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11.
Abstract. Chemical and sulfur isotopic compositions were obtained for a series of rocks within the chert‐clastic sequence surrounding the Kajika massive sulfide ore horizon at Shibukawasawa in the Ashio copper‐mining district, Ashio Terrane, central Japan. The sequence is lithologically classified into three units: chert, siliceous shale with basic volcanics, and sandstone‐shale, in ascending stratigraphic order. The Kajika ore horizon corresponds to the lowermost part of the unit that contains siliceous shale with basic volcanics. The rocks around the Kajika ore horizon are enriched in P2O5 (max. 0.22 %), Ba (max. 2400 ppm), Cu (595 ppm), V (323 ppm), Pb (168 ppm), Zn (124 ppm), and Mo (24 ppm) in siliceous shale; and Ba (4220 ppm), Zr (974 ppm), Cr (718 ppm), Ni (492 ppm), V (362 ppm), Zn (232 ppm), Nb (231 ppm), and Co (71 ppm) in the basic volcanics. The siliceous shale is enriched in a number of redox‐sensitive elements such as Cu, V, Pb, Zn, and Mo, which are known to be enriched in black shale and anoxic and hydrothermal sediments. The δ34S values of sulfides in the chert and sandstone‐shale lie in the range of 0±2 %, and those in the siliceous shale range from ‐5 to ‐14 %. The measured δ34S values in the basic volcanics are ‐0.3, ‐2.7, and ‐31.5 %. These heavier δ34S signatures (around 0 %) recorded throughout the sequence indicate that the rocks formed under anoxic bottom‐water conditions. Slightly lighter δ34S values recorded in siliceous shale might reflect significant mixing of sulfides that formed by sulfate‐reducing bacteria in an overlying oxic environment. The long‐term duration of anoxic conditions indicated by the heavier δ34S signature is considered to have played an important role in protecting the Kajika sulfide ores from oxidative decomposition and preserving the ores in sedimentary accumulations.  相似文献   
12.
Abstract. A series of mudstones corresponding to N.8 to N.17 of Blow from the Uyashinai Mudstone Member, the Onnagawa Formation and the Funakawa Formation in the Taiheizan area of the central Green Tuff region, northeast Japan, was examined by chemical analysis. According to conventional chemical systematics, the mudstones are analyzed in terms of detrital, biogenic-A (siliceous), biogenic-B (calcareous) and hydrogenous components. The relative contribution of the biogenic-A (siliceous) component increases in upward succession in the Uyashinai and Onnagawa mudstones, whereas the contribution of the biogenic-B (calcareous) component is restricted to the lower Uyashinai mudstones. The contribution of hydrogenous components Zn, Pb, Cu and Ba tends to increase during the Nishikurosawa stage, and decreases near the Nishikurosawa/Onnagawa boundary (Pb and Ba) or in the Onnagawa stage (Zn and Cu). The observed enrichment of heavy metals in the Uyashinai mudstones is attributed to the onset of vigorous upwelling of deep water with higher nutrient and metal content associated with a contemporaneous change in global deep-water circulation.  相似文献   
13.
A statistical approach is proposed for nonlinear surface ground analysis. In contrast to the conventional method which deals with only a single ground motion for equivalent linearization of soil properties, a design response spectrum defined at the upper level (bottom of the surface ground) of an engineering bedrock can be handled as the target design earthquake in the present paper. The effective shear strain in each soil layer is evaluated by means of a statistical procedure in which the mean peak shear strain is computed in terms of its standard deviation and the corresponding peak factor. The stiffness and damping ratio of each soil layer are obtained iteratively from the nonlinear relation of stiffness reduction factors and damping ratios with respect to the strain level. After the evaluation of the equivalent stiffness and damping ratio of every soil layer, the ground surface response spectrum is transformed from the design response spectrum defined at the upper level of the engineering bedrock via the one-dimensional wave propagation theory. The reliability and accuracy of the proposed analysis method is examined through the comparison with the results by the conventional method (represented by the program) for many simulated spectrum-compatible ground motions.  相似文献   
14.
Signals from the tsunami waves induced by the March 11, 2011 moment magnitude (Mw) 9.0 Tohoku-Oki earthquake and from subsequent resonances were detected as radial velocity variability by a high-frequency ocean surface radar (HF radar) installed on the eastern coast of the Kii Channel, at a range of about 1000 km from the epicenter along the eastern to southern coasts of Honshu Island. A time–distance diagram of band-passed (9–200 min) radial velocity along the beam reveals that the tsunami waves propagated from the continental shelf slope to the inner channel as progressive waves for the first three waves, and then natural oscillations were excited by the waves; and that the direction of the tsunami wave propagation and the axis of the natural oscillations differed from that of the radar beam. In addition, spectral analyses of the radial velocities and sea surface heights obtained in the channel and on the continental shelf slope suggest complex natural oscillation modes excited by the tsunami waves.  相似文献   
15.
Dislocation microstructures in experimentally deformed single-crystal pyrope-rich garnet, (Mg,Fe)3(Al,Cr)3Si3O12, and polycrystalline forsterite, Mg2SiO4, were investigated by using electron channeling contrast imaging (ECCI) and transmission electron microscopy (TEM) combined with a focused ion beam (FIB)-microsampling. In the orientation-optimized ECCI method, we successfully observed individual dislocations across subgrain boundaries in a low-atomic-number mineral, pyrope-rich garnet (averaged Z-numbers, AZs ~ 10). Dislocations in a deformed forsterite (iron-free olivine) were also visible in the ECCI. In the ECCI on the single-crystal garnet, deformation bands consisting of dislocations, unusual contrasts in stripes and inhomogeneous distributions of sub-micrometer-sized pores were found. Further site-specific TEM observation on the deformation band revealed a high density of partial dislocations and stacking fault ribbons. The site-specific characterizations from ECCI to TEM, with assistance of FIB, can provide a new approach to investigate dislocation microstructures of deformed materials at high pressure and high temperature.  相似文献   
16.
Dietary intake is one of the important routes of human exposure to brominated flame retardants (BFRs) such as polybrominated diphenyl ethers (PBDEs). The use of PBDEs may also result in exposure to polybrominated dibenzo-p-dioxins and dibenzofurans (PBDDs/DFs), as these compounds are impurities in technical mixtures of BFRs and can also be formed unintentionally by the same processes that generate chlorinated dioxins. This study determined the concentrations of polybrominated compounds in common seafood in Guangzhou and Zhoushan, and assessed the health risks of these chemicals via consumption of contaminated seafood. Seafood samples (fish, bivalves, shrimp, crab, and cephalopods) purchased from local markets in 2003 and 2004 were analyzed for PBDEs and PBDDs/DFs. The highest concentration of total PBDEs (46.3 ng g(-1) lipid wt.) was detected in fish from Guangzhou, in which BDEs 47 and 209 were the two predominant congeners. The total daily intakes of PBDEs, PBDDs, and PBDFs were, 946, 6.39, and 6.54 pg kg(-1) body weight (bw) in Guangzhou, and 489, 4.99, and 7.65 pg kg(-1) bw in Zhoushan, respectively. The hazard ratios for PBDDs and PBDFs were both greater than unity, indicating that these compounds may pose some health risks to the local population.  相似文献   
17.
ABSTRACT

This paper proposed and evaluated an estimation method for indoor positioning. The method combines location fingerprinting and dead reckoning differently from the conventional combinations. It uses compound location fingerprints, which are composed of radio fingerprints at multiple points of time, that is, at multiple positions, and displacements between them estimated by dead reckoning. To avoid errors accumulated from dead reckoning, the method uses short-range dead reckoning. The method was evaluated using 16 Bluetooth beacons installed in a student room with the dimensions of 11 × 5 m with furniture inside. The Received Signal Strength Indicator (RSSI) values of the beacons were collected at 30 measuring points, which were points at the intersections on a 1 × 1 m grid with no obstacles. A compound location fingerprint is composed of RSSI vectors at two points and a displacement vector between them. Random Forests (RF) was used to build regression models to estimate positions from location fingerprints. The root mean square error of position estimation was 0.87 m using 16 Bluetooth beacons. This error is lower than that received with a single-point baseline model, where a feature vector is composed of only RSSI values at one location. The results suggest that the proposed method is effective for indoor positioning.  相似文献   
18.
A dataset of historical river discharge into oceans was created using the CaMa-Flood global river routing model and adjusted runoff from the land component of JRA-55. The major rivers were well resolved with a 0.25° horizontal resolution. The total runoff on each drainage basin exhibits a distinctive bias on decadal time scales. The input runoff data were modified using 5-year low-pass-filtered multiplicative factors to fit the annual mean climatology and decadal variations in the reference dataset. The model incorporated data from 1958 to 2016. The yearly and seasonal variations of the major rivers are well represented by the model.  相似文献   
19.
20.
The chemical composition and microstructure of rutile grains in a ultra-high pressure metamorphic gneiss of the Saxonian Erzgebirge, Germany have been studied by Raman spectroscopy, SEM, EMPA and TEM. Rutile inclusions in garnet contain free dislocations, iron-enriched dislocations and exsolved ilmenite lamellae, while subgrain boundaries are observed in rutile grains of the rock matrix. The previously reported α-PbO2 type TiO2 phase could not be confirmed by our TEM observations. On the basis of Zr solubility in the rutile and the presence of microdiamonds, minimum metamorphic peak conditions of 3.95 GPa and 915 °C are estimated.  相似文献   
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