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11.
12.
Determination of Lithium, Beryllium and Boron at Trace Levels by Laser Ablation-Inductively Coupled Plasma-Sector Field Mass Spectrometry 总被引:1,自引:2,他引:1
Massimo Tiepolo Alberto Zanetti Riccardo Vannucci 《Geostandards and Geoanalytical Research》2005,29(2):211-224
The analytical capabilities of laser ablation (LA)-ICP-MS in determining Li, Be and B at trace levels in geological samples have been tested on a series of glass reference materials and natural samples. The LA-ICP-MS instrument used consisted of a sector-field ICP-MS coupled with a laser ablation microprobe operating at either 266 or 213 nm wavelength. Reference glasses from NIST (SRM 612, 614 and 616) and MPI-DING (KL2-G, ML3B-G, StHs6/80-G, GOR128-G, GOR132-G, T1-G and ATHO-G) were selected to develop the analytical method and to assess the best instrumental configuration. A series of calcic amphiboles with different Li, Be and B concentrations were also analysed using both LA-ICP-MS and SIMS to test the applicability of the method to natural minerals. Results indicated that with a spot size of 40 μm the agreement between measured and reference values of Li, Be and B is generally better than 10% for NIST SRM 612 and 20% for NIST SRM 614. Average reproducibility at the 2s level was 10% for Li, 20% for Be and 15% for B. Limits of detection were approximately 100 ng g-1 for Be and B and 200 ng g-1 for Li. These results were confirmed by analyses carried out on natural amphiboles and compared well in terms of precision and accuracy with those commonly achieved by SIMS. 相似文献
13.
Olga Didova Brian Gunter Riccardo Riva Roland Klees Lutz Roese-Koerner 《Journal of Geodesy》2016,90(11):1207-1221
14.
Alessandro Comunian Leonardo De Micheli Claudio Lazzati Fabrizio Felletti Francesca Giacobbo Mauro Giudici Riccardo Bersezio 《Hydrogeology Journal》2016,24(2):319-334
The fine-scale heterogeneity of porous media affects the large-scale transport of solutes and contaminants in groundwater and it can be reproduced by means of several geostatistical simulation tools. However, including the available geological information in these tools is often cumbersome. A hierarchical simulation procedure based on a binary tree is proposed and tested on two real-world blocks of alluvial sediments, of a few cubic meters volume, that represent small-scale aquifer analogs. The procedure is implemented using the sequential indicator simulation, but it is so general that it can be adapted to various geostatistical simulation tools, improving their capability to incorporate geological information, i.e., the sedimentological and architectural characterization of heterogeneity. When compared with a standard sequential indicator approach on bi-dimensional simulations, in terms of proportions and connectivity indicators, the proposed procedure yields reliable results, closer to the reference observations. Different ensembles of three-dimensional simulations based on different hierarchical sequences are used to perform numerical experiments of conservative solute transport and to obtain ensembles of equivalent pore velocity and dispersion coefficient at the scale length of the blocks (meter). Their statistics are used to estimate the impact of the variability of the transport properties of the simulated blocks on contaminant transport modeled on bigger domains (hectometer). This is investigated with a one-dimensional transport modeling based on the Kolmogorov-Dmitriev theory of branching stochastic processes. Applying the proposed approach with diverse binary trees and different simulation settings provides a great flexibility, which is revealed by the differences in the breakthrough curves. 相似文献
15.
In order to explain a fine structure of parallel ridges in stationary type IV continua, the emission due to the coupling of electrostatic upper hybrid waves and Bernstein waves at the sum frequency of the upper hybrid and harmonics of the gyro frequency has been calculated. If the energy density of these electrostatic waves is of the order of 10-3 times the thermal energy density, then the observed zebra pattern can be emitted by a region with a diameter of 103 km. 相似文献
16.
Luiz N. da Costa Adi Nusser Wolfram Freudling Riccardo Giovanelli Martha P. Haynes John J. Salzer & Gary Wegner 《Monthly notices of the Royal Astronomical Society》1998,299(2):425-432
We present a comparison between the peculiar velocity fields measured from a recently completed l -band Tully–Fisher survey of field spirals (SFI) and that derived from the IRAS 1.2-Jy redshift survey galaxy distribution. The analysis is based on the expansion of these data in redshift space using smooth orthonormal functions, and is performed using low- and high-resolution expansions, with an effective smoothing scale which increases almost linearly with redshift. The effective smoothing scales at 3000 km s−1 are 1500 and 1000 km s−1 for the low- and high-resolution filters. The agreement between the high- and low-resolution SFI velocity maps is excellent. The general features in the filtered SFI and IRAS velocity fields agree remarkably well within 6000 km s−1 . This good agreement between the fields allows us to determine the parameter β = Ω0.6 / b , where Ω is the cosmological density parameter, and b is the linear biasing factor. From a likelihood analysis on the SFI and IRAS modes we find that β = 0.6 ± 0.1, independently of the resolution of the modal expansion. For this value of β, the residual fields for the two filters show no systematic variations within 6000 km s−1 . Most remarkable is the lack of any coherent, redshift-dependent dipole flow in the residual field. 相似文献
17.
Simone Dell��Agnello Caterina Lops Giovanni O. Delle Monache Douglas G. Currie Manuele Martini Roberto Vittori Angioletta Coradini Cesare Dionisio Marco Garattini Alessandro Boni Claudio Cantone Riccardo March Giovanni Bellettini Roberto Tauraso Mauro Maiello Luca Porcelli Simone Berardi Nicola Intaglietta 《Experimental Astronomy》2011,32(1):19-35
MAGIA is a mission approved by the Italian Space Agency (ASI) for Phase A study. Using a single large-diameter laser retroreflector, a large laser retroreflector array and an atomic clock onboard MAGIA we propose to perform several fundamental physics and absolute positioning metrology experiments: VESPUCCI, an improved test of the gravitational redshift in the Earth?CMoon system predicted by General Relativity; MoonLIGHT-P, a precursor test of a second generation Lunar Laser Ranging (LLR) payload for precision gravity and lunar science measurements under development for NASA, ASI and robotic missions of the proposed International Lunar Network (ILN); Selenocenter (the center of mass of the Moon), the determination of the position of the Moon center of mass with respect to the International Terrestrial Reference Frame/System (ITRF/ITRS); this will be compared to the one from Apollo and Lunokhod retroreflectors on the surface; MapRef, the absolute referencing of MAGIA??s lunar altimetry, gravity and geochemical maps with respect to the ITRF/ITRS. The absolute positioning of MAGIA will be achieved thanks to: (1) the laboratory characterization of the retroreflector performance at INFN-LNF; (2) the precision tracking by the International Laser Ranging Service (ILRS), which gives two fundamental contributions to the ITRF/ITRS, i.e. the metrological definition of the geocenter (the Earth center of mass) and of the scale of length; (3) the radio science and accelerometer payloads; (4) support by the ASI Space Geodesy Center in Matera, Italy. Future ILN geodetic nodes equipped with MoonLIGHT and the Apollo/Lunokhod retroreflectors will become the first realization of the International Moon Reference Frame (IMRF), the lunar analog of the ITRF. 相似文献
18.
Riccardo Claudi 《Astrophysics and Space Science》2010,328(1-2):319-323
The satellite PLATO represents a new challenge for future investigations of exoplanets and oscillations of stars. It is one of the proposed missions of ESA COSMIC VISION 2015–2025 and it is scheduled for launch in 2017. The goal of the mission is a full characterization of the planet star systems with an asteroseismic analysis of the host stars. The PLATO Payload Consortium (PPLC) includes several European countries which are employed in the assessment study of the mission. Thanks to the high precision photometry, PLATO is thought to be able to detect planets and oscillations within a large sample of targets. 相似文献
19.
20.
J.J. Blackford R.J. Payne M.P. Heggen A. de la Riva Caballero J. van der Plicht 《Quaternary Research》2014
The mid-Holocene eruption of Aniakchak volcano (Aniakchak II) in southwest Alaska was among the largest eruptions globally in the last 10,000 years (VEI-6). Despite evidence for possible impacts on global climate, the precise age of the eruption is not well-constrained and little is known about regional environmental impacts. A closely spaced sequence of radiocarbon dates at a peatland site over 1000 km from the volcano show that peat accumulation was greatly reduced with a hiatus of approximately 90–120 yr following tephra deposition. During this inferred hiatus no paleoenvironmental data are available but once vegetation returned the flora changed from a Cyperaceae-dominated assemblage to a Poaceae-dominated vegetation cover, suggesting a drier and/or more nutrient-rich ecosystem. Oribatid mites are extremely abundant in the peat at the depth of the ash, and show a longer-term, increasingly wet peat surface across the tephra layer. The radiocarbon sample immediately below the tephra gave a date of 1636–1446 cal yr BC suggesting that the eruption might be younger than previously thought. Our findings suggest that the eruption may have led to a widespread reduction in peatland carbon sequestration and that the impacts on ecosystem functioning were profound and long-lasting. 相似文献