10 mM) was added to sacrificial vials before sterilization using either (1) 25 kGy of gamma irradiation, (2) three 1-h autoclave cycles, (3) a single addition of an antibiotic mixture at 1× or (4) 10× the typical dose, and (5) a 10 mM addition of azide. The effectiveness of sterilization was evaluated using two indicators of microbial Fe reduction, changes in diffuse spectral reflectance and leachable Fe(II)/Fe ratios, as well as changes in P-extractable As concentrations in the solid phase. A low dose of antibiotics was ineffective after 70 days, whereas autoclaving significantly altered groundwater composition. Gamma irradiation, a high dose of antibiotics, and azide were effective for the duration of the experiment.  相似文献   
107.
108.
个旧矿区遥感异常信息解译及找矿远景分析   总被引:3,自引:0,他引:3  
文章以TM多光谱遥感数据为基本信息源,从实际地质情况出发,采用计算机识别和人工判读相结合,对区内的线形、环形构造进行了解译.应用比值 主成分分析的方法对区内热液弱蚀变信息进行了提取.在此基础上,综合利用已知矿床的分布以及遥感构造信息、遥感蚀变晕信息,结合已有的物化探资料,分析出4个找矿远景区.  相似文献   
109.
万全寺银金矿床位于张宣幔枝构造东侧的侏罗纪断陷盆地中,成矿时限晚于133.33Ma~101.82 Ma.通过硫、铅、氢、氧、碳及稀有气体同位素研究认为,成矿物质应源自地球深部,在中生代冀西北幔枝构造演化过程中集中成矿.成矿热液以岩浆水为主并加入了部分天水.  相似文献   
110.
双壳类壳体碳酸盐(文石)稳定同位素组成已被广泛地用于古气候和古环境重建研究中,但是双壳类壳体碳同位素组成所指示的气候和环境意义一直是争议的问题.对双壳类河蚬(corbicula fluminea)进行了室内养殖,并选取两个壳体样品(壳高,A=13 mm,B=9mm),测定其生长部分壳体和生长期间水体碳同位素,研究表明,随着水体碳同位素的升高(δ13CDIC由-5.24‰升至1.41‰),两壳体碳同位素也随之升高,表明水体对壳体碳同位素的影响;δ13CA分布范围为-4.76‰~2.09‰,δ13CB为-8.49‰~2.89,壳体A和B碳同位素均比预测平衡值偏负,表明壳体在形成过程中利用了新陈代谢产生的富集12C的CO2.根据计算壳体A在实验中沉淀部分壳体利用新陈代谢碳的比例(M值)为24%~43%,平均值为33%;壳体B为33%~75%,平均值为58%.M值随生物的生长呈下降变化,这说明在实验中河蚬主要是通过增加对DIC的吸收和利用来满足壳体生长对物质量增加的需求.  相似文献   
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