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31.
32.
Distinctive uptake mechanisms of different radiotracers by red clays in seawater are elucidated from the magnitude and change of distribution coefficients (Kd) for up to 17 γ-emitting radiotracers as functions of equilibration time, suspended particle concentration and compositions of solids and seawaters. The adsorption of ionic metals onto colloids and subsequent coagulation of colloids onto larger particles are the dominant removal processes of metals in the aquatic environments of low suspended particle concentration.  相似文献   
33.
The manner in which small channels are generated, from plane beds beneath sheet flows, has been experimentally elucidated. On plane, erodible, sand beds, the transition from thin, supercritical sheet flows to the channelled condition was studied over ranges of discharge, slope, and temperature. Secondary flow of the second kind, its action facilitated by steep vertical velocity gradients in the primary flows, caused sheet-flow instability. Along junctions between neighbouring secondary cells, both either raised or lowered elements of the primary flow. In the latter case, fast surface water was lowered to the bed, causing relatively intense, local, longitudinal scour. Dislodged grains were moved divergently to either side, leaving straight, central trenches. Development of positive feedback between cells and trenches led to rapid enlargement of the latter and concomitant growth of paired levees. The resulting structures, ‘protochannels’, were themselves ephemeral, developing two types of instability associated with secondary flow of the first kind. Firstly, small deviations from bilateral symmetry were enhanced, causing evolution into meandering channels. Secondly, headcutting led to multiple tributary development and, at resulting confluences, the action of strong pairs of secondary cells led to the development of braiding channels. Because they are shortlived, protochannels are but rarely seen in nature. Their seeding is markedly temperature-sensitive, reflecting their frictional origin. The erosive power of shallow overland flow largely depends on flow-energy concentration by secondary flow, firstly into channels, then within the channels themselves. Suppression of secondary flow, as by intense raindrop bombardment, can stabilize sheet flows. In deeper water, the effects of secondary flow appear relatively less dramatic. However, even if such motion is weak, bedload divergence from attachment lines can favour entrainment locally and thus affect bed geometry. Analogy between our results and river behaviour appears close and. on continental shelves where water must often flow as sheets, structures resembling giant protochannels evidently persist.  相似文献   
34.
From 2002 through 2004, time-series sediment trap samples were collected from a depth of 410 m in Cuenca Alfonso, Bahía de La Paz, on the SW coast of the Gulf of California. The instrument recorded the impact of the local passage of hurricanes “Ignacio” (24–26 August) and “Marty” (21–23 September) in 2003. These two events accounted for 82% of the total rainfall measured in 2003, equivalent to the annual average precipitation in years without hurricanes. Mean total mass fluxes (TMFs) of 2.88 and 3.58 g m−2 d−1 were measured during the week of each hurricane as well as the following week. This may have been enough to produce a lamina in the underlying sediment with characteristics peculiar to such events. The terrigenous component was particularly abundant, with notably higher concentrations of Fe, Sc, Co and Cs and REEs. In contrast, TMFs throughout 2002–2004 (excluding the hurricane periods) averaged only 0.73 g m−2 d−1 and had a larger marine biogenic component. The extraordinary elemental fluxes during the 29 days of hurricane-influenced sedimentation represented a great proportion of the totals over an entire “normal” year: Co (67.8%) >Sc (62.6) >Fe (59.6) >Cs (53.4)>Lu (51.5)>La (51.3)>Yb (51.0)>Ce (49.5) >Tb (48.4) >Sm (44.7)>Cr (36.5) >Ca (31.0)>Eu (25.4%). The terrigenous fraction was calculated using (a) TMF minus the sum of CaCO3, biogenic silica and organic matter and (b) the ratio of Sc in the trap samples to the average in the Earth's crust. The latter was consistently smaller, but the two methods offered similar results following hurricanes (78% vs. 63%, respectively). For normal sedimentation, however, the difference method yielded values twice as large as the Sc method (58% vs. 30%) This suggests that the mineralogy of the terrigenous fraction may also vary, with unsorted dessert soil being carried to sea by the powerful flash floods associated with hurricanes. Eolian supply of particles, particularly Sc-free quartz grains, possibly from beyond the limited fluvial drainage basin, apparently dominates normal sedimentation.  相似文献   
35.
Guagua Pichincha, located 14 km west of Quito, Ecuador, is a stratovolcano bisected by a horseshoe-shaped caldera. In 1999, after some months of phreatic activity, Guagua Pichincha entered into an eruptive period characterized by the extrusion of several dacitic domes, vulcanian eruptions, and pyroclastic flows. We estimated the three-dimensional (3-D) P-wave velocity structure beneath Guagua Pichincha using a tomographic inversion method based on finite-difference calculations of first-arrival times. Hypocenters of volcano-tectonic (VT) earthquakes and long-period (LP) events were relocated using the 3-D P-wave velocity model. A low-velocity anomaly exists beneath the caldera and may represent an active volcanic conduit. Petrologic analysis of eruptive products indicates a magma storage region beneath the caldera, having a vertical extent of 7–8 km with the upper boundary at about sea level. This zone coincides with the source region of deeper VT earthquakes, indicating that a primary magma body exists in this region. LP swarms occurred in a cyclic pattern synchronous with ground deformation during magma extrusions. The correlation between seismicity and ground deformation suggests that both respond to pressure changes caused by the cyclic eruptive behavior of lava domes.  相似文献   
36.
Previous research by our group (e.g., [Chem. Geol. 132 (1996) 25; Geochim. Cosmochim. Acta 64 (2000) 1363]) has shown that an aerobic Pseudomonas mendocina bacterium enhances Fe(hydr)oxide dissolution in order to obtain Fe under Fe-limited conditions. The P. mendocina is incapable of utilizing Fe as a terminal electron acceptor and requires several orders of magnitude lower Fe concentrations than do dissimilatory Fe reducing bacteria. The research reported here compared the effects of the P. mendocina on dissolution of well and poorly ordered Clay Minerals Society Source Clay kaolinites KGa-1b and KGa-2, respectively, under Fe-limited conditions. KGa-1b and KGa-2 contain 0.04 and 0.94 bulk wt.% Fe, respectively, and their surface Fe/Si atomic RATIOS=0.008 and 0.012. Following strong cleaning of the kaolinites in 5.8 M HCl at 85 °C, the surface Fe/Si atomic ratios decreased to 0.004 and 0.008, respectively. Both kaolinites also developed a Si-enriched surface precipitate upon strong cleaning.

Because the P. mendocina take up Fe, we could not measure Fe release from the kaolinite directly, but rather had to monitor it indirectly by comparing microbial populations sizes under Fe-limited growth conditions. We found that microbial growth on uncleaned, weakly cleaned, and strongly cleaned kaolinites increased with the amount of Fe readily available to organic ligands as estimated by dissolution in 0.001 M oxalate (pH 3). This suggests that it is the amount of readily accessible Fe that controls Fe acquisition and hence microbial growth. The trend is based on only a relatively small range of kaolinite Fe contents, and the research thus needs to be expanded to include kaolinites with a broader range of bulk and surface Fe concentrations.

Significant enhancement of Al release was observed in the presence of the bacteria, along with generally some enhancement of Si release. This enhancement of kaolinite dissolution could be related to an observed pH increase from 7–8 to 9 in the presence of the bacteria and/or to production of Al chelating agents. The P. mendocina produce a variety of organic exudates, including siderophores [Chem. Geol. 132 (1996) 25; Geomicrobiology (2001b)], and further studies into the effects of the siderophores on Al complexation and on kaolinite dissolution are ongoing.  相似文献   

37.
Scales of nutrient-limited phytoplankton productivity in Chesapeake Bay   总被引:1,自引:0,他引:1  
The scales on which phytoplankton biomass vary in response to variable nutrient inputs depend on the nutrient status of the plankton community and on the capacity of consumers to respond to increases in phytoplankton productivity. Overenrichment and associated declines in water quality occur when phytoplankton growth rate becomes nutrient-saturated, the production and consumption of phytoplankton biomass become uncoupled in time and space, and phytoplankton biomass becomes high and varies on scales longer than phytoplankton generation times. In Chesapeake Bay, phytoplankton growth rates appear to be limited by dissolved inorganic phosphorus (DIP) during spring when biomass reaches its annual maximum and by dissolved inorganic nitrogen (DIN) during summer when phytoplankton growth rates are highest. However, despite high inputs of DIN and dissolved silicate (DSi) relative to DIP (molar ratios of N∶P and Si∶P>100), seasonal accumulations of phytoplankton biomass within the salt-intruded-reach of the bay appear to be limited by riverine DIN supply while the magnitude of the spring diatom bloom is governed by DSi supply. Seasonal imbalances between biomass production and consumption lead to massive accumulations of phytoplankton biomass (often>1,000 mg Chl-a m?2) during spring, to spring-summer oxygen depletion (summer bottom water <20% saturation), and to exceptionally high levels of annual phytoplankton production (>400 g m?2 yr?1). Nitrogen-dependent seasonal accumulations of phytoplankton biomass and annual production occur as a consequence of differences in the rates and pathways of nitrogen and phosphorus cycling within the bay and underscore the importance of controlling nitrogen inputs to the mesohaline and lower reaches of the bay.  相似文献   
38.
Sediments from Rapid Lake document glacial and vegetation history in the Temple Lake valley of the Wind River Range, Wyoming over the past 11,000 to 12,000 yr. Radiocarbon age determinations on basal detrital organic matter from Rapid Lake (11,770 ± 710 yr B.P.) and Temple Lake (11,400 ± 630 yr B.P.) bracket the age of the Temple Lake moraine, suggesting that the moraine formed in the late Pleistocene. This terminal Pleistocene readvance may be represented at lower elevations by the expansion of forest into intermontane basins 12,000 to 10,000 yr B.P. Vegetation in the Wind River Range responded to changing environmental conditions at the end of the Pleistocene. Following deglaciation, alpine tundra in the Temple Lake valley was replaced by a Pinus albicaulis parkland by about 11,300 14C yr B.P. Picea and Abies, established by 10,600 14C yr B.P., grew with Pinus albicaulis in a mixed conifer forest at and up to 100 m above Rapid Lake for most of the Holocene. Middle Holocene summer temperatures were about 1.5°C warmer than today. By about 5400 14C yr B.P. Pinus albicaulis and Abies became less prominent at upper treeline because of decreased winter snowpack and higher maximum summer temperatures. The position of the modern treeline was established by 3000 14 C yr B.P. when Picea retreated downslope in response to Neoglacial cooling.  相似文献   
39.
Regional studies of Sq variations measured at five permanent observatories in Argentina were performed to estimate the distribution of the electrical conductivity of the upper and mid-mantle, reaching a depth of approximately 800 km. After separating the total field into its parts of external and internal origin, the in duced field was modeled, applying two-dimensional techniques. Additionally, induction arrows and an equivalent apparent resistivity curve were calculated A north-south heterogeneity was detected, showing an increase of the conductivity of the shallower layers north of the profile, which may be related to the presence of high volcanic activity in the area.Also at CONICET (Consejo Nacional de Investigaciones Científicas y Técnicas).  相似文献   
40.
Increased divorce, declining fertility and mortality, and changing lifestyles have resulted in a consistent decline in average household size in U.S. urban areas. The purpose of this paper is to show that decreases in household size between 1970 and 1975 were spatially variable in metropolitan Phoenix and that this affected the overall pattern of residential density. This is demonstrated by a series of maps depicting average household size in 1970, changes therein between 1970 and 1975, and the relationships between changes in population, numbers of dwelling units, and household size in the study area.  相似文献   
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