外贝加尔大骨节病地区水文地球化学特征分析(英文)          下载免费PDF全文

Leonid V. Zamana 《中国地质》2010,37(3):582-586

本文通过对在外贝加尔大骨节病区水文地球化学研究结果表明,该地区天然水呈现出高浓度的磷(高达3.5mg/L),同时,锰、硅、铅等元素也呈现出高浓度的地球化学特征。分析水文地球化学数据,认为大骨节病可能与生物地球化学性质的多种因素有关系。进一步研究大骨节病的成因机制需要新的可靠的环境地球化学数据。  相似文献   

Mineral equilibria in mantle-derived rocks     

Leonid Perchuk  Tibor Gasparik   《Lithos》2002,60(3-4):vii

  相似文献   

Numerical modeling of EM fields over local anomalies with a vertical axis of symmetry     

Michael S. Zhdanov  Vjacheslav V. Spichak  Leonid Yu. Zaslavsky 《Physics of the Earth and Planetary Interiors》1990,60(1-4):53-61

A method for numerical modeling of quasi-stationary electromagnetic fields in axially symmetric media is proposed. It is based on the direct finite-element method and the use of special basis functions. Assuming cylindrical coordinates r, φ, z, the three-dimensional solution is presented as a superposition of fields with the azimuthal dependence exp(inφ). For each case this results in a system of two equations of elliptical type in two scalar functions in the (r, z) plane.

The discretization leads to the conservative nine-points difference scheme. The system of linear equations is solved by means of the LU-decomposition technique, the band structure of the matrix being taken into account.

The program is tested using analytical results (DC asymptote) for a near-surface inhomogeneity. Comparison also is made with 2D results (H-polarization) for the model of a local well conducting inclusion in a three-layered Earth.  相似文献   

A Set of Far East Magmatic Rock Reference Samples: DV     

Leonid A. BERKOVITS  Alexander K. PARSHIN 《Geostandards and Geoanalytical Research》1991,15(1):67-76

  相似文献   

High-pressure and high-temperature in situ X-ray diffraction study of iron and corundum to 68 GPa using an internally heated diamond anvil cell   总被引：1，自引：1，他引：0  

Leonid S. Dubrovinsky  Surendra K. Saxena  Peter Lazor 《Physics and Chemistry of Minerals》1998,25(6):434-441

Using powder X-ray diffraction of heated solids to pressures reaching 68 GPa, the pressure-volume-temperature (PVT) data on corundum Al₂O₃ and ɛ-Fe were determined with the following results: *Corundum,*Iron, *Al₂O₃*ɛ-Fe Isothermal bulk*258 (2)*164 (3)  modulus K'_{300, 1} (GPa) Pressure derivative K_{300, 1}*4.88 (4)*5.36 (16) Temperature derivative*–0.020 (2)*–0.043 (3)  (∂K _T,1 /∂T) _P (GPa/K) Molar volume V_300,1*25.59 (2)*6.76 (2)  (cm³/mol) Isobaric thermal expansion at 1 atm (0.101 MPa) is given by (K^–1): α _T =2.6 (2) 10^–5+1.81 (9) 10^–9 T–0.67 (6)/T ² for corundum, and α _T =5.7 (4) 10^–5+4.2 (4) 10^–9 T–0.17 (7)/T ² for iron ɛ-Fe. Received: 1 March 1997 / Revised, accepted: 21 August 1997  相似文献   

Complexation of Gold(III)-Chloride at the Surface of Hematite     

Olga N. Karasyova  Lyudmila I. Ivanova  Leonid Z. Lakshtanov  Lars Lövgren  Staffan Sjöberg 《Aquatic Geochemistry》1998,4(2):215-231

The acid/base properties of the hematite/water interface and surfacecomplexation with gold has been studied by potentiometric titrations in thefour component system H⁺ – FeOH –AuCl ₄ ^- – Cl^-. Equilibrium measurementswere performed in NaCl media at 298.2 K. In the evaluation of equilibriummodel from experimental data the constant capacitance model was applied. Theacid/base properties were investigated in 0.1 M NaCl in the range 2.6 pH 7.4. The resulting intrinsic constants for protonation anddeprotonation of hydroxyl groups at the surface were log _1,1,0,0(int) ^s = 7.10 ± 0.06 andlog _{-1,1,0,0(int)} ^s = - 7.80 ±0.06. The density of proton active surface sites was 2.85nm^-2 and the specific capacitance 2.5 C V^-1 m^-2. In the investigation of surface complexation of gold, thepotentiometric titrations were performed in the range 2.0 pH 10.2.Titration data was supplemented with analysis of Au in the aqueous phase byatomic absorbance spectrometry. The equilibrium model proposed consists ofthe following monodentate surface complexes: FeOHAuCl₃(log _0,1,1,-1 ^s = 1.45 ± 0.03),FeOHAuCl₂OH (log _-1,1,1,-2 ^s = -3.89 ± 0.02), FeOHAu(OH)₃ (log _-3,1,1,-4 ^s = -21.94 ± 0.05). Aslightly better fit could be obtained by assuming formation of a bidentatecomplex with the composition(FeO)₂Au(OH)H₂O. However, based onstructural arguments this complex was rejected.  相似文献   

A new natural,super-hard,transparent polymorph of carbon from the Popigai impact crater,Russia   总被引：1，自引：0，他引：1  

Ahmed El Goresy  Leonid S Dubrovinsky  Philippe Gillet  Smail Mostefaoui  Günther Graup  Michael Drakopoulos  Alexandre S Simionovici  Varghese Swamy  Victor L Masaitis 《Comptes Rendus Geoscience》2003,335(12):889-898

A natural shockwave event led to the formation of a new crystalline polymorph of carbon in gneisses from the Popigai crater, Russia. The new species occupies the interior of a multiphase assemblage and is entirely enveloped by lonsdaleite and graphite. Polishing hardness of this new phase is greater than that of lonsdaleite. Micro-beam synchrotron X-ray diffraction, imaging and fluorescence studies revealed a pure transparent carbon phase. The diffraction pattern is indexed in terms of a cubic cell (a=14.697 Å, space group Pm3m.). This species was neither encountered in static or dynamic high-pressure experiment nor predicted by theoretical calculations. To cite this article: A. El Goresy et al., C. R. Geoscience 335 (2003).  相似文献   

Sounding Rocket Observations of Active Region Soft X-Ray Spectra Between 0.5 and 2.5 nm Using a Modified SDO/EVE Instrument     

Seth Wieman  Leonid Didkovsky  Thomas Woods  Andrew Jones  Christopher Moore 《Solar physics》2016,291(12):3567-3582

Spectrally resolved measurements of individual solar active regions (ARs) in the soft X-ray (SXR) range are important for studying dynamic processes in the solar corona and their associated effects on the Earth’s upper atmosphere. They are also a means of evaluating atomic data and elemental abundances used in physics-based solar spectral models. However, very few such measurements are available. We present spectral measurements of two individual ARs in the 0.5 to 2.5 nm range obtained on the NASA 36.290 sounding rocket flight of 21 October 2013 (at about 18:30 UT) using the Solar Aspect Monitor (SAM), a channel of the Extreme Ultaviolet Variability Experiment (EVE) payload designed for underflight calibrations of the orbital EVE on the Solar Dynamics Observatory (SDO). The EVE rocket instrument is a duplicate of the EVE on SDO, except the SAM channel on the rocket version was modified in 2012 to include a freestanding transmission grating to provide spectrally resolved images of the solar disk with the best signal to noise ratio for the brightest features, such as ARs. Calibrations of the EVE sounding rocket instrument at the National Institute of Standards and Technology Synchrotron Ultraviolet Radiation Facility (NIST/SURF) have provided a measurement of the SAM absolute spectral response function and a mapping of wavelength separation in the grating diffraction pattern. We discuss techniques (incorporating the NIST/SURF data) for determining SXR spectra from the dispersed AR images as well as the resulting spectra for NOAA ARs 11877 and 11875 observed on the 2013 rocket flight. In comparisons with physics-based spectral models using the CHIANTI v8 atomic database we find that both AR spectra are in good agreement with isothermal spectra (4 MK), as well as spectra based on an AR differential emission measure (DEM) included with the CHIANTI distribution, with the exception of the relative intensities of strong Fe?xvii lines associated with \(2p^{6}\)–\(2p^{5}3{s}\) and \(2p^{6}\)–\(2p^{5}3{d}\) transitions at about 1.7 nm and 1.5 nm, respectively. The ratio of the Fe?xvii lines suggests that the AR 11877 is hotter than the AR 11875. This result is confirmed with analysis of the active regions imaged by X-ray Telescope (XRT) onboard Hinode.  相似文献   

滇东北麻栗坪铅锌矿床微量元素分布与赋存状态:LA-ICPMS研究   总被引：4，自引：2，他引：2  

胡宇思  叶霖  黄智龙  李珍立  韦晨  Danyushevskiy Leonid 《岩石学报》2019,35(11):3477-3492

位于扬子板块西南缘的"川滇黔接壤铅锌矿集区"是我国西南大面积低温成矿域的重要组成部分,麻栗坪铅锌矿床位于该矿集区昭通-曲靖成矿带中段,是近年来滇东北地区新发现的铅锌矿床。本文以麻栗坪铅锌矿不同硫化物为研究对象,通过LA-ICPMS原位点测试和元素Mapping分析,尝试揭示该矿床中Ge、Cd和In等微量元素在不同硫化物中分布规律与赋存状态。本次研究发现,麻栗坪矿床不同硫化物中富集的微量元素明显不同,闪锌矿主要富集Mn、Cu、Sn、Cd、In和Ge,而方铅矿主要富集Ag、Sb和Se,黄铁矿则富集As、Co和Ni。闪锌矿是分散元素Ge、In和Cd的主要载体矿物,且Cd、Ge、In、Mn、As、Sb和Ag以类质同象形式赋存于闪锌矿中;而Cu则主要以类质同象形式存在,部分Cu以黄铜矿的显微包裹体形式赋存于闪锌矿中,其中以类质同象赋存于闪锌矿中Cu和Ge呈现明显的相关性,可能暗示其与Zn的置换方式为:3Zn2+Ge4++2Cu+。总体上,该矿床闪锌矿以富集Cd、Ge,贫Fe、Mn、Co、Sn为特征,这些微量元素组成与典型MVT型矿床基本一致,明显有别于喷流沉积和岩浆热液型矿床,而与中低温条件下形成的闪锌矿微量元素组成相似。结合该矿床后生成矿特征明显等地质地球化学研究成果,我们认为该矿床应属于MVT型铅锌矿床。值得注意的是,该矿床闪锌矿相对富集In,可能暗示其形成具有特殊性,这可能与其成矿流体在长距离运移过程中所流经地层有关,该类流体活化萃取了基底地层的中-酸性岩浆岩或火山碎屑岩中的In,致使矿床中闪锌矿相对富集In。  相似文献   

Simultaneous volume measurements of post-perovskite and perovskite in MgSiO3 and their thermal equations of state     

Tetsuya Komabayashi  Kei Hirose  Emiko Sugimura  Nagayoshi Sata  Yasuo Ohishi  Leonid S. Dubrovinsky 《Earth and Planetary Science Letters》2008,265(3-4):515-524

Simultaneous volume measurements of MgSiO₃ post-perovskite (PPv) and perovskite (Pv) were performed in a diamond anvil cell (DAC) combined with synchrotron X-rays. An externally-heated DAC was used in addition to a laser-heated DAC for the volume measurement experiment at high temperatures. The volume data were collected in the stability field of post-perovskite from 115 to 130 GPa. The temperature generated in the externally-heated and the laser-heated DACs for the volume measurement were up to 832 and 2330 K, respectively. Using two different but complementary heating techniques, we collected the data at a wide temperature range from 300 to 2330 K. The obtained P-V-T data for PPv and Pv were fitted to a third-ordered Birch-Murnaghan equation of state (EOS). For a precise comparison of the volume between the two phases, the EOSs were constructed based on the same pressure scale of MgO. The simultaneous volume measurements and the volumes calculated from the determined EOSs demonstrate that the volume difference between PPv and Pv of about 1.5% is almost constant with increasing temperature to 4000 K at the transition. At the base of the mantle, this density difference corresponds to a temperature anomaly of 1300 K without the phase transition due to the very small thermal expansivity of minerals, which has a significant effect on mantle dynamics. The thermal expansivity contrast between the top and the bottom of the mantle is a factor of 3.6. From a mantle convection study, this value suggests that huge and hot plumes are formed at the core–mantle boundary.  相似文献