The preparation and characterization of vanadium-substituted goethite: The importance of temperature     

Navdeep Kaur  Brendan J. Kennedy 《Geochimica et cosmochimica acta》2009,73(3):582-9557

Despite a close geo-chemical association between vanadium (V) and iron (Fe) in natural environments, there is little research on the substitution of V in goethite. To assess the effect of temperature on V-substitution in goethite, a series of V-substituted goethite were prepared under varying synthesis temperatures, and analysed using wet chemical and multi-spectroscopic techniques. Vanadium substitution was inversely related to synthesis temperatures and was hindered by the oxidation of V³⁺ to V^4+/5+ as indicated by X-ray absorption near-edge spectroscopy. The presence of V (V⁵⁺ > V⁴⁺ > V³⁺) at high temperature hindered the nucleation of goethite and crystal growth along particular faces resulting in large-sized and twinned crystals as shown by transmission electron microscopy. The large-sized goethite crystals released more Fe (mmoles) per unit surface area during proton-promoted dissolution than the smaller-sized crystals, which could be due to distorted V^4+/5+ local coordination environments in the mineral structure. The dissolution studies showed a heterogeneous distribution of V and/or crystal defects in goethite crystals. The results show that low synthesis temperatures preserved the oxidation state of V³⁺, which has ionic radius and hydrolytic properties similar to Fe³⁺, and hence resulted in as much as 13.3 mol per cent substitution. The structural stability of the goethite decreased upon V-substitution in order; V³⁺ > V⁴⁺ > V⁵⁺. This research provides important information about the interaction between temperature, V incorporation, and crystal structure properties of goethite for V sequestration and other potentially toxic metal cations.  相似文献   

Origin of trondhjemite and albitite at the expense of A-type granite,Aravalli orogen,India:Evidence from new metasomatic replacement fronts     

Parampreet Kaur  Naveen Chaudhri  Nusrat Eliyas 《地学前缘(英文版)》2019,10(5):1891-1913

The A-type Harsora-Dadikar granites in the Alwar complex of northern Aravalli orogen,NW India provide evidence for subsolidus-requilibration of feldspars.They record three new discrete stages of albitisation,producing trondhjemite and albitite sequentially at the expense of original granite.Stage-Ⅰ metasomatism deanorthised the magmatic oligoclase and transformed the grey least-albitised granite to pinkish grey microcline-oligoclase granite.Stage-II converted the latter to trondhjemite by replacement of microcline to oligoclase.Stage-Ⅲ metasomatism led to the formation of albitite/albite granite from trondhjemite,where the metasomatically formed oligoclase was replaced by albite.This stage of metasomatism resulted in nearly complete disappearance of amphibole and biotite,producing a monomineralic rock(albitite),which is consistent with Korzhinskii theory of infiltration metasomatism.The reaction fronts delineating the Stage-Ⅱ and Stage-Ⅲ are sharp and easily discernible by their prominent color differences in Harsora on the outcrop scale.Chemically,the mineral transformations during three stages are manifested by the differential gains/losses in Na,K,Ca,Rb,Ba,Sr,Fe and Mg.The formation of albite,Cl-rich marialitic scapolite and Cl-rich amphibole in the albitised granites are suggestive of Naand Cl-brines as the metasomatising fluids.The fluid-rock interactions,which can significantly transform the pristine mineralogy of granitoids,should be carefully considered to avoid any misinterpretations about their petrological history.  相似文献   

Water chemistry of Mansar Lake (India): an indication of source area weathering and seasonal variability   总被引：2，自引：0，他引：2  

Ahmed?S.?Al-Mikhlafi  Brijraj?K.?DasEmail author  Parkash?Kaur 《Environmental Geology》2003,44(6):645-653

The chemistry of major elements (Ca, Mg, Na, K and Si) and anions (HCO ₃, SO ₄ and Cl) in the water of Mansar Lake was studied, based on seasonal data. The results show that total dissolved solid (TDS) concentration in a particular season is similar, but varies slightly in different seasons with a variation factor of less than 2. This is because the collections were made in the dry seasons and the Ca-precipitation is the cause for the seasonal variability. The major element chemistry of Mansar Lake is mainly controlled by rock weathering, with HCO ₃ and Ca dominating the major ion composition because of the abundance of carbonate rocks in the basin. The results also indicate that the lake water is saturated with respect to calcite and/or dolomite during the spring season whereas it is undersaturated in the summer season. This contrast brings out seasonal variability. The lake shows disequilibrium with atmospheric CO ₂ as a result of carbonate dissolution in the drainage basin. The study also shows that physical weathering/erosion is dominant and that chemical weathering is incipient. This is consistent with the Chemical Index of Alteration (CIA) data.  相似文献   

Observations on the Abiotic Factors and Planktonic Periodicity in a Shallow Pond of the Highlands of Shillong (India)     

S. A. K. Nasar  S. Kaur 《洁净——土壤、空气、水》1982,10(2):167-175

The pond, situated at an altitude of 4862 m, shows an annual variation of temperature between 15 and 27 °C in a close correlation with the air temperature. In the case of a weakly acidic reaction of water an inverse relation exists between pH and conductivity and between free CO₂ and alkalinity. The nutrient content of 0.05 mg/l PO₄-P and NO₃-N each is low, the phosphorus concentration being maintained by re-solution from the sediment. Chlorophyceae and diatoms are dominant in the phytoplankton alternately, and rotatoria and copepoda are dominant in the zoo-plankton in winter and in summer, respectively. The pronounced changes in the composition of plankton do not show any definite dependence on the physico-chemical factors, particularly since a significant share of the nutrient metabolism and the oxygen balance in the pond investigated is determined by macrophytes.  相似文献   

Structural set up in northern part of Kumaun Himalaya     

L S Chamyal  Manudip Kaur 《Journal of Earth System Science》1994,103(1):37-46

The Main Central Thrust (MCT) and the Main Boundary Thrust (MBT) are the two major thrusts in Kumaun, the MCT forming the boundary between highly sheared, deformed and mylonitized rocks of the Great Himalayan Central Crystallines and the Lesser Himalayan metasedimentaries. While in the Central Crystallines four-folding episodes are observed of which two are of the Precambrian age, the Lesser Himalayan rocks show only two phases of folding. MCT has its own distinctive structural history and the crystalline mass comprises an integral part of peninsular India.  相似文献   

Geochemistry of Mansar Lake sediments, Jammu, India: Implication for source-area weathering, provenance, and tectonic setting   总被引：5，自引：0，他引：5  

Brijraj K. Das  A.S. AL-Mikhlafi  P. Kaur 《Journal of Asian Earth Sciences》2006,26(6):649-668

The sediment geochemistry, including REE, of surface and core samples from Mansar Lake, along with mineralogical investigations, have been carried out in order to understand the provenance, source area weathering, hydrolic sorting and tectonic setting of the basin. The geochemical signatures preserved in these sediments have been exploited as proxies in order to delineate these different parameters.The major element log values (Fe₂O₃/K₂O) vs (SiO₂/Al₂O₃) and (Na₂O/K₂O) vs (SiO₂/Al₂O₃) demarcate a lithology remarkably similar to that exposed in the catchment area. The chondrite normalized REE patterns of lake samples are similar to Post Archaean Australian Shale (PAAS) with LREE enrichment, a negative Eu anomaly and almost flat HREE pattern similar to a felsic and/or cratonic sedimentary source. However, the La–Th–Sc plot of samples fall in a mixed sedimentary domain, close to Upper Continental Crust (UCC) and PAAS, suggesting sedimentary source rocks for the Mansar detritus. It also indicates that these elements remained immobile during weathering and transportation. The mineralogical characteristic, REEs, and high field strength elements (HFSE), together with the high percentage of metamorphic rock fragments in the Siwalik sandstone, support a metamorphic source for lower Siwalik sediments. A very weak positive correlation between Zr and SiO₂, poor negative correlation with Al₂O₃, negative correlation of (La/Yb)_N and (Gd/Yb)_N ratios with SiO₂ and positive correlation with Al₂O₃, suggest that Zr does not dominantly control the REE distribution in Mansar sediments. The petrographic character and textural immaturity indicate a short distance transport for the detritus. The distribution of elements in core samples reflect fractionation. The higher Zr/Th and Zr/Yb ratios in coarse sediments and PAAS compared to finer grained detritus indicate sedimentary sorting. Plots of the geochemical data on tectonic discrimination diagrams suggest that the sediments derived from the lower Siwalik were originated within a cratonic interior and later deposited along a passive margin basinal setting. It therefore reveals lower Siwalik depositional history.  相似文献   

Integrated geospatial,geostatistical, and remote-sensing approach to estimate groundwater level in North-western India   总被引：1，自引：0，他引：1  

Lakhvinder Kaur  Madhuri S. Rishi 《Environmental Earth Sciences》2018,77(23):786

The depletion of groundwater resources in Northwest India has been extensively studied. The top priority to meet the scarcity of water for irrigation, industrial and domestic purposes is supplemented by groundwater. Geostatistical modelling approach is considered to be beneficial tool for the assessment, evaluation, monitoring, and management of groundwater resources. This study is an attempt to analyze the spatio-temporal variability of groundwater level in semi-arid region of Panipat district, Haryana, India using kriging technique to fill the data gaps. Ordinary kriging was found optimal for the interpolation of groundwater levels. The results revealed that there was not much seasonal variation and also the groundwater flow direction remained almost constant in the study area during the assessment period. Spatial variability analysis showed significant variation in groundwater level and further depicted that the study area had undergone more or less decline in groundwater over the period of time. To validate the observations and results geo spatial and remote sensing techniques including normalised difference vegetation index and impervious surface relationships were worked out. It was further co-related with the rainfall data and the canal network existing in Panipat region. The integrated approach substantiated the observed results with the ground reality and helped in better understanding of the causes of declining groundwater trend in central part of Panipat.  相似文献   

Silting patterns in the reservoirs of small- and medium-sized earthen check dams in humid subtropical monsoon regions     

Ranbir S. Kang  Elizabeth Chacko  Dhian Kaur  Roger Viadero 《地球表面变化过程与地形》2019,44(13):2638-2648

Silting of reservoirs is a ubiquitous process whenever water is impounded. Despite substantial work on the rates of silting, the spatial pattern of silting in reservoirs is not clearly understood. While it is anticipated that the variability of silting increases with decreasing reservoir size, not much is known about siltation in subtropical humid regions affected by monsoon rainfall. This paper presents the initial results of geomorphic analysis of six earthen check dams in the Shiwalik foothills of the Himalayas (India) in areas that are inhabited by high proportions of disempowered populations. These check dams include three small-sized dams (Dhamala-II, Rel Majra and Sukhomajri-II) and three medium-sized dams (Bunga-I, Parachh-II and Siswan). Field data were collected from each reservoir. The methods used included spatial interpolations of bed depth and silt thickness in each reservoir, Structure from Motion photogrammetry to extract multiple channel cross-sections from photographic scans along tributary mouths, texture analysis of bed and bank materials, and visual observations of hill slopes around the check dams. Based on this study, silt tended to concentrate either in the middle portion of the reservoir or near the dam; however, silt accumulation did not always occur along the dam or in the deepest portion of the reservoirs. Areas located downstream from these check dams are heavily used for various human activities and the channel network has almost been eliminated. While these earthen check dams may be cost-effective tools for water conservation in economically marginalized areas, if abandoned, these structures may pose a physical hazard to downstream communities. © 2019 John Wiley & Sons, Ltd. © 2019 John Wiley & Sons, Ltd.  相似文献   

Installation of solar chromospheric telescope at the Indian Astronomical Observatory,Merak     

B. Ravindra  Prabhu Kesavan  K. C. Thulasidharen  M. Rajalingam  K. Sagayanathan  P. U. Kamath  Namgyal Dorjey  Angchuk Dorjee  P. M. M. Kemkar  Tsewang Dorjai  Ravinder K. Banyal 《Journal of Astrophysics and Astronomy》2018,39(5):60

We report the observations of the solar chromosphere from a newly commissioned solar telescope at the incursion site near Pangong Tso lake in Merak (Leh/Ladakh). This new \(\hbox {H}_{\alpha }\) telescope at the Merak site is identical to the Kodaikanal \(\hbox {H}_{\alpha }\) telescope. The telescope was installed in the month of August 2017 at the Merak site. The telescope consists of a 20-cm doublet lens with additional re-imaging optics. A Lyot filter with 0.5 Å passband isolates the Balmer line of the hydrogen spectra to make the observations of the solar chromosphere. The observations made in \(\hbox {H}_{\alpha }\) wavelength delineates the magnetic field directions at the sunspot and the quiet regions. A CCD detector records the images of the chromosphere with a pixel resolution of 0.27\(^{\prime \prime }\) and covers 9.2\(^{\prime }\) field-of-view. This telescope has a good guiding system that keeps the FoV in the intended position. We report the development of control software for tuning the filter unit, control detector system, observations and calibration of the data to make it useful for the scientific community. Some preliminary results obtained from the Merak \(\hbox {H}_{\alpha }\) telescope are also presented. This high altitude facility is a timely addition to regularly obtain \(\hbox {H}_{\alpha }\) images around the globe.  相似文献   

The Lost Natural Wetlands of Punjab (India): An Inventory     

Karanjot Kaur Brar  Vishwa Bandhu Singh Chandel 《Journal of the Indian Society of Remote Sensing》2012,40(1):97-107

Wetlands play a vital role in maintaining groundwater levels in an area. This is true for Punjab that was bestowed with several natural wetlands in the flood plains of its rivers. These natural wetlands have never been mapped and their existence has not been acknowledged. The large scale agricultural development in the state has made it India's leading food producing state. This development was done at the cost of certain ecologically sensitive parts, mainly the flood plains thus leading to the demise of wetlands. This paper is an attempt to retrace the lost wetlands that were existed in the flood plains of the three major rivers: Satluj, Beas and Ravi in the present day Punjab at the beginning of 20th century. A majority of these wetlands have not been documented so far and do not even have names. The purpose is to emphasize their elimination in addition to establishing a baseline dataset that can be a tool for wetland planning and management.  相似文献