Homogeneous nucleation of amorphous solid water particles in the upper mesosphere     

Benjamin J. Murray  Eric J. Jensen 《Journal of Atmospheric and Solar》2010,72(1):51-61

Condensed water particles are known to exist in the high latitude upper mesosphere during the summer months. However, the mechanism or mechanisms through which they nucleate remains uncertain. It is postulated here that particles of amorphous solid water (ASW, condensed water with a non-crystalline structure) may nucleate homogeneously in the summer mesosphere. Using classical nucleation theory and a one-dimensional model, it is shown that more than 10⁵ cm^?3 amorphous solid water particles can nucleate homogeneously under mesopause conditions. Furthermore, it is shown that homogeneous nucleation competes with heterogeneous nucleation on meteoric smoke particles when the cooling rate is >0.5 K/h. The homogeneous nucleation of amorphous solid water could provide an explanation for the high density of ice particles (many thousands per cm³) thought to be required for electron depletions in the upper mesosphere. A parameterisation for homogeneous nucleation is presented which can be used in other mesospheric cloud models.  相似文献   

Statewide groundwater‐vulnerability assessment in nebraska using the drastic/GIS model     

Donald C. Rundquist  Albert J. Peters  Liping Di  Donn A. Rodekohr  Richard L. Ehrman  Gene Murray 《国际地球制图》2013,28(2):51-58

The paper summarizes a technique for implementing the “DRASTIC” groundwater‐vulnerability model within the context of an automated raster‐based geographic information system. Discussion focuses on a methodological development and a statewide project completed recently in Nebraska. The final products, a comprehensive flow chart illustrating procedures and a map of calculated potential pollution hazard, are presented. The methodology can be executed successfully with minimal training and experience. Areas of Nebraska considered vulnerable to groundwater pollution are identified.  相似文献   

Evaluating the impact of caprock and reservoir properties on potential risk of CO2 leakage after injection     

Zhangshuan Hou  Mark L. Rockhold  Christopher J. Murray 《Environmental Earth Sciences》2012,66(8):2403-2415

Numerical models are essential tools in fully understanding the fate of injected CO₂ for commercial-scale sequestration projects and should be included in the life cycle of a project. Common practice involves modeling the behavior of CO₂ during and after injection using site-specific reservoir and caprock properties. Little has been done to systematically evaluate and compare the effects of a broad but realistic range of reservoir and caprock properties on potential CO₂ leakage through caprocks. This effort requires sampling the physically measurable range of caprock and reservoir properties, and performing numerical simulations of CO₂ migration and leakage. In this study, factors affecting CO₂ leakage through intact caprocks are identified. Their physical ranges are determined from the literature from various field sites. A quasi-Monte Carlo sampling approach is used such that the full range of caprock and reservoir properties can be evaluated without bias and redundant simulations. For each set of sampled properties, the migration of injected CO₂ is simulated for up to 200 years using the water–salt–CO₂ operational mode of the STOMP simulator. Preliminary results show that critical factors determining CO₂ leakage rate through caprocks are, in decreasing order of significance, the caprock thickness, caprock permeability, reservoir permeability, caprock porosity, and reservoir porosity. This study provides a function for prediction of potential CO₂ leakage risk due to permeation of intact caprock and identifies a range of acceptable seal thicknesses and permeability for sequestration projects. The study includes an evaluation of the dependence of CO₂ injectivity on reservoir properties.  相似文献   

Probabilistic Methods Applied to Unsaturated Numerical Modeling     

Murray Fredlund  Gilson GitiranaJr 《Geotechnical and Geological Engineering》2011,29(2):217-223

The numerical modeling of unsaturated soil processes is becoming more prevalent worldwide. Although numerical modeling is becoming increasingly accepted in geotechnical engineering practice, care must be exercised and improper modeling techniques and procedures must be avoided. Many issues such as nodal resolution and imperfect convergence can result in inaccurate solutions. Unfortunately, analyses of highly nonlinear unsaturated soil flow and slope stability models can significantly increase the modeling time required. As a result, there is a trend to reduce the number of model runs. Results are often presented to client as single model runs or simplistic sensitivity analysis. This paper presents methodologies for applying probabilistic methods to unsaturated soils seepage and slope stability analysis models. The focus is on the application of the alternative point estimate method to practical problems in such a way as to minimize the number of model runs. The demonstration of a successful application to a waste rock pile is presented.  相似文献   

Carbon Sequestration and Release from Antarctic Lakes: Lake Vida and West Lake Bonney (McMurdo Dry Valleys)     

G. M. Marion  A. E. Murray  B. Wagner  C. H. Fritsen  F. Kenig  P. T. Doran 《Aquatic Geochemistry》2013,19(2):135-145

Perennial ice covers on many Antarctic lakes have resulted in high lake inorganic carbon contents. The objective of this paper was to evaluate and compare the brine and CO₂ chemistries of Lake Vida (Victoria Valley) and West Lake Bonney (Taylor Valley), two lakes of the McMurdo Dry Valleys (East Antarctica), and their potential consequences during global warming. An existing geochemical model (FREZCHEM-15) was used to convert measured molarity into molality needed for the FREZCHEM model, and this model added a new algorithm that converts measured DIC into carbonate alkalinity needed for the FREZCHEM model. While quite extensive geochemical information exists for ice-covered Taylor Valley lakes, such as West Lake Bonney, only limited information exists for the recently sampled brine of >25 m ice-thick Lake Vida. Lake Vida brine had a model-calculated pCO₂ = 0.60 bars at the field pH (6.20); West Lake Bonney had a model-calculated pCO₂ = 5.23 bars at the field pH (5.46). Despite the high degree of atmospheric CO₂ supersaturation in West Lake Bonney, it remains significantly undersaturated with the gas hydrate, CO₂·6H₂O, unless these gas hydrates are deep in the sediment layer or are metastable having formed under colder temperatures or greater pressures. Because of lower temperatures, Lake Vida could start forming CO₂·6H₂O at lower pCO₂ values than West Lake Bonney; but both lakes are significantly undersaturated with the gas hydrate, CO₂·6H₂O. For both lakes, simulation of global warming from current subzero temperatures (?13.4 °C in Lake Vida and ?4.7 °C in West Lake Bonney) to 10 °C has shown that a major loss of solution-phase carbon as CO₂ gases and carbonate minerals occurred when the temperatures rose above 0 °C and perennial ice covers would disappear. How important these Antarctic CO₂ sources will be for future global warming remains to be seen. But a recent paper has shown that methane increased in atmospheric concentration due to deglaciation about 10,000 years ago. So, CO₂ release from ice lakes might contribute to atmospheric gases in the future.  相似文献   

Significance of ichnofossils to genetic stratigraphy--Examples from the Cretaceous of Alberta, Canada   总被引：1，自引：0，他引：1  

S. George Pemberton  James A. MacEachern  Murray K. Gingras  ZHANG Jianping 《中国科学D辑(英文版)》2000,43(5)

Trace fossils represent both sedimentological and paleontological entities, representing a unique blending of potential environmental indicators in the rock record. Trace fossils and trace fossil suites can be employed effectively to aid in the recognition of various discontinuity types and to assist in their genetic interpretation. Ichnology may be employed to resolve surfaces of stratigraphic significance in two main ways: 1) through the identification of discontinuities using substrate-controlled ichnofacies, and 2) through careful analysis of vertical softground (penecontemporaneous) ichnologic successions (analogous to facies successions). Ichnological analysis is a valuable tool in genetic stratigraphic studies. Integrating the data derived from substrate-controlled ichnofacies with paleoecological data from vertical ichnologic successions greatly enhances the recognition and interpretation of a wide variety of stratigraphic surfaces. When this is coupled with conventional facies analysis and sequence stratigraphy, a powerful approach to the interpretation of the rock record is generated.  相似文献   

Land Cover Change and its Environmental Significance in the Herbert River Catchment,North-east Queensland     

A.K.L. Johnson  S.P. Ebert  A.E. Murray 《The Australian geographer》2000,31(1):75-86

There has been considerable recent concern over the amount of vegetation clearance in the wet tropics of northern Australia. This paper reports on the results of a case study undertaken in the lower Herbert River catchment in north-east Queensland, which utilised remote sensing and Geographic Information Systems (GIS) to assess both spatial and temporal changes in land cover since European settlement in the mid-nineteenth century. We demonstrate that since European settlement there has been a substantial reduction in the area of Melaleuca, rainforest, and eucalyptus-dominated land-cover patterns. We also provide a range of quantitative measures to show that the landscape diversity, integrity and quality of these ecosystems have also declined between the 1860s and 1996. We conclude that reform is required at policy, planning and enterprise levels if the ecological, economic and social values of these systems are to be maintained in the future.  相似文献   

The precession of eccentric discs in close binaries   总被引：1，自引：0，他引：1  

J. R. Murray 《Monthly notices of the Royal Astronomical Society》2000,314(1):L1-L5

If the emission of gamma-ray bursts were as a result of the synchrotron process in the standard internal shock scenario, then the typical observed spectrum should have a slope F _ν ∝ ν ^−1/2, which strongly conflicts with the much harder spectra observed. This directly follows from the cooling time being much shorter than the dynamical time. Particle re-acceleration, deviations from equipartition, quickly changing magnetic fields and adiabatic losses are found to be inadequate to account for this discrepancy. We also find that in the internal shock scenario the relativistic inverse Compton scattering is always as important as the synchrotron process, and faces the same problems. This indicates that the burst emission is not produced by relativistic electrons emitting synchrotron and inverse Compton radiation.  相似文献   

Outback Elvis: the story of a festival,its fans,and a town called Parkes     

Warwick Murray 《The Australian geographer》2019,50(2):265-267

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Understanding the effect of catchment characteristics on suspended sediment dynamics during flood events     

Arman Haddadchi  Murray Hicks 《水文研究》2020,34(7):1558-1574

Hysteresis in the relationship between suspended sediment concentration and flow during run-off events is commonly used to inform on sediment sources and hydrological pathways. Less attention, however, has been paid to comparing the water and sediment hydrographs, which provide a more direct appreciation of in-event sediment dynamics and their relationship with the upstream catchment characteristics. The aim of this study is to better understand the catchment and hydrological controls on the phasing of water and sediment discharges during events and, in particular, to explore what controls sediment concentrations late on event recessions. Continuous records of flow and turbidity data (calibrated to suspended sediment concentration) were collected from 17 catchments across New Zealand for this purpose. Relationships between event sediment yield and peak flow showed, as anticipated, higher event sediment loads were generated in pasture compared with forested catchments and were also higher from catchments in more erodible terrain. One novel result was that these differences were greater during smaller, more frequent events, whereas the loads from larger flood events tended to converge between pasture and forest catchments. Another novel result was that event sediment load tends to be evenly split between rising and falling stages of the hydrograph in pasture catchments, but forested catchments yield more of their event loads on flood recessions, probably because of delayed erosion or more sediment sources remote from the channel network. Land cover, distance of the sediment sources from the monitoring site, and size of the catchments control sediment concentrations late on event recession. Pasture-dominated and more erodible catchments show longer sediment recessions and therefore stay dirtier for longer time periods. In addition, the size of previous flood events appeared to control the extent of sediment exhaustion after the flood peaks in some catchments.  相似文献