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11.
Desorption of Cu and low molecular weight dissolved organics are the primary factors that impact fate and transport of Cu in soils. To improve predictions of the toxicity and threat from Cu contaminated soil, it is critical that time-dependent desorption behavior be understood. In this paper, the effect of organic ligands citrate, malate, and succinate on the kinetics of Cu desorption from contaminated soils varying widely in soil characteristics was investigated at 25° C and the soils used were referred to as clay, calcareous and sandy soils. The amount of Cu released by the used organic ligands varied greatly with physicochemical properties of the soils. The rate of Cu release by different extractants was in the order citric > malic > succinic, which was consistent with the stability constants of Cu complexes with these ligands. The modified Freundlich and the Elovich and Parabolic diffusion models were used to describe dsorption of Cu2+ from the three studied soils as affected by the organic ligands. All of the models fit the data well with correlation coefficients ranging from 0.83 to 1.00 (P < 0.01). Each Model has a set of assumptions for the different physical and chemical properties of the systems to which they are being applied. The uses of these equations yield different magnitudes for the calculated variable, but the relationships between the soil + organic ligands and their effect (i.e., increase or decrease) on these variables are the same. Such information is critical, since Cu is used in a variety of industrial and manufacturing processes and is one of the most common contaminants found at hazardous waste sites.  相似文献   
12.
The field relations, mineralogy, and major and trace elements (including REE analyses of whole-rock samples and minerals) of granites and their associated molybdenite uranium mineralized aplites in Southeastern Desert, Egypt, have been studied. The granites are leucocratic and mostly peraluminous in nature with muscovite increasing at the expense of biotite. The chemical and mineralogical characteristics of the granitic rocks indicate that their melts originated from the LILE-enriched mantle wedge by partial melting and are contaminated by crustal melts, followed by thermogravitational processes. Leucogranites with higher Na2O/K2O ratios from Um Dargag and Um Maiat crystallized under H2O-saturated equilibrium conditions in which the exsolved vapor continuously migrated away. The REE patterns of the granites studied are characterized by LREE enrichments and negative Eu anomalies. In comparison, the potassic aplites and the more sodic leucogranites are depleted in LREE, enriched in HREE and show more remarkable negative Eu anomalies. Allanite and monazite are the most important REE carriers in the granites. These minerals are strongly enriched in LREE, whereas fluorite and xenotime, which are more abundant in the aplites, are enriched in HREE. The average Lu/Ce ratio represents the fractionation trend with respect to HREE. It is 0.71 for radioactive fluorite, and it increases to 1.22 for non-radioactive fluorite. The high REE contents of molybdenite represent re-deposition of the mobilized Mo and REE. Due to the strong control of accessory minerals, the REEs are of limited use in petrogenetic modelling of highly evolved granitic systems.  相似文献   
13.
In spite of Jordan's insignificant natural resources and geopolitical problems, industrial development is being emphasized in Jordan since 1972. Industries are now the second largest sector of economy. Industries contributed 10% of the GDP in 1972, 19.5% in 1989 and 17.4% in 1993. This is remarkable as the national investment in industries is declining. The investments for industrial development was 30% of the total national investment in five year development plans (1976–1980), 23% in the next plan (1981–1985), and 13% in the following plan (1986–1990).The number of; industries has increased from 2500 in 1959 to 4684 in 1974, to 8533 in 1984, and 18600 in 1992. The employment or labor force also increased from 10,000 in 1959 to 70,000 in 1988, and to 110,000 in 1992. It represents about 16.4% of the total labor force in Jordan, the index number of industrial production also increased from (100) in 1979 which was the same base year, to (151) in 1983 to (205) in 1987 and to (215) in 1993. The study was based on three hypotheses: (i) the magnitude varies from one industry to another at the national (Jordan) and local (governorate levels), (ii) temporal change in the magnitude of industries has taken place during the period 1979–1992, (iii) the temporal change in the magnitude of industries was positive in some industries and negative in others.  相似文献   
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15.
Diverse vulnerabilities of Bangladesh's agricultural sector in 16 sub-regions are assessed using experiments designed to investigate climate impact factors in isolation and in combination. Climate information from a suite of global climate models (GCMs) is used to drive models assessing the agricultural impact of changes in temperature, precipitation, carbon dioxide concentrations, river floods, and sea level rise for the 2040–2069 period in comparison to a historical baseline. Using the multi-factor impacts analysis framework developed in Yu et al. (2010), this study provides new sub-regional vulnerability analyses and quantifies key uncertainties in climate and production. Rice (aman, boro, and aus seasons) and wheat production are simulated in each sub-region using the biophysical Crop Environment REsource Synthesis (CERES) models. These simulations are then combined with the MIKE BASIN hydrologic model for river floods in the Ganges-Brahmaputra-Meghna (GBM) Basins, and the MIKE21 Two-Dimensional Estuary Model to determine coastal inundation under conditions of higher mean sea level. The impacts of each factor depend on GCM configurations, emissions pathways, sub-regions, and particular seasons and crops. Temperature increases generally reduce production across all scenarios. Precipitation changes can have either a positive or a negative impact, with a high degree of uncertainty across GCMs. Carbon dioxide impacts on crop production are positive and depend on the emissions pathway. Increasing river flood areas reduce production in affected sub-regions. Precipitation uncertainties from different GCMs and emissions scenarios are reduced when integrated across the large GBM Basins’ hydrology. Agriculture in Southern Bangladesh is severely affected by sea level rise even when cyclonic surges are not fully considered, with impacts increasing under the higher emissions scenario.  相似文献   
16.
Water Resources - The scour and flow field patterns with accumulation of debris around bridge piers are completely different due to the reduction of flow area and the increase in depth average...  相似文献   
17.
Dammam City is one of the gorgeous coastal areas in the Arabian Gulf of Saudi Arabia.The present study aimed to ex-amine one of the copepod species infecting the rosy goatfish that represents a highly consumed fish species by the local population in the Arabian Gulf.The copepod species isolated from the infected fish specimens belong to the family Taeniacanthidae and was iden-tified as Irodes parupenei Ho and Lin(2007),primarily based on its morphological,morphometric,and ultrastructural characteris-tics,especially the structures of the dorsal cephalic area,segmentation of the first antenna,the absence of the maxilliped claw in the fe-male specimens,and the setation and spinulation of the legs 2-4 for the adult females are of great significance in the taxonomic iden-tification.The 18S rRNA gene sequence was analyzed to ensure the precise identity and exact taxonomic status of the copepod species.The result showed that this copepod species belong to Taenicanthidae and closely related to Irodes sauridi(gb|JF781550.1)in the same taxon.More details on the specificity of the goatfish for Irodes species and identifying these parasitic taxa using molecular analysis are given in the present study.  相似文献   
18.
Effects of rainfall patterns on runoff and rainfall-induced erosion   总被引:3,自引:0,他引:3  
Rainfall-induced erosion involves the detachment of soil particles by raindrop impact and their transport by the combined action of the shallow surface runoff and raindrop impact.Although temporal variation in rainfall intensity(pattern)during natural rainstorms is a common phenomenon,the available information is inadequate to understand its effects on runoff and rainfall-induced erosion processes.To address this issue,four simulated rainfall patterns(constant,increasing,decreasing,and increasing-decreasing)with the same total kinetic energy were designed.Two soil types(sandy and sandy loam)were subjected to simulated rainfall using 15 cm×30 cm long detachment trays under infiltration conditions.For each simulation,runoff and sediment concentration were sampled at regular intervals.No obvious difference was observed in runoff across the two soil types,but there were significant differences in soil losses among the different rainfall patterns and stages.For varying-intensity rainfall patterns,the dominant sediment transport mechanism was not only influenced by raindrop detachment but also was affected by raindrop-induced shallow flow transport.Moreover,the efficiency of equations that predict the interrill erosion rate increased when the integrated raindrop impact and surface runoff rate were applied.Although the processes of interrill erosion are complex,the findings in this study may provide useful insight for developing models that predict the effects of rainfall pattern on runoff and erosion.  相似文献   
19.
Crustal and lithospheric thicknesses of the southeastern Mediterranean Basin region were determined using 3D Bouguer and elevation data analysis. The model is based on the assumption of local isostatic equilibrium. The calculated regional and residual Bouguer anomaly maps were employed for highlighting both deep and shallow structures. Generally, the regional field in the area under study is considered to be mainly influenced by the density contrast between the crust and upper mantle. Use of the gravity and topographic data with earthquake focal depths has improved both the geometry and the density distribution in the 3-D calculated profiles. The oceanic-continental boundary, the basement relief, Moho depth and lithosphere-asthenosphere boundary maps were estimated. The results point to the occurrence of thick continental crust areas with a thickness of approximately 32 km in northern Egypt. Below the coastal regions, the thickness of crust decreases abruptly (transition zone). An inverse correlation between sediment and crustal thicknesses shows up from the study. Furthermore, our density model reveals the existence of a continental crustal zone below the Eratosthenes Seamount block. Nevertheless, the crustal type beneath the Levantine basin is typically oceanic; this is covered by sedimentary sequences more than 14 km thick. The modeled Moho map shows a depth of 28–30 km below Cyprus and a depth of 26–28 km beneath the south Florence Rise in the northern west. However, the Moho lies at a constant shallow depth of 22–24 km below the Levantine Basin, which indicates thinning of the crust beneath this region. The Moho map reveals also a maximum depth of about 33–35 km beneath both the northern Egypt and northern Sinai, both of which are of the continental crust. The resulting mantle density anomalies suggest important variations of the lithosphere-asthenosphere boundary (LAB) topography, indicating prominent lithospheric mantle thinning beneath south Cyprus (LAB ~90 km depth), followed by thickening beneath the Eratosthenes seamount, Florence Rise, Levantine Basin and reaching to maximum thickness below Cyprian Arc (LAB ~115–120 km depth), and further followed by thinning in the north African margin plate and north Sinai subplate (LAB ~90–95 km depth). According to our density model profiles, we find that almost all earthquakes in the study area occurred along the western and central segments of the Cyprian arc while they almost disappear along the eastern segment. The active subduction zone in the Cyprian Arc is associated with large negative anomalies due to its low velocity upper mantle zone, which might be an indication of a serpentinized mantle. This means that collision between Cyprus and the Eratosthenes Seamount block is marked by seismic activity. Additionally, this block is in the process of dynamically subsiding, breaking-up and being underthrusted beneath Cyprus to the north and thrusted onto the Levantine Basin to the south.  相似文献   
20.
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