Chemical and isotopic (Pb,Sr) zonation in a peraluminous granite pluton: role of fluid fractionation     

J.?DostalEmail author  A.?K.?Chatterjee  D.?J.?Kontak 《Contributions to Mineralogy and Petrology》2004,147(1):74-90

The Davis Lake pluton (DLP, ~800 km²) of southwestern Nova Scotia, Canada, part of the large peraluminous South Mountain batholith of ca. 380 Ma (U/Pb zircon, Ar/Ar mica), consists of granite and subordinate topaz–muscovite leucogranite that hosts greisen tin-base metal mineralization. A new Pb–Pb isochron age for leucogranite from the most evolved part of the DLP indicates a crystallization age of 378±3.6 Ma, coincident with other radiometric ages of the DLP (Rb–Sr, Re–Os, Pb–Pb). The intrusion displays a compositional zonation defined by lead and strontium isotopic ratios, as well as some major elements (e.g., Si, F), incompatible trace elements (e.g., Li, Rb, Ta, U, Sn), and elemental ratios (e.g., K/Rb and Nb/Ta). The greisens and the leucogranites that host them are characterized by extreme radiogenic compositions for Pb and Sr, and their chemical-isotopic trends are extensions of the trends displayed by the less evolved granites. The covariations of the isotopic ratios with several major and trace elements and elemental ratios as well as the Pb–Pb and Rb–Sr isochrones indicate that all phases of the intrusion originated from a homogeneous parental magma. The granitoid magma underwent extensive fractional crystallization of feldspars, minor biotite and accessory minerals (monazite, apatite and zircon) in a compositionally zoned magma chamber that was subsequently accompanied by fluid fractionation, during which time the internally derived fluorine-rich fluids modified the Rb/Sr, U/Pb and Th/Pb ratios, leading to distinct variations of ⁸⁷Sr/⁸⁶Sr, ²⁰⁶Pb/²⁰⁴Pb, ²³⁸U/²⁰⁴Pb and ²³²Th/²⁰⁴Pb isotopic ratios. These data therefore document the evolution of a granitic magma through magmatic (i.e., crystal fractionation), orthomagmatic (i.e., crystal-fluid fractionation) and hydrothermal (i.e., fluid fractionation) stages that culminated in the formation of a tin-base metal deposit. The Pb isotope data also constrain the source region for the DLP as being Avalonian basement that, by inference, must underlie much of the Meguma Terrane.Editorial responsibility: T.L. Grove  相似文献   

Wavelet‐based non‐stationary seismic rocking response of flexibly supported tanks     

Pranesh Chatterjee  Biswajit Basu 《地震工程与结构动力学》2004,33(2):157-181

The non‐stationary rocking response of liquid storage tanks under seismic base excitations including soil interaction has been developed based on the wavelet domain random vibration theory. The ground motion has been characterized through statistical functionals of wavelet coefficients of the ground acceleration history. The tank–liquid–foundation system is modelled as a multi‐degree‐of‐freedom (MDOF) system with both lateral and rocking motions of vibration of the foundation. The impulsive and convective modes of vibration of the liquid in the tank have been considered. The wavelet domain coupled dynamic equations are formulated and then solved to get the expressions of instantaneous power spectral density function (PSDF) in terms of functionals of input wavelet coefficients. The moments of the instantaneous PSDF are used to obtain the stochastic responses of the tank in the form of coefficients of hydrodynamic pressure, base shear and overturning base moment for the largest expected peak responses. Parametric variations are carried out to study the effects of various governing parameters like height of liquid in the tank, height–radius ratio of the tank, ratio of total liquid mass to mass of foundation, and shear wave velocity in the soil medium, on the responses of the tank. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

Understanding the turbulent structure of the atmospheric boundary layer: A diagnostic approach     

M Chatterjee  G K Sen  D K Sinha 《Journal of Earth System Science》1996,105(1):63-80

In this paper, we have attempted a diagnostic study of the turbulence characteristics of the ABL by means of two one-dimensional models. The first model uses a first order non-local closure, based on the Transilient Turbulence Theory, for parameterizing turbulent fluxes. while the second model uses second order local closure for parameterizing these. The models have been applied to conduct case studies using the Kytoon data taken at Kharagpur, during 17th–21st June, 1990, as part of the MONTBLEX programme. Our findings bring out various interesting features regarding the non-local and local turbulent statistics such as kinematic fluxes, turbulence kinetic energy, vertical velocity variance, the contribution of the eddies of various sizes to the fluxes at different level and the mixing lengths. The one-dimensional anisotropy of the turbulent eddies has been revealed by the findings from the transilient model. The vertical variation of the turbulence kinetic energy, as computed directly by the second order model, is found to be strongly correlated with the vertical velocity variance. In particular, for stably stratified boundary layers, identification of two distinct zones of the turbulence kinetic energy and corresponding vertical velocity maxima is possible, which has been interpreted as positive evidence of patchy turbulence in the boundary layer.  相似文献   

Results from the Indo-USSR ozonesonde intercomparison experiment     

B. H. Subbaraya  K. S. Appu  K. P. Chatterjee  A. F. Chizhov  V. D. Grinchinkov  A. Jayaraman  G. A. Khokin  V. A. Kononkov  I. S. Moshnikov  V. Narayanan  S. P. Perov  O. V. Shtrikov  Y. V. Somayajulu  C. R. Sreedharan  K. S. Zalpuri 《Journal of Earth System Science》1987,96(1):25-40

A total of seventeen vertical profiles of ozone were obtained during an Indo-USSR collaborative experiment on ozonesonde intercomparison conducted at Thumba during March 1983. The vertical distribution of ozone was measured using rocket-borne, balloon-borne as well as ground-based instruments. Four different rocket ozonesondes from India and USSR and the balloon ozonesonde were used to makein situ observations of ozone concentrations in addition to the Dobson spectrophotometric observations of total ozone and Umkehr. The rocket and the balloon launchings were effected in three salvos and measurements were made at different times of the day as well as during night. The results of all these measurements are used to obtain a mean ozone vertical distribution over Thumba foT the spring equinoxial period. The mean profile shows the maximum ozone concentration at 27 km with a value of (3.86±0-52)×10¹² molecules per cc. Comparison of this mean profile with available satellite data for the equatorial regions shows that, in general, the Thumba values are lower by 10–15% at altitudes below 40 km and larger at altitudes above 50 km compared to the satellite results. The data also show evidence for a day-to-day variability and a possible day-to-night variability in the ozone vertical distribution with the night-time values higher than the daytime values at all altitudes above 35 km and the difference is found to increase with the increasing altitude.  相似文献   

Ephesite,Na(LiAl2) [Al2Si2O10] (OH)2: II. Thermodynamic analysis of its stability and compatibility relations,and its geological occurrences     

Niranjan D. Chatterjee  Udo Warhus 《Contributions to Mineralogy and Petrology》1984,85(1):80-84

The trioctahedral mica ephesite, Na(LiAl₂) [Al₂Si₂O₁₀] (OH)₂, has a large -T stability field in the quaternary system NaAlSiO₄-LiAlSiO₄-Al₂O₃-H₂O. At temperatures below 400–500° C it coexists with diaspore, while at higher temperatures it occurs with corundum, until it decomposes to nepheline +eucryptite+corundum+H₂O at 600–800° C (Fig. 1). Nature faithfully reflects these phase relations; ephesite is found to coexist with diaspore or corundum in silicadeficient metamorphosed rocks or in hydrothermally altered nepheline-syenite pegmatite.Thermodynamic analysis of phase relations of ephesite in the silica saturated portion of the quinary system NaAlSiO₄-LiAlSiO₄-Al₂O₃-SiO₂-H₂O shows that the assemblage quartz+ephesite is always metastable with respect to paragonite+spodumene or paragonite+petalite at temperatures down to approximately 300° C (Fig. 3). At lower temperatures, a number of other phases like bikitaite, cookeite, Na-montmorillonite, and analcime are stabilized. Stability and compatibility relations involving these phases are presently not amenable to thermodynamic treatment due to lack of suitable data. Nevertheless, the absence of the assemblage quartz+ephesite in nature seems to vindicate our conclusion that it is metastable down to at least 300° C.The frequently encountered assemblage quartzspodumene (or petalite)-microcline-albite of some lithium pegmatites contains muscovite (±lepidolite), rather than paragonite. The absence of paragonite in such rocks is best explained by the inherent metastability of the phase-pair paragonite+microcline with respect to muscovite+albite. The pegmatite bulk compositions plot in the four-phase field spodumene (petalite)-microcline-muscovite-albite, cutting out paragonite from the observed assemblage Thus, absence of paragonite-spodumene or paragonitepetalite in nature reflects lack of suitable bulk compositions in rocks.  相似文献   

Pressure-induced (Al,Si)[4]-ordering in dioctahedral micas?     

Susanne Flux  Niranjan D. Chatterjee  Klaus Langer 《Contributions to Mineralogy and Petrology》1984,86(3):294-297

Pure, synthetic 2M₁-muscovites (Ms) and 2M₁-paragonites (Pg) prepared at 7, 13.5, and 18 kbar have been subjected to careful X-ray powder diffractometry and IR powder spectrometry. The results of X-ray studies show that the lattice constants of these micas are independent of the pressure employed in synthesizing them. Similarly, the IR powder spectra of Ms and Pg remain unaffected by the synthesis pressure. Neither the Al^[4]-O-Al^[4] vibrations decrease in relative intensity nor do the Si-O-Al^[4] vibrations increase in intensity with increasing pressure of synthesis, as they should, if pressure-induced (Al, Si)^[4] ordering had been operative. Finally, the v _OH bands in Ms and Pg are also found to retain their fine structural details, regardless of the pressures employed in synthesizing these phases. In particular, the half widths of v _OH in these (Al,Si)^[4]-disordered micas remain constant at around 60 cm⁻¹, compared to ∼ 10 cm⁻¹ in (Al,Si)^[4]-ordered mica margarite. In the light of this study, shortening of the b lattice parameter and progressive (Al,Si)^[4] ordering with increasing pressure of synthesis of muscovites reported by Velde (1980) would appear to be anomalous. Consequently, any discussion of the effect of (Al,Si)^[4] ordering on the stability of muscovite is a moot point at present.  相似文献   

Two- and three-dimensional gravity modeling along western continental margin and intraplate Narmada-Tapti rifts: Its relevance to Deccan flood basalt volcanism   总被引：1，自引：0，他引：1  

Somdev Bhattacharji  Rajesh Sharma  Nilanjan Chatterjee 《Journal of Earth System Science》2004,113(4):771-784

The western continental margin and the intraplate Narmada-Tapti rifts are primarily covered by Deccan flood basalts. Three-dimensional gravity modeling of +70mgal Bouguer gravity highs extending in the north-south direction along the western continental margin rift indicates the presence of a subsurface high density, mafic-ultramafic type, elongated, roughly ellipsoidal body. It is approximately 12.0 ±1.2 km thick with its upper surface at an approximate depth of 6.0 ±0.6 km, and its average density is {dy2935} kg/m³. Calculated dimension of the high density body in the upper crust is 300 ±30 km in length and 25 ±2.5 to 40 ±4 km in width. Three-dimensional gravity modeling of +10mgal to -30mgal Bouguer gravity highs along the intraplate Narmada-Tapti rift indicates the presence of eight small isolated high density mafic bodies with an average density of {dy2961} kg/m³. These mafic bodies are convex upward and their top surface is estimated at an average depth of 6.5 ±0.6 (between 6 and 8km). These isolated mafic bodies have an average length of 23.8 ±2.4km and width of 15.9 ±1.5km. Estimated average thickness of these mafic bodies is 12.4±1.2km. The difference in shape, length and width of these high density mafic bodies along the western continental margin and the intraplate Narmada-Tapti rifts suggests that the migration and concentration of high density magma in the upper lithosphere was much more dominant along the western continental margin rift. Based on the three-dimensional gravity modeling, it is conjectured that the emplacement of large, ellipsoidal high density mafic bodies along the western continental margin and small, isolated mafic bodies along the Narmada-Tapti rift are related to lineament-reactivation and subsequent rifting due to interaction of hot mantle plume with the lithospheric weaknesses (lineaments) along the path of Indian plate motion over the Réunion hotspot. Mafic bodies formed in the upper lithosphere as magma chambers along the western continental margin and the intraplate Narmada-Tapti rifts at estimated depths between 6 and 8 km from the surface (consistent with geological, petrological and geochemical models) appear to be the major reservoirs for Deccan flood basalt volcanism at approximately 65 Ma.  相似文献   

A Breadth Averaged Numerical Model for Suspended Sediment Transport in Hooghly Estuary,East Coast of India   总被引：2，自引：0，他引：2  

Sinha  P. C.  Guliani  Pragya  Jena  G. K.  Rao  A. D.  Dube  S. K.  Chatterjee  A. K.  Murty  Tad 《Natural Hazards》2004,32(2):239-255

Sedimentation is of vital concern in the conservation, development and utilization ofour soil and water resources. The suspended sediment in estuarine waters is hazardousto navigation in estuaries, which have important ports and harbours. A breadth-averagednumerical model to study circulation and sediment transport is presented in this paper.The model is applied to Hooghly estuary, along the east coast of India. The model is fullynon-linear and uses a semi-explicit finite difference scheme to solve mass, momentum andadvection diffusion equation for suspended sediments in a vertical plane. The erosion anddeposition have been computed by empirically developed source and sink terms in thesuspended sediment equation.  相似文献   

A dynamical study of the frequency of merging galaxies     

Tapan K. Chatterjee 《Astrophysics and Space Science》1991,184(2):273-280

A study of the expected frequency of merging galaxies, involving disk-sphere systems, is conducted by use of the impulsive approximation. The results indicate that the expected frequencies of such galaxies is several orders of magnitude smaller than the observational value, if mergers taking place in a single crossing time or orbital period are considered. The expected frequency of elliptical pairs and spiral-elliptical pairs in merger is of the same order of magnitude, indicating that the two types of collisions are equally frequent. This aspect will be further investigated in subsequent papers of this series.  相似文献   

On the Dispersion of Love Waves and Crust-Mantle Structure in the Gangetic Basin     

S. N. Chatterjee 《Geophysical Journal International》1971,23(2):129-138

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