Laboratory kinetics of C₂H radical reactions with ethane, propane, and n-butane at T = 96-296 K: implications for Titan     

James E. Murphy  Stephen R. Leone 《Icarus》2003,163(1):175-181

The kinetics of the reactions of C₂H radical with ethane (k₁), propane (k₂), and n-butane (k₃) are studied over the temperature range of T = 96-296 K with a pulsed Laval nozzle apparatus that utilizes a pulsed laser photolysis-chemiluminescence technique. The C₂H decay profiles in the presence of both the alkane reactant and O₂ are monitored by the CH(A²Δ) chemiluminescence tracer method. The results, together with available literature data, yield the following Arrhenius expressions: k₁(T) = (0.51 ± 0.06) × 10⁻¹⁰ exp[(−76 ± 30)K/T] cm³ molecule⁻¹ s⁻¹ (T = 96-800 K), k₂(T) = (0.98 ± 0.32) × 10⁻¹⁰exp[(−71 ± 60)K/T] cm³ molecule⁻¹ s⁻¹ (T = 96-361 K), and k₃(T) = (1.23 ± 0.26) × 10⁻¹⁰ cm³ molecule⁻¹ s⁻¹ (T = 96-297 K). At T = 296 K, k₁ is measured as a function of total pressure and has little or no pressure dependence. The results from this work support a direct hydrogen abstraction mechanism for the title reactions. Implications to the atmospheric chemistry of Titan are discussed.  相似文献   

Ghosts of the Milky Way: a search for topology in new quasar catalogues     

S. J. Weatherley  S. J. Warren  S. M. Croom  R. J. Smith  B. J. Boyle  T. Shanks  L. Miller  M. P. Baltovic 《Monthly notices of the Royal Astronomical Society》2003,342(1):L9-L13

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Planar deformation features and impact glass in inclusions from the Vredefort Granophyre,South Africa     

P. C. Buchanan  W. U. Reimold 《Meteoritics & planetary science》2002,37(6):807-822

Abstract— The Vredefort Granophyre represents impact melt that was injected downward into fractures in the floor of the Vredefort impact structure, South Africa. This unit contains inclusions of country rock that were derived from different locations within the impact structure and are predominantly composed of quartzite, feldspathic quartzite, arkose, and granitic material with minor proportions of shale and epidiorite. Two of the least recrystallized inclusions contain quartz with single or multiple sets of planar deformation features. Quartz grains in other inclusions display a vermicular texture, which is reminiscent of checkerboard feldspar. Feldspars range from large, twinned crystals in some inclusions to fine‐grained aggregates that apparently are the product of decomposition of larger primary crystals. In rare inclusions, a mafic mineral, probably biotite or amphibole, has been transformed to very fine‐grained aggregates of secondary phases that include small euhedral crystals of Fe‐rich spinel. These data indicate that inclusions within the Vredefort Granophyre were exposed to shock pressures ranging from <5 to 8–30 GPa. Many of these inclusions contain small, rounded melt pockets composed of a groundmass of devitrified or metamorphosed glass containing microlites of a variety of minerals, including K‐feldspar, quartz, augite, low‐Ca pyroxene, and magnetite. The composition of this devitrified glass varies from inclusion to inclusion, but is generally consistent with a mixture of quartz and feldspar with minor proportions of mafic minerals. In the case of granitoid inclusions, melt pockets commonly occur at the boundaries between feldspar and quartz grains. In metasedimentary inclusions, some of these melt pockets contain remnants of partially melted feldspar grains. These melt pockets may have formed by eutectic melting caused by inclusion of these fragments in the hot (650 to 1610 °C) impact melt that crystallized to form the Vredefort Granophyre.  相似文献   

An analytical representation of non-gyrotropic distributions and related space applications     

M.P. Leubner 《Planetary and Space Science》2003,51(12):723-729

Clear signature of non-gyrotropic energetic electron distributions was found by ISEE 1 and ISEE 2 spacecrafts just upstream of the Earth's bow shock and recently detected by in situ observations of the WIND plasma experiment. On the other hand, the appearance of non-gyrotropic ion velocity distributions is well established in the magnetotail providing evidence of magnetic reconnection processes. Motivated by these findings we introduce an analytical representation of non-Maxwellian/non-gyrotropic distribution functions, accurately fitting the characteristics of observations, where Maxwellians are recovered as special case of these highly general velocity space distributions. In particular, the analytical distribution function model can serve as basis of detailed wave-particle interaction analysis and of studies of the physical background of the evolution of both, non-gyrotropic electron and ion distributions, which is discussed for various space plasma environments.  相似文献   

Isolation of resonance in acoustic backscatter from elastic targetsusing adaptive estimation schemes     

Azimi-Sadjadi  M.R. Wilbur  J. Dobeck  G.J. 《Oceanic Engineering, IEEE Journal of》1995,20(4):346-353

It has been shown that at certain frequencies the acoustic backscatter from elastic targets exhibits certain resonance behavior which closely relates to the physical properties of the target such as dimension, thickness, and composition. The purpose of this paper is to develop an automated approach for identifying the presence of resonance in the acoustic backscatter from an unknown underwater target by isolating the resonance part from the specular contribution. An adaptive transversal filter structure is used to estimate the specular part of the backscatter and consequently the error signal would provide an estimate of the resonance part. An important aspect of this scheme lies in the fact that it does not require an underlying model for the elastic return. The adaptation rule is based upon fast recursive least squares (RLS) learning. The approach taken in this paper is general in the sense that it can be applied to targets of unknown geometry and thickness and, further, does not require any a priori information about the target and/or the environment. Test results on acoustic data are presented which indicate the effectiveness of the proposed approach  相似文献   

Radial velocity searches for other planetary systems:Current status and future prospects     

W. D. Cochran  A. P. Hatzes 《Astrophysics and Space Science》1996,241(1):43-60

Measurement of variations in the radial velocities of stars due to the reflex orbital motion of the star around the planetary-system barycenter constitutes a powerful method of searching for substellar or planetary mass companions. After several years of patient data acquisition, radial-velocity searches for planetary systems around other stars are now beginning to bear fruit. In late 1995 and early 1996, three candidate systems were announced with Jovian-mass planets around solar-type stars. The current paradigm for low-mass star formation suggests that planetary systems should be able to form in the circumstellar disks surrounding young stellar objects. These newly discovered systems, and other discoveries which will soon follow them, will test critically our understanding of the processes of star- and planet-formation. We review the techniques used in these radial-velocity searches and their results to date. We then discuss planned improvements in the surveys, and the prospects for the next 20 years.  相似文献   

The MPE X-ray test facility PANTER: Calibration of hard X-ray (15–50 kev) optics     

M. J. Freyberg  H. Bräuninger  W. Burkert  G. D. Hartner  O. Citterio  F. Mazzoleni  G. Pareschi  D. Spiga  S. Romaine  P. Gorenstein  B. D. Ramsey 《Experimental Astronomy》2005,20(1-3):405-412

The Max-Planck-Institut für extraterrestrische Physik (MPE) in Garching, Germany, uses its large X-ray beam line facility PANTER for testing X-ray astronomical instrumentation. A number of telescopes, gratings, filters, and detectors, e.g. for astronomical satellite missions like Exosat, ROSAT, Chandra (LETG), BeppoSAX, SOHO (CDS), XMM-Newton, ABRIXAS, Swift (XRT), have been successfully calibrated in the soft X-ray energy range (< 15keV). Moreover, measurements with mirror test samples for new missions like ROSITA and XEUS have been carried out at PANTER. Here we report on an extension of the energy range, enabling calibrations of hard X-ray optics over the energy range 15–50 keV. Several future X-ray astronomy missions (e.g., Simbol-X, Constellation-X, XEUS) have been proposed, which make use of hard X-ray optics based on multilayer coatings. Such optics are currently being developed by the Osservatorio Astronomico di Brera (OAB), Milano, Italy, and the Harvard-Smithsonian Center for Astrophysics (CfA), Cambridge, MA, USA. These optics have been tested at the PANTER facility with a broad energy band beam (up to 50 keV) using the XMM-Newton EPIC-pn flight spare CCD camera with its good intrinsic energy resolution, and also with monochromatic X-rays between C-K (0.277 keV) and Cu-Kα (8.04 keV). PACS: 95.55.Ka, 95.55.Aq, 41 50.+h, 07.85.Fv  相似文献   

A robust sample of submillimetre galaxies: constraints on the prevalence of dusty, high-redshift starbursts     

R. J. Ivison  Ian Smail  J. S. Dunlop  T. R. Greve  A. M. Swinbank  J. A. Stevens  A. M. J. Mortier  S. Serjeant  T. A. Targett  F. Bertoldi  A. W. Blain  S. C. Chapman 《Monthly notices of the Royal Astronomical Society》2005,364(3):1025-1040

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Five WC9 stars discovered in the AAO/UKST Hα survey     

E. C. Hopewell  M. J. Barlow  J. E. Drew  Y. C. Unruh  Q. A. Parker  M. J. Pierce  P. A. Crowther  C. Knigge  S. Phillipps  A. A. Zijlstra 《Monthly notices of the Royal Astronomical Society》2005,363(3):857-866

We report the discovery of five massive Wolf–Rayet (WR) stars resulting from a programme of follow-up spectroscopy of candidate emission-line stars in the Anglo-Australian Observatory United Kingdom Schmidt Telescope (AAO/UKST) Southern Galactic Plane Hα survey. The 6195–6775 Å spectra of the stars are presented and discussed. A WC9 class is assigned to all five stars through comparison of their spectra with those of known late-type WC stars, bringing the known total number of Galactic WC9 stars to 44. Whilst three of the five WC9 stars exhibit near-infrared (NIR) excesses characteristic of hot dust emission (as seen in the great majority of known WC9 stars), we find that two of the stars show no discernible evidence of such excesses. This increases the number of known WC9 stars without NIR excesses to seven. Reddenings and distances for all five stars are estimated.  相似文献   

A Chandra view of the multiple merger in Abell 2744     

Joshua C. Kempner  Laurence P. David 《Monthly notices of the Royal Astronomical Society》2004,349(2):385-392

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