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91.
The Breccia Museo is one of the most debated volcanic formations of the Campi Flegrei volcanic district. The deposit, made up of six distinctive stratigraphic units, has been interpreted by some as the proximal facies of the major caldera-forming Campanian Ignimbrite eruption, and by others as the product of several, more recent, independent and localized events. New geochemical and chemostratigraphical data and Ar–Ar age determinations for several units of the Breccia Museo deposits (~39 ka), correlate well with the Campanian Ignimbrite-forming eruption. The chemical zoning of the Breccia Museo deposits is interpreted here to be a consequence of a three-stage event that tapped a vertically zoned trachytic magma chamber. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.  相似文献   
92.
The ophiolitic sequence which crops out along the Aspropotamos Valley, Northern Pindos, Greece is composed from the bottom to the top of cumulates, dolerites, basaltic lavas, upper pillow lavas with basaltic/andesitic composition, and scarce basaltic dykes. The intrusive sequence, which is the subject of the present paper, exhibits magmatic layering more pronounced at the bottom than at the top where isotropic gabbros occur; they grade into the overlying dolerites. Troctolites with rare ultramafites prevail in the lower section and olivine gabbros in the upper section; at the top two-pyroxene gabbros appear. The rocks are mainly adcumulates and mesocumulates with subordinate heteradcumulates. The cumulus phases separated in the order: olivine and Cr-spinel, plagioclase, clinopyroxene, orthopyroxene. Olivine, plagioclase and pyroxenes frequently exhibit adeumulus overgrowth. Intercumulus phases may be plagioclase, clinopyroxene, orthopyroxene, pale brown amphibole and magnetite. Where pore material is present, it is composed of plagioclase, clinopyroxene, orthopyroxene, hornblende and ores. Cr-spinel occurs mainly at the bottom of the sequence (Cr2O3 between 30·5 and 39·8 per cent), while magnetite appears as a very rare phase in the upper section. Olivine, orthopyroxene, clinopyroxene exhibit slight cryptic variation (Mg × 100/(Mg + Fe) in the range 90–79, 90–70, 93–72 respectively). The investigated dolerites are non-cumulus rocks where clinopyroxene may be more magnesian than in the uppermost gabbros. The cumulate sequence and dolerites underwent variable but generally slight spilitization, in contrast to the overlying lavas. The sequence was generated through crystal accumulation probably from periodic pulses of tholeiitic magma; newly injected magma batches mixing with magma fractions already differentiated in the magma chamber. The high fluid pressure evidenced by the fluid inclusions in plagioclase and the whole chemical trend of the cumulate sequence are consistent with a genesis above a subduction zone, as already hypothesized for the overlying lavas.  相似文献   
93.
A numerical approach is presented for the ‘identification’ (or back calculation) of the earth pressure acting on embedded or retaining structures. The procedure is applicable to structures of any shape and requires a set of in situ measurements that may include displacements of points on the structure, values of concentrated forces, values of distributed loads at some locations, etc. Possible limiting values of the unknown loads, non-linear structural behaviour, varying accuracies of the input data are accounted for in the problem formulation. Depending upon the type of problem, the solution is reached by means of the unconstrained or constrained minimization of a suitably defined error function. As an example, the proposed approach is applied to the identification of the earth pressure acting on some typical geotechnical engineering structures.  相似文献   
94.
The winter water mass distributions in the western Gulf of Mexico, affected by the collision of a Loop Current anticyclonic ring, during January 1984 are analyzed. Two principal modes of Gulf Common Water (GCW) formation, arising from the dilution of the Caribbean Subtropical Underwater (SUW), are identified. Within the western gulf continental slope to the east of Tamiahua, the GCW is formed by the collision of anticyclonic rings. During these collision events, the SUW, entrapped at the core (200 m depth) of these features, is diluted by low salinity (36.1S36.3) water from the uppermost layer of the main thermocline. The end product of this mixture is GCW, which is further diluted by low salinity coastal water within the western gulf continental shelf. The second GCW formation mode is associated to the northerly wind stress which propagates over the western gulf during winter. During January, 1984, this wind stress gave rise to a 175 m mixed layer. This convective mixing destroyed the static stability of the summer thermocline and allowed for the partial dilution of the SUW with low salinity (S36.3) water from the western gulf continental shelf. Within the western gulf's upper 2000 m, the following water masses were identified to be present: GCW, SUW, Tropical Atlantic Central Water and associated dissolved oxygen minimum stratum, Antarctic Intermediate Water remnant, a mixture of the Caribbean Intermediate Water and the upper portion of North Atlantic Deep Water (NADW), and the NADW itself. The topographic distribution of these water masses' strata was dictated by the cyclonic-anticyclonic baroclinic circulation that evolved from the anticyclone's collision to the east of Tamiahua. Between the cyclonic and anticyclonic domains, the maximum pressure differential of these water masses' core occurrences was 150 to 280 dbar. The topographic transition zone defined by these strata occurred between the cyclonic and anticyclonic domains and coincided unambiguously with the anticyclone's collision zone. Within the continental shelf, we identified low temperature (12°C) and low salinity (31) coastal waters contributed by river runoff. Driven by the northerly wind stress, these coastal waters were advected toward the south hugging the coastline. The coastal and continental shelf waters demarcated a sea surface temperature, salinity, and dissolved oxygen discontinuity region that coincided with the horizontal baroclinic flow transition zone associated to the anticyclone's collision.  相似文献   
95.
The fishery for the edible sea urchin Paracentrotus lividus is of great importance to many European regions, although in some of them this species has shown a wide scale decline in recent years. This paper reports on direct (on P. lividus) and indirect (on the co-occurring but not fished echinoid, Arbacia lixula) effects of sea urchin harvesting in shallow rocky reefs in North-western Sardinia (Italy, central-western Mediterranean Sea), where this activity is intensively practised. Density, size (test diameter), and biomass of both species were assessed in autumn 2004 at two locations impacted by P. lividus fishery, and at two controls within an adjacent Marine Protected Area. Density of P. lividus and A. lixula was significantly greater at the controls than at the exploited locations. The average test diameter of P. lividus was also significantly larger at the controls, where large-sized specimens (i.e. >5 cm) were notably more abundant. The average size of A. lixula did not significantly differ between the impacted locations and the controls. The average biomass of P. lividus was significantly greater at the controls than at the exploited locations, whereas no differences were detected for A. lixula. These results reveal the existence of a heavy fishing impact on P. lividus in North-western Sardinia and the need for regulation of its harvesting to prevent severe direct effects on its populations. Since no indirect effects on A. lixula have been detected, it could be hypothesized that this species did not benefit from P. lividus fishery due to an only moderate competition for habitat and resources between these two echinoids. Implications for management of edible sea urchin fishery are also discussed.  相似文献   
96.
The response of the Gulf of Alaska (GOA) circulation to large-scale North Pacific climate variability is explored using three high resolution (15 km) regional ocean model ensembles over the period 1950-2004. On interannual and decadal timescales the mean circulation is strongly modulated by changes in the large scale climate forcing associated with PDO and ENSO. Intensification of the model gyre scale circulation occurs after the 1976-1977 climate shift, as well as during 1965-1970 and 1993-1995. From the model dynamical budgets we find that when the GOA experiences stronger southeasterly winds, typical during the positive phase of the PDO and ENSO, there is net large-scale Ekman convergence in the central and eastern coastal boundary. The geostrophic adjustment to higher sea surface height (SSH) and lower isopycnals lead to stronger cyclonic gyre scale circulation. The opposite situation occurs during stronger northwesterly winds (negative phase of the PDO).Along the eastern side of the GOA basin, interannual changes in the surface winds also modulate the seasonal development of high amplitude anticyclonic eddies (e.g. Haïda and Sitka eddies). Large interannual eddy events during winter-spring, are phase-locked with the seasonal cycle. The initial eddy dynamics are consistent with a quasi-linear Rossby wave response to positive SSH anomalies forced by stronger downwelling favorable winds (e.g. southwesterly during El Niño). However, because of the fast growth rate of baroclinic instability and the geographical focusing associated with the coastal geometry, most of the perturbation energy in the Rossby wave is locally trapped until converted into large scale nonlinear coherent eddies. Coastally trapped waves of tropical origin may also contribute to positive SSH anomalies that lead to higher amplitude eddies. However, their presence does not appear essential. The model ensembles, which do not include the effects of equatorial coastally trapped waves, capture the large Haïda and Sitka eddy events observed during 1982 and 1997 and explain between 40% and 70% of the tidal gauges variance along the GOA coast.In the western side of the GOA basin, interannual eddy variability located south of the Alaskan Stream is not correlated with large scale forcing and appears to be intrinsic. A comparison of the three model ensembles forced by NCEP winds and a multi-century-long integration forced only with the seasonal cycle, shows that the internal variability alone explains most of the eddy variance. The asymmetry between the eddy forced regime in the eastern basin, and the intrinsic regime in the western basin, has important implications for predicting the GOA response to climate change. If future climate change results in stronger wintertime winds and increased downwelling in the eastern basin, then increased mesoscale activity (perhaps more or larger eddies) might occur in this region. Conversely, the changes in the western basin are not predictable based on environmental forcing. Eastern eddies transport important biogeochemical quantities such as iron, oxygen and chlorophyll-a into the gyre interior, therefore having potential upscale effects on the GOA high-nutrient-low-chlorophyll region.  相似文献   
97.
98.
Acid extractions represent a simple and effective tool for the assessment of metal contamination, origin and bioavailability in the aquatic environment. Optimized microwave-assisted procedures utilizing two extractions (8 M HNO3 and 1 M HCl) were developed. Particular attention was given to the evaluation of efficiency and selectivity of the developed procedures. This involved an examination of the sediment and the extraction residues by Mössbauer spectroscopy and X-ray diffractometry. These instrumental approaches were used to identify the geochemical phases associated with acid decomposition. Microwave digestion with 8 M HNO3 produced an efficient solubilization of the most important metal-bearing phases and left unaffected only the minerals (quartz, feldspars, muscovite) with a negligible metal content, thus providing a good estimate of the total metal concentrations. The 1 M HCl extraction, despite the limitation due to the incomplete solubilization of pyrite and to the partial dissolution of sheet silicates, represents a simple and effective technique for providing an estimate of the bioavailable metal fraction in sediments. The combined use of the two microwave-assisted acid extractions can provide a rapid and simple approach for the risk assessment of metal-polluted sediments.  相似文献   
99.
100.
A 2D depth‐averaged model has been developed for simulating water flow, sediment transport and morphological changes in gravel‐bed rivers. The model was validated with a series of laboratory experiments and then applied to the Nove reach of the Brenta River (Northern Italy) to assess its bed material transport, interpret channel response to a series of intensive flood events (R.I. ≈ 10 years) and provide a possible evolutionary scenario for the medium term. The study reach is 1400 m long with a mean slope of 0.0039 m m?1. High‐resolution digital terrain models were produced combining LiDAR data with colour bathymetry techniques. Extensive field sedimentological surveys were also conducted for surface and subsurface material. Data were uploaded in the model and the passage of two consecutive high intensity floods was simulated. The model was run under several hypotheses of sediment supply: one considering substantial equilibrium between sediment input and transport capacity, and the others reducing the sediment supply. The sediment supply was then calibrated comparing channel morphological changes as observed in the field and calculated by the model. Annual bed material transport was assessed and compared with other techniques. Low‐frequency floods (R.I. ≈ 1.5 years) are expected to produce negligible changes in the channel while high floods may erode banks rather than further incising the channel bed. Location and distribution of erosion and deposition areas within the Nove reach were predicted with acceptable biases stemming from imperfections of the model and the specified initial, boundary and forcing conditions. A medium‐term evolutionary scenario simulation underlined the different response to and impact of a consecutive sequence of floods. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   
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