Analysis of the THM behaviour in a clay-based engineered barrier system (EBS): modelling of the HE-E experiment (Mont Terri URL)     

Xuerui Wang  Hua Shao  Jürgen Hesser  Olaf Kolditz 《Environmental Earth Sciences》2016,75(20):1350

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Impact of drilling mud on chemistry and microbiology of an Upper Triassic groundwater after drilling and testing an exploration well for aquifer thermal energy storage in Berlin (Germany)     

Simona Regenspurg  Mashal Alawi  Guido Blöcher  Maria Börger  Stefan Kranz  Ben Norden  Ali Saadat  Traugott Scheytt  Lioba Virchow  Andrea Vieth-Hillebrand 《Environmental Earth Sciences》2018,77(13):516

After completion of an exploration well, sandstones of the Exter Formation were hydraulically tested to determine the hydraulic properties and to evaluate chemical and microbial processes caused by drilling and water production. The aim was to determine the suitability of the formation as a reservoir for aquifer thermal energy storage. The tests revealed a hydraulic conductivity of 1–2 E-5 m/s of the reservoir, resulting in a productivity index of 0.6–1 m³/h/bar. A hydraulic connection of the Exter Formation to the overlaying, artesian “Rupelbasissand” cannot be excluded. Water samples were collected for chemical and microbiological analyses. The water was similarly composed as sea water with a maximum salinity of 24.9 g/L, dominated by NaCl (15.6 g/L Cl and 7.8 g/L Na). Until the end of the tests, the water was affected by drilling mud as indicated by the high pH (8.9) and high bicarbonate concentration (359 mg/L) that both resulted from the impact of sodium carbonate (Na₂CO₃) additives. The high amount of dissolved organic matter (>?58 mg/L) and its molecular-weight distribution pattern indicated that residues of cellulose, an ingredient of the drilling mud, were still present at the end of the tests. Clear evidence of this contamination gave the measured uranine that was added as a tracer into the drilling mud. During fluid production, the microbial community structure and abundance changed and correlated with the content of drilling mud. Eight taxa of sulfate-reducing bacteria, key organisms in processes like bio-corrosion and bio-clogging, were identified. It can be assumed that their activity will be affected during usage of the reservoir.  相似文献   

Ulvöspinel in native iron-bearing assemblages and the origin of these assemblages in basalts from Ovifak,Greenland, and Bühl,Federal Republic of Germany     

Olaf Medenbach  Ahmed ElGoresy 《Contributions to Mineralogy and Petrology》1982,80(4):358-366

Euhedral crystals of ulvöspinel are found in many of the native-iron-bearing xenoliths from the basalt of Bühl near Kassel (West Germany) and Ovifak on Disko Island (West Greenland). The typical assemblage of these xenoliths at both localities is: native Fe, troilite, cohenite, ulvöspinel, ilmenite, olivine, and plagioclase, as well as silicate glass containing droplets of former Fe and troilite melt. The ulvöspinel subsolidus textures and intergrowths also indicate identical cooling histories for the xenoliths in both cases. Ulvöspinel crystallized after the formation of iron, but still above the Fe-FeS eutectic at 988° C. A subsequent strong drop in oxygen fugacity revealed partial breakdown of ulvöspinel according to the reaction .Microprobe analyses of a Bühl xenolith indicate that ulvöspinel contains up to 4.7 w.t.% MnO, while olivine compositions correspond to Fa_64–74Fo_12–24Te_12–15. The entire xenolith contains 1.9 w.t.% MnO. This fact, together with the geological evidence and the occurrence of corroded quartz relicts within some of the xenoliths provides clear evidence for reduction under near-surface conditions in a blast-furnace-like process. The reducing agent was coal from the Tertiary seams cut by the erupting basalt, while the xenolith source material most probably was spherosiderite, which is very common in the coals and would explain the high MnO content. Consequently, the presence of cohenite is not necessarily an indicator of high pressure.The analogies between the Bühl and Ovifak localities and their xenoliths strongly suggest a similar formation through near surface reduction and not derivation from the mantle.  相似文献   

Authigenic sericite record of a fossil geothermal system: the Offenburg trough,central Black Forest,Germany     

Olaf?Brockamp  Norbert?Clauer  Michael?ZutherEmail author 《International Journal of Earth Sciences》2003,92(6):843-851

A fossil geothermal area is hosted by the Carboniferous, Permian and Bunter sandstones of the Offenburg intramontane trough in the central Black Forest. The hydrothermal alteration is identified on the basis of newly formed sericites, which appear as pseudomorphs after feldspar and filling of pore spaces. According to K–Ar dating of sericite, serititization occurred about 145 Ma ago (Jurassic). On the basis of ¹⁸O analyses of sericite, sericite composition and vitrinite reflectance, the hydrothermal fluids had temperatures of 150–210 °C. Because their electrolyte content was low, these fluids are assumed to have derived from meteoric water. A second pulse of electrolyte-rich hydrothermal fluids resulted in quartz overgrowths. Fluid mobilization seems to be linked to the disintegration of Pangaea and to reactivated fault systems extending from the crystalline basement into the intramontane sediments.  相似文献   

Polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans in sediments from Hong Kong   总被引：4，自引：0，他引：4  

Müller JF  Gaus C  Prange JA  Päpke O  Poon KF  Lam MH  Lam PK 《Marine pollution bulletin》2002,45(1-12):372-378

Concentrations of 2,3,7,8-substituted polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs) were determined in 14 sediment samples collected from four sites in the Mai Po Marshes Nature Reserve (within a RAMSAR Site) and from another six sites in Victoria Harbour and along the Hong Kong coastline. Elevated levels of PCDDs, and particularly OCDD, were detectable in all samples collected from the Mai Po Marshes and five of the six sites. In contrast to PCDDs, PCDFs were mainly found in sediment samples collected from industrial areas (Kwun Tong and To Kwa Wan) in Victoria Harbour. PCDD/F levels and congener profiles in the samples from the Mai Po Marshes Nature Reserve in particular show strong similarities to those reported in studies which have attributed similar elevated PCDD concentrations to nonanthropogenic PCDD sources.  相似文献   

Amorphous copper and zinc sulfides in the metalliferous sediments of the Red Sea     

Olaf Brockamp  Evaristo Goulart  Hermann Harder  Annerose Heydemann 《Contributions to Mineralogy and Petrology》1978,68(1):85-88

Detailed studies on the copper and zinc distribution in metalliferous sediments from the Atlantis II Deep (Red Sea) demonstrate that beside chalcopyrite and sphalerite appreciable amounts of copper and zinc are found in X-ray amorphous copper and zinc sulfides not previously described. Only low contents of copper and zinc are present in nontronites, hydroxides and carbonates.  相似文献   

Identification of high energy gamma-ray sources and source populations in the era of deep all-sky coverage     

Olaf Reimer  Diego F. Torres 《Astrophysics and Space Science》2007,309(1-4):57-62

A large fraction of the anticipated source detections by the Gamma-ray Large Area Space Telescope (GLAST-LAT) will initially be unidentified. We argue that traditional approaches to identify individuals and/or populations of gamma ray sources will encounter procedural limitations. Those limitations are discussed on the background of source identifications from EGRET observations. Generally, our ability to classify (faint) source populations in the anticipated GLAST dataset with the required degree of statistical confidence will be hampered by sheer source wealth. A new paradigm for achieving the classification of gamma ray source populations is discussed.  相似文献   

INTEGRAL/XMM views on the MeV source GRO J1411-64     

Diego F. Torres  Shu Zhang  Olaf Reimer  Xavier Barcons  Amalia Corral  Valentí Bosch-Ramon  Josep M. Paredes  Gustavo E. Romero  Jin Qu  Werner Collmar  Volker Schönfelder  Yousaf Butt 《Astrophysics and Space Science》2007,309(1-4):17-21

The COMPTEL unidentified source GRO J 1411-64 was observed by INTEGRAL and XMM-Newton in 2005. The Circinus Galaxy is the only source detected within the 4σ location error of GRO J1411-64, but in here excluded as the possible counterpart. At soft X-rays, 22 reliable and statistically significant sources (likelihood >10) were extracted and analyzed from XMM-Newton data. Only one of these sources, XMMU J141255.6-635932, is spectrally compatible with GRO J1411-64 although the fact the soft X-ray observations do not cover the full extent of the COMPTEL source position uncertainty make an association hard to quantify and thus risky. At the best location of the source, detections at hard X-rays show only upper limits, which, together with MeV results obtained by COMPTEL suggest the existence of a peak in power output located somewhere between 300–700 keV for the so-called low state. Such a spectrum resembles those in blazars or microquasars, and might suggest at work by the models accordingly. However, an analysis using a microquasar model consisting on a magnetized conical jet filled with relativistic electrons, shows that it is hard to comply with all observational constrains. This fact and the non-detection at hard X-rays introduce an a-posteriori question mark upon the physical reality of this source, what is discussed here.  相似文献   

Autochthonous block fields in southern Norway: Implications for the geometry,thickness, and isostatic loading of the Late Weichselian Scandinavian ice sheet     

Atle Nesje  Svein Olaf Dahl 《第四纪科学杂志》1990,5(3):225-234

The consistent geographical and altitudinal distribution of autochthonous block fields (mantle of bedrock weathered in situ) and trimlines in southern Norway suggests a multi-domed and asymmetric Late Weichselian ice sheet. Low-gradient ice-sheet profiles in the southern Baltic region, in the North Sea, and along the outer fjord areas of southern Norway, are best explained by movement of ice on a bed of deforming sediment, although water lubricated sliding or a combination of the two, may not be excluded. The ice-thickness distribution of the Late Weichselian Scandinavian ice sheet is not in correspondence with the modern uplift pattern of Fennoscandia. Early Holocene crustal rebound was apparently determined by an exponential, glacio-isostatic rise. Later, however, crustal movements appear to have been dominated by large-scale tectonic uplift of the Fennoscandian Shield, centred on the Gulf of Bothnia, the region of maximum lithosphere thickness.  相似文献   

A new particulate Mn-Fe-P-shuttle at the redoxcline of anoxic basins   总被引：1，自引：0，他引：1  

Olaf Dellwig  Thomas Leipe  Michael Glockzin  Bernhard Schnetger  Michael E. Böttcher 《Geochimica et cosmochimica acta》2010,74(24):7100-7115

Pelagic redoxclines of anoxic basins and deeps form the suboxic transition between oxygenated surface and anoxic or even sulfidic bottom waters. Intense element cycling, favoured by elevated microbial activity, causes steep gradients of physico-chemical parameters, nutrients and redox-sensitive trace metals. This study presents a conceptual model for authigenic particle formation at pelagic redoxclines, which is based on the tight coupling of Mn, Fe, and P cycles. Besides the well-known occurrence of Mn-oxides, textural (SEM-EDX) and geochemical (ICP-OES, ICP-MS) analyses of particles from the redoxclines of the Black Sea and the Baltic Sea (Gotland Basin, Landsort Deep) evidence the existence of earlier postulated Fe-oxyhydroxo-phosphates and emphasize mixed phases consisting of Mn-oxides and Fe-oxyhydroxo-phosphates as a new solid species. Most of the analyzed particles are star-shaped, of about 5 μm in size, and occur as single particles or aggregates without any morphological differences between Mn-oxides, Fe-oxyhydroxo-phosphates, and mixed phases. Throughout the redoxcline, these minerals show a general succession with maximum abundance of Mn-oxides above the redoxcline followed by mixed phases and almost pure Fe-phosphates within and below the redoxcline, respectively. Molar Fe/P ratios of single particles argue against the formation of known pure Fe-phosphates like vivianite or strengite at the lower end of the redox transition zone, but are consistent with recent experimental findings for colloidal P-bearing hydrous ferric oxides. Moreover, morphological similarities suggest the formation of irregular Fe-oxyhydroxo coatings due to oxidation of upward diffusing Fe²⁺ by oxygen and stepwise replacement of Mn(IV) by Fe(III) on sinking MnO_x particles followed by immediate adsorption or even co-precipitation of phosphate. Batch-type experiments using biogenic MnO_x particles demonstrate the efficient potential of Fe²⁺ oxidation by sinking MnO_x particles. When entering sulfidic waters MnO_x particles are progressively reduced leading to an increasing relative abundance of Fe- and P-rich particles. In deeper parts of the water column these particles are also reductively dissolved, thereby releasing Fe²⁺ and phosphate to the water column. This Mn-Fe-P-shuttle likely affects phosphate transport throughout the water column and thus impacts primary production at least over longer time scales. Furthermore, the particulate Mn-Fe-P-shuttle must have played an important role for the cycling of P and certain trace metals in ancient ocean basins, e.g., during certain periods of Cretaceous black shale formation and should be considered in future mass balances and modeling approaches dealing with oxic/anoxic interfaces of aquatic ecosystems.  相似文献