Detection of a new interstellar molecular ion, H2COH+ (protonated formaldehyde)     

Ohishi M  Ishikawa SI  Amano T  Oka H  Irvine WM  Dickens JE  Ziurys LM  Apponi AJ 《The Astrophysical journal》1996,471(1):L61-L64

A new interstellar molecular ion, H2COH+ (protonated formaldehyde), has been detected toward Sgr B2, Orion KL, W51, and possibly in NGC 7538 and DR21(OH). Six transitions were detected in Sgr B2(M). The 1(1,0)-1(0,1) transition was detected in all sources listed above. Searches were also made toward the cold, dark clouds TMC-1 and L134N, Orion (3N, 1E), and a red giant, IRC + 10216, without success. The excitation temperatures of H2COH+ are calculated to be 60-110 K, and the column densities are on the order of 10(12)-10(14) cm-2 in Sgr B2, Orion KL, and W51. The fractional abundance of H2COH+ is on the order of 10(-11) to 10-(9), and the ratio of H2COH+ to H2CO is in the range 0.001-0.5 in these objects. The values in Orion KL seem to be consistent with the "early time" values of recent model calculations by Lee, Bettens, & Herbst, but they appear to be higher than the model values in Sgr B2 and W51 even if we take the large uncertainties of column densities of H2CO into account. We suggest production routes starting from CH3OH may play an important role in the formation of H2COH+.  相似文献   

A photochemical model of the martian atmosphere     

Nair H  Allen M  Anbar AD  Yung YL  Clancy RT 《Icarus》1994,111(1):124-150

The factors governing the amounts of CO, O2, and O3 in the martian atmosphere are investigated using a minimally constrained, one-dimensional photochemical model. We find that the incorporation of temperature-dependent CO2 absorption cross sections leads to an enhancement in the water photolysis rate, increasing the abundance of OH radicals to the point where the model CO abundance is smaller than observed. Good agreement between models and observations of CO, O2, O3, and the escape flux of atomic hydrogen can be achieved, using only gas-phase chemistry, by varying the recommended rate constants for the reactions CO + OH and OH + HO2 within their specified uncertainties. Similar revisions have been suggested to resolve discrepancies between models and observations of the terrestrial mesosphere. The oxygen escape flux plays a key role in the oxygen budget on Mars; as inferred from the observed atomic hydrogen escape, it is much larger than recent calculations of the exospheric escape rate for oxygen. Weathering of the surface may account for the imbalance. Quantification of the escape rates of oxygen and hydrogen from Mars is a worthwhile objective for an upcoming martian upper atmospheric mission. We also consider the possibility that HOx radicals may be catalytically destroyed on dust grains suspended in the atmosphere. Good agreement with the observed CO mixing ratio can be achieved via this mechanism, but the resulting ozone column is much higher than the observed quantity. We feel that there is no need at this time to invoke heterogeneous processes to reconcile models and observations.  相似文献   

Near-infrared spectroscopy of dark asteroids     

Barucci MA  Lazzarin M  Owen T  Barbieri C  Fulchignoni M 《Icarus》1994,110(2):287-291

Near-infrared (J, H and K bands) spectra of nine dark asteroids (chosen among a sample of supposed primitive objects between C and D classes) have been obtained at the Mauna Kea Observatory (Hawaii) with the 2.2-m telescope using KSPEC as spectrograph. The aim of this work was to search for evidence of the presence of organic materials in these objects as found in other planetary bodies as 5145 Pholus, and in some cometary nuclei. A careful analysis of the data has revealed flat or slightly redder spectra than the solar one for all observed asteroids. No evidence of distinct absorption features was found.  相似文献   

Reservoir timescales for anthropogenic CO2 in the atmosphere     

O'Neill BC  Gaffin SR  Tubiello FN  Oppenheimer M 《Tellus. Series B, Chemical and physical meteorology》1994,46(5):378-389

Non-steady state timescales are complicated and their application to specific geophysical systems requires a common theoretical foundation. We first extend reservoir theory by quantifying the difference between turnover time and transit time (or residence time) for time-dependent systems under any mixing conditions. We explicitly demonstrate the errors which result from assuming these timescales are equal, which is only true at steady state. We also derive a new response function which allows the calculation of age distributions and timescales for well-mixed reservoirs away from steady state, and differentiate between timescales based on gross and net fluxes. These theoretical results are particularly important to tracer-calibrated "box models" currently used to study the carbon cycle, which usually approximate reservoirs as well-mixed. We then apply the results to the important case of anthropogenic CO2 in the atmosphere, since timescales describing its behavior are commonly used but ambiguously defined. All relevant timescales, including lifetime, transit time, and adjustment time, are precisely defined and calculated from data and models. Apparent discrepancies between the current, empirically determined turnover time of 30-60 years and longer model-derived estimates of expected lifetime and adjustment time are explained within this theoretical framework. We also discuss the results in light of policy issues related to global warming, in particular since any comparisons of the "lifetimes" of different greenhouse gases (CO2, CH4, N2O, CFC's etc.) must use a consistent definition to be meaningful.  相似文献   

Nitrogen sulfide in quiescent dark clouds     

McGonagle D  Irvine WM  Ohishi M 《The Astrophysical journal》1994,422(2):621-625

We report the first detection of interstellar nitrogen sulfide (NS) in cold dark clouds. Several components of the 2 pi 1/2, J = 3/2 --> 1/2 and J = 5/2 --> 3/2 transitions were observed in TMC-1 and L134N. The inferred column density for TMC-1 is NNS approximately 8 x 10(12)cm-2 toward the NH3 peak in that cloud, and in L134N is NNS approximately 3 x 10(12)cm-2 toward the position of peak NH3 emission. These values correspond to fractional abundances relative to molecular hydrogen of fNS approximately 8 x 10(-10) for TMC-1, and fNS approximately 6 x 10(-10) for L134N. The NS emission is extended along the TMC-1 ridge and is also extended in L134N. The measured abundances are significantly higher than those predicted by some recent gas phase ion-molecule models.  相似文献   

Carbon isotope systematics of individual hydrocarbons in hydrothermal petroleum from Escanaba Trough, northeastern Pacific Ocean     

Simoneit BR  Schoell M  Kvenvolden KA 《Organic Geochemistry》1997,26(7-8):511-515

We submitted individual aliphatic and polycyclic aromatic hydrocarbons in samples of hydrothermal petroleum from Escanaba Trough to compound specific isotope analysis to trace their origins. The carbon isotope compositions of the alkanes and polycyclic aromatic hydrocarbons (means -27.5 and -24.7%, respectively) reflect a primarily terrestrial organic matter source.  相似文献   

Sedimentary Features of Shallow Ancient River Channels on the Northern Shelf of the South China Sea   总被引：1，自引：0，他引：1  

Kou Yangqi  Du Deli nd Marine Geological Investigation Party  MGMR  Guangzhou  Guangdong Jiang M inxi 《《地质学报》英文版》1995,69(1)

Quaternary buried ancient river channels are widespread in the shallow-level sediments of the northern shelf of the South China Sea. The sedimentary sequence mainly of fluvial deposits comprise an important component part of the low-stand system tract and transgressive system tract in the study region. The plannar variation and spatial association of the sedimentary features such as incised valley fillings, deltaic foreset wedges and block slides of shelf-marginal fans reflect the palaeogeographic environment during the fall of the regional sea level in the northern part of the South China Sea. Based on the high-resolution seismic reflection data and gelogical data from boreholes, the present paper makes an integrated interpretation of the Quaternary ancient river channels in the shallow sediments of the study area, studies the sedimentary features of the ancient channels such as their spatial distribution, seismic facies reflection indicators, sedimentary facies and sand -body types, and discusses thei  相似文献   

Measurements in N2-CH4(C2H2) discharges of reaction rates and thermochemical constants for Titan atmosphere study     

Ricard A  Cernogora G  Fitaire M  Hochard L  Kouassi N  Speller C  Vacher JR 《Planetary and Space Science》1995,43(1-2):41-46

The kinetic reactions in N2-xCH4(C2H2) gas discharges with x less than 1% have been studied by emission spectroscopy in the afterglow of D.C. discharges and by mass spectroscopy from radiolysis ionization using alpha particles. The pressure range is from several Torr to 100 Torr. At the end of N2 D.C. discharges at room temperature, for a residence time of about 10(-2) s, the dominant active species are the N atoms with density of 10(14)-10(15) cm-3 for N2 density of about 10(17) cm-3 (3 Torr), the N2(X,V) vibrational molecules with for example [N2(X,V = 10)] approximately 10(14) cm-3 and the electronic metastable molecules N2(A 3 sigma u +) with a density of 10(12) cm-3. In such conditions, the following kinetic reactions have been studied: N2(A) + N2(A) --> N2(C,B,V') + N2(X), N2(A) + N2(X,V>5) --> N2(X) + N2(B,V') in pure N2 post-discharges and N2(A) + CH4 --> products, C + N + M2 --> CN(B,V') + M2, N2(X,V>4) + CN --> N2(X) + CN(B,A,V'), in N2-1% CH4 post-discharges. The clustering reactions of N2-(1-5%)CH4(C2H2) gas mixtures after radiolysis ionization have been studied for the H2CN+ nN2 ions and the equilibrium constants have been determined in the temperature range T = 140-300 K.  相似文献   

哀牢山-红河剪切带的热年代学研究——多重扩散域模式的应用实例   总被引：22，自引：3，他引：19       下载免费PDF全文

陈文寄 Harr.  M 《地震地质》1992,14(2):121-128

洛弗拉等人(1989)把Dodson(1973)建立的单一扩散域模式扩展成矿物扩散域不连续分布的模式,即多重扩散域模式,与之对应具有某一封闭温度范围,因此利用单个K-长石矿物样品可以揭示更长时间段上的冷却过程。对云南哀牢山-红河剪切带的K-长石样品(FA-2-1)进行40Ar/39Ar同位素分析,利用多重扩散域模式,揭示在距今约20～19Ma问该带存在一快速冷却过程,这与西藏南部曲水地区快速抬升的时间是一致的  相似文献   

Chemical abundances in cold, dark interstellar clouds     

Irvine WM  Ohishi M  Kaifu N 《Icarus》1991,91(1):2-6

The Sun may well have formed in the type of interstellar cloud currently referred to as a cold, dark cloud. We present current tabulations of the totality of known interstellar molecules and of the subset which have been identified in cold clouds. Molecular abundances are given for two such clouds which show interesting chemical differences in spite of strong physical similarities, Taurus Molecular Cloud 1 (TMC-1) and Lynd's 134N (L134N, also referred to as L183). These regions may be at different evolutionary stages.  相似文献