Methane‐related microbial gypsum calcitization in stromatolites of a marine evaporative setting (Münder Formation,Upper Jurassic,Hils Syncline,north Germany)     

GERNOT ARP  CHRISTIAN OSTERTAG‐HENNING  SELÇÜK YÜCEKENT  JOACHIM REITNER  VOLKER THIEL 《Sedimentology》2008,55(5):1227-1251

Fossil stromatolites may reveal information about their hydrochemical palaeoenvironment, provided that assignment to a specific microbial community and a corresponding biogeochemical mechanism of formation can be made. Tithonian stromatolites of the Münder Formation at Thüste, north Germany, have traditionally been considered as formed by intertidal cyanobacterial communities. However, thin sections of the stromatolites show elongated angular traces of former gypsum crystals in a dense arrangement, but no algal or cyanobacterial filament traces. Moreover, high Fe²⁺ and Mn²⁺ contents, oxygen‐isotope and sulphur‐isotope ratios of carbonate‐bound sulphates, and sulphurized hydrocarbon biomarkers of the stromatolitic carbonate indicate that CaCO₃ precipitation occurred near the oxic–anoxic interface as a result of intensive bacterial sulphur cycling rather than photosynthetic activity. Furthermore, anaerobic oxidation of methane by Archaea may have driven CaCO₃ precipitation in deeper parts of the biofilm community, as reflected by high concentrations of squalane with a strongly negative δ¹³C in conjunction with evaporite pseudomorphs showing extremely low δ¹³C_Carb ratios. Consequently, the Thüste stromatolites are now interpreted as having initially formed by gypsum impregnation of biofilms. Subsequently, early Mg‐calcitic calcitization within the biofilms occurred because of combined bacterial iron, manganese and sulphate reduction, with an increasing contribution of anaerobic oxidation of methane with depth. This model plausibly explains the prominent preservation of signals derived from oxygen‐independent metabolic pathways, whereas virtually no geochemical record exists for an aerobic community that may, nevertheless, have prevailed at the stromatolite surface. Photic‐zone stromatolites with a prominent signal of anaerobic oxidation of methane may be common in, and indicative of, oxygen‐depleted sulphate‐bearing environments with high rates of methane production, conditions that possibly were fulfilled at the Archaean to Proterozoic transition.  相似文献   

Multiple discriminant analysis of the Drava River alluvial plain sediments     

Zoran Peh  Robert Šajn  Josip Halamić  Lidija Galović 《Environmental Geology》2008,55(7):1519-1535

Three discriminant function models are raised and cross-compared in order to distinguish geochemical patterns characteristic for the Drava River floodplain sediments. Based on data representing total element concentrations in samples collected from alluvium (A), terrace (T), and unconsolidated bedrock (B) at the border of a floodplain, four element clusters emerged accounting for discrimination between the referred groups of sediments. The most prominent is contaminant/carbonate cluster characteristic for alluvium. The other two are: silicate cluster typical for unconsolidated geological substrate (Neogene sedimentary rocks); and naturally dispersed heavy metal cluster separating terrace from the former two groups. Models introducing depth intervals and single profiles as grouping criteria reveal identical sediment-heavy metal matrices. The second important issue of this paper is possibility of reclassification of samples originally assigned to one of the a priori defined groups of sediments, based on established geochemical pattern. The mapped geological units can be reconsidered by the post hoc assignments to a different group if geological border between alluvium and terrace or between terrace and bedrock can not be established geologically with absolute certainty.  相似文献   

Biomarker distributions as indicators for the depositional environment of lacustrine sediments in the Valjevo-Mionica basin (Serbia)     

Aleksandra Šajnović  Ksenija Stojanović  Branimir Jovančićević  Olga Cvetković 《Chemie der Erde / Geochemistry》2008,68(4):395-411

In this study, the molecular composition and biomarker distribution of lacustrine sediments from Val-1 drillhole in the central zone of the western part of the Valjevo-Mionica basin were investigated at depth interval of 0–400 m. Former investigations have shown that the core material can be separated into six depth intervals based on bulk geochemical, mineralogical and sedimentological characteristics. Concerning the quality of organic matter, presence of specific minerals, and high salinity and anoxicity, or alkalinity, three zones are of highest interest, defined at depth intervals of 15–75 m (A), 75–200 m (B) and 360–400 m (F). The first aim of the study was to identify which biomarkers characterize these specific intervals. The second aim, addressing the transitions zones of these intervals, was to extend the changes in the characteristics of the organic substance, to reflect the changes of conditions in the depositional environment as well as to define biomarker parameters which are the most sensitive sedimentological indicators.The sediments from the hypersaline anoxic and alkaline environment show high contribution of algal precursor biomass, what is in accordance with the good quality of organic substances in the sediments from these zones. High squalane content and low content of regular isoprenoid C₂₅ are typical for hypersaline anoxic environment, whereas sediments from alkaline environment have high regular isoprenoid C₂₅ content.Transition to specific sedimentation zones is characterized by change in total organic matter content, and of both free and pyrolysis-derived, and change in hydrogen index value. In the biomarker distributions, more significant changes were detected in distributions of n-alkanes and isoprenoids, compared to polycyclic alkanes. The most intensive changes in alkane distribution are reflected in changes in n-C₁₇ content compared to n-C₂₇, and phytane compared to n-C₁₈. In addition, significant sensitivity was seen in ratios between squalane and n-alkane C₂₆ (hypersaline depositional environment), or isoprenoid C₂₅ and n-alkane C₂₂ for high alkalinity environment.This study showed that Sq/n-C₂₆ ratio can be used to assess the quality of organic substance in immature lacustrine sediments.  相似文献   

DEM analysis of the crack propagation in brittle clays under uniaxial compression tests   总被引：2，自引：0，他引：2  

Luis F. Vesga  Luis E. Vallejo  Sebastian Lobo‐Guerrero 《国际地质力学数值与分析法杂志》2008,32(11):1405-1415

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Numerical estimation of REV and permeability tensor for fractured rock masses by composite element method   总被引：2，自引：0，他引：2  

S.‐H. Chen  X.‐M. Feng  S. Isam 《国际地质力学数值与分析法杂志》2008,32(12):1459-1477

The Monte Carlo method is used to generate parent stochastic discrete fracture network, from which a series of fractured rock samples of different sizes and orientations are extracted. The fracture network combined with a regular grid forms composite element mesh of the fractured rock sample, in which each composite element is composed of sub‐elements incised by fracture segments. The composite element method (CEM) for the seepage is implemented to obtain the nodal hydraulic potential as well as the seepage flow rates through the fractured rock samples. The application of CEM enables a large quantity of stochastic tests for the fractured rock samples because the pre‐process is facilitated greatly. By changing the sizes and orientations of the samples, the analysis of the seepage characteristics is realized to evaluate the variation of the permeability components, the existence of the permeability tensor and the representative element volume. The feasibility and effectiveness are illustrated in a numerical example. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   

Biaxial test simulations using a packing of polygonal particles   总被引：1，自引：0，他引：1  

A. A. Peña  A. Lizcano  F. Alonso‐Marroquin  H. J. Herrmann 《国际地质力学数值与分析法杂志》2008,32(2):143-160

The mechanical response of cohesionless granular materials under monotonic loading is studied by performing molecular dynamic simulations. The diversity of shapes of soil grains is modelled by using randomly generated convex polygons as granular particles. Results of the biaxial test obtained for dense and loose media show that samples achieve the same void ratio at large strains independent of their initial density state. This limit state resembles the so‐called critical state of soil mechanics, except for some stress fluctuations, which remain for large deformations. These fluctuations are studied at the micro‐mechanical level, by following the evolution of the co‐ordination number, force chains and the fraction of the sliding contacts of the sample. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

Flexural isostatic response of the Alps to increased Quaternary erosion recorded by foreland basin remnants,SE France     

Jean‐Daniel Champagnac  Peter Van Der Beek  Gaël Diraison  Samuel Dauphin 《地学学报》2008,20(3):213-220

We test the hypothesis that flexural isostatic compensation of the mass removed by enhanced Quaternary erosion is responsible for uplift of the Western European Alps and their forelands. We use two well‐preserved and well‐dated (1.8 Ma) abandonment surfaces of foreland basin remnants in SE France (the Chambaran and Valensole plateaux) as passive benchmarks for tilting of the foreland. Estimating their initial slope from morphometric scaling relationships, we determine bulk post‐depositional tilting of 0.5–0.8% for these surfaces. The calculated isostatic response of the Alpine lithosphere to erosional unloading, using the method recently proposed by Champagnac et al. [Geology 35 (2007) 195–198] , yields a predicted tilting of 0.3–0.4% in the considered areas, explaining approximately half of the determined post‐depositional tilting. Such long‐term deformation being insensitive to cyclic loading/unloading because of glaciations, we suspect the other half to be related to as yet undetermined long‐wavelength and long‐lived tectonic process(es).  相似文献   

Thermodynamische Antizyklogenese     

M. Čadež 《Pure and Applied Geophysics》1960,47(1):172-182

Zusammenfassung Man beobachtet Antizyklonen, die als Folge einer Konzentration von Kaltluftmasssen auf ein kleineres Gebiet gedeutet werden können. Die Konzentration der Kaltluft ist durch die Umwandlung der kinetischen Energie der Kaltluft in potentielle Energie oder durch die Wärmezufuhr der kalten Luft bedingt. Solche Antizyklonen bilden sich oft in Berggebieten, da dort wegen der grossen äusseren Reibung die erwähnte Umwandlung der Energie beschleunigt wird. Wie gross solche antizyklogenetischen Effekte sein können, ist berechnet.

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Summary The origin of some anticyclones can be explained as a consequence of the concentration of the cold air on a smaler area. The concentration of the cold air is caused by a transformation of the kinetic energy of the cold air into the potential energy or by the heating of the cold air. Such anticyclones often appear in mountain regions where the transformation of the mentioned energy is more intense. The intensity of such anticyclogenetical effects is evaluated.

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Ermittlung der QNH-werte aus dem luftdruckfeld der synoptischen bodenkarte     

Antonín Papež 《Studia Geophysica et Geodaetica》1964,8(2):200-204

Резюме Дабление воздуха, переснитанное иа уровень моря по стандартной атмосфере в Q-коде обозчачается через QNH. Давление воздуха пересчитанное на уровень моря по высотной барометрической формуле обознаеается через QFF. Для целей авиационной службы погоды должны быть известны значения QNH, однако Зе барическое поле на синоптических картах выражается через QFF. С помощью рис. 1 для соответствующей температуры воздуха на станцин и ее высоты н. у. м. можно определить разность значений QFF—QNH при давленин QFF=1000мб. Далее по табл. 2 можно определить поправку для каждого значения QFF отличного от значения QFF при ином давлении, чем 1000мб путем умножения табулированного значения ва разность QFF—1000мб и его алгебраического сложения со значением, полученным по рис. 1.   相似文献   

La formation des Nuages Altocumulus Translucidus     

M. Čadež 《Pure and Applied Geophysics》1963,54(1):182-189

Résumé Dans cette étude l'explication de la formation des nuages Ac tra part de la supposition que l'air dans ce type de nuages est plus froid que l'air environnant, ce qui provoque certains courants convectifs dans la région du nuage. Ces courants ressemblent à ceux qui sont supposés par la théorie thermoconvective actuelle. D'après notre avis se trouvent des courants descendants audessous des petits nuages qui composent l'Ac tra, et les petits nuages qui forment l'Ac tra sont des corps séparés dont la température est moindre que la température de l'air environnant: c'est pour cela qu'ils tombent. Au contraire, d'après la théorie thermoconvective actuelle, l'air audessous de petits nuages monte et dans la distribution de la température des discontinuités n'existent pas.

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Summary In this paper the explanation of the formation of clouds Ac tra is based on the assumption that the air in the cloud is colder than the surrounding air, causing convective currents in the region of the cloud. These currents are not unlike those assumed by the existing thermoconvective theory. According to the author's view there are descending currents under the cloudlets of which the Ac tra is made, and these cloudlets are separate bodies at a lower temperature than that of the surrounding air, so that the cloudlets fall. On the contrary, according to the existing thermoconvective theory, the air under the cloudlets rises and there are no discontinuities in the distribution of the temperature.

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Rapport présenté le 26 Avril 1962 à la Xème Assemblée Générale de laSocietà Italiana di Geofisica e Meteorologia (26–28 Avril 1962)  相似文献